Adsorption Isotherms and Kinetics of Pb (II) and Cd (II) Ions onto Carbonised Sugarcane Bagasse

Oklo Ahola David; Enenche Elaigwu Daniel; Adie Agorye Peter; Enyi Ogor Simeon

doi:doi:10.11648/j.ab.20210903.12

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Adsorption Isotherms and Kinetics of Pb (II) and Cd (II) Ions onto Carbonised Sugarcane Bagasse

Oklo Ahola David, Enenche Elaigwu Daniel, Adie Agorye Peter, Enyi Ogor Simeon

Published in Advances in Biochemistry (Volume 9, Issue 3)

Received: 8 May 2021 Accepted: 2 June 2021 Published: 18 August 2021

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Abstract

In the present study, the adsorption of Pb (II) and Cd (II) ions from aqueous solution of lead (II) nitrate and cadmium chloride onto carbonized sugarcane bagasse was investigated. The physicochemical attributes of the adsorbent were: bulk density =0.58 g/mL, Ash content =21%, Attrition =31.33% and moisture =0.79%. The effects of adsorption dosage, effect of concentration, effect of ion concentration, effect of adsorbent contact time and effect of pH was discussed and detailed. Batch adsorption experiments revealed that the amount of ion adsorbed decreased with increase in adsorbent dosage; the effect of concentration on ion uptake increased with increase in concentration; there was a rapid increase in amount adsorbed as contact time increased with maximum adsorption reached at 80 minutes before subsequent reduction. The effect of pH showed that there was effective removal of ions at acidic pH than in alkaline pH level. The linearized form of Langmuir model revealed isotherm parameters that confirmed the sorptive capacity of the sugarcane bagasse and thus fit for heavy metal remediation from aqueous solution. Besides, the adsorption isotherm indicated that the adsorption occurred at homogeneous sites and form a monolayer. The Langmuir model was also able to explain the sorption equilibrium with maximum biosorption capacity.

Published in	Advances in Biochemistry (Volume 9, Issue 3)
DOI	10.11648/j.ab.20210903.12
Page(s)	44-49
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Sugarcane Bagasse, Adsorption, Activated Carbon, Heavy Metals

References

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[5]	Bulgariu, L., Escudero, L. B., Bello, O. S., Iqbal, M.; Nisar, J., Adegoke, K. A., Alakhras, F., Kornaros, M. and Anastopoulos, I. (2019). The utilization of leaf-based adsorbents for dyes removal: A review. J. Mol. Liq. 276: 728–747.
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[12]	Dias, J. M. Alvim-Ferraz, M. C. M. Almeida, M. F. Rivera-Utrilla, J. Sánchez-Polo, M. (2007). Waste materials for activated carbon preparation and its use in aqueous-phase treatment: A review, Journal of Environmental Management. 85 (4): 833-846.
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APA Style

Oklo Ahola David, Enenche Elaigwu Daniel, Adie Agorye Peter, Enyi Ogor Simeon. (2021). Adsorption Isotherms and Kinetics of Pb (II) and Cd (II) Ions onto Carbonised Sugarcane Bagasse. Advances in Biochemistry, 9(3), 44-49. https://doi.org/10.11648/j.ab.20210903.12

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ACS Style

Oklo Ahola David; Enenche Elaigwu Daniel; Adie Agorye Peter; Enyi Ogor Simeon. Adsorption Isotherms and Kinetics of Pb (II) and Cd (II) Ions onto Carbonised Sugarcane Bagasse. Adv. Biochem. 2021, 9(3), 44-49. doi: 10.11648/j.ab.20210903.12

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AMA Style

Oklo Ahola David, Enenche Elaigwu Daniel, Adie Agorye Peter, Enyi Ogor Simeon. Adsorption Isotherms and Kinetics of Pb (II) and Cd (II) Ions onto Carbonised Sugarcane Bagasse. Adv Biochem. 2021;9(3):44-49. doi: 10.11648/j.ab.20210903.12

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@article{10.11648/j.ab.20210903.12,
  author = {Oklo Ahola David and Enenche Elaigwu Daniel and Adie Agorye Peter and Enyi Ogor Simeon},
  title = {Adsorption Isotherms and Kinetics of Pb (II) and Cd (II) Ions onto Carbonised Sugarcane Bagasse},
  journal = {Advances in Biochemistry},
  volume = {9},
  number = {3},
  pages = {44-49},
  doi = {10.11648/j.ab.20210903.12},
  url = {https://doi.org/10.11648/j.ab.20210903.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ab.20210903.12},
  abstract = {In the present study, the adsorption of Pb (II) and Cd (II) ions from aqueous solution of lead (II) nitrate and cadmium chloride onto carbonized sugarcane bagasse was investigated. The physicochemical attributes of the adsorbent were: bulk density =0.58 g/mL, Ash content =21%, Attrition =31.33% and moisture =0.79%. The effects of adsorption dosage, effect of concentration, effect of ion concentration, effect of adsorbent contact time and effect of pH was discussed and detailed. Batch adsorption experiments revealed that the amount of ion adsorbed decreased with increase in adsorbent dosage; the effect of concentration on ion uptake increased with increase in concentration; there was a rapid increase in amount adsorbed as contact time increased with maximum adsorption reached at 80 minutes before subsequent reduction. The effect of pH showed that there was effective removal of ions at acidic pH than in alkaline pH level. The linearized form of Langmuir model revealed isotherm parameters that confirmed the sorptive capacity of the sugarcane bagasse and thus fit for heavy metal remediation from aqueous solution. Besides, the adsorption isotherm indicated that the adsorption occurred at homogeneous sites and form a monolayer. The Langmuir model was also able to explain the sorption equilibrium with maximum biosorption capacity.},
 year = {2021}
}

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TY  - JOUR
T1  - Adsorption Isotherms and Kinetics of Pb (II) and Cd (II) Ions onto Carbonised Sugarcane Bagasse
AU  - Oklo Ahola David
AU  - Enenche Elaigwu Daniel
AU  - Adie Agorye Peter
AU  - Enyi Ogor Simeon
Y1  - 2021/08/18
PY  - 2021
N1  - https://doi.org/10.11648/j.ab.20210903.12
DO  - 10.11648/j.ab.20210903.12
T2  - Advances in Biochemistry
JF  - Advances in Biochemistry
JO  - Advances in Biochemistry
SP  - 44
EP  - 49
PB  - Science Publishing Group
SN  - 2329-0862
UR  - https://doi.org/10.11648/j.ab.20210903.12
AB  - In the present study, the adsorption of Pb (II) and Cd (II) ions from aqueous solution of lead (II) nitrate and cadmium chloride onto carbonized sugarcane bagasse was investigated. The physicochemical attributes of the adsorbent were: bulk density =0.58 g/mL, Ash content =21%, Attrition =31.33% and moisture =0.79%. The effects of adsorption dosage, effect of concentration, effect of ion concentration, effect of adsorbent contact time and effect of pH was discussed and detailed. Batch adsorption experiments revealed that the amount of ion adsorbed decreased with increase in adsorbent dosage; the effect of concentration on ion uptake increased with increase in concentration; there was a rapid increase in amount adsorbed as contact time increased with maximum adsorption reached at 80 minutes before subsequent reduction. The effect of pH showed that there was effective removal of ions at acidic pH than in alkaline pH level. The linearized form of Langmuir model revealed isotherm parameters that confirmed the sorptive capacity of the sugarcane bagasse and thus fit for heavy metal remediation from aqueous solution. Besides, the adsorption isotherm indicated that the adsorption occurred at homogeneous sites and form a monolayer. The Langmuir model was also able to explain the sorption equilibrium with maximum biosorption capacity.
VL  - 9
IS  - 3
ER  -

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Author Information

Oklo Ahola David

Department of Chemistry, Benue State University, Makurdi, Nigeria
Enenche Elaigwu Daniel

Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria
Adie Agorye Peter

Department of Chemistry, Benue State University, Makurdi, Nigeria
Enyi Ogor Simeon

Department of Chemistry, Benue State University, Makurdi, Nigeria

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APA Style

Oklo Ahola David, Enenche Elaigwu Daniel, Adie Agorye Peter, Enyi Ogor Simeon. (2021). Adsorption Isotherms and Kinetics of Pb (II) and Cd (II) Ions onto Carbonised Sugarcane Bagasse. Advances in Biochemistry, 9(3), 44-49. https://doi.org/10.11648/j.ab.20210903.12

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ACS Style

Oklo Ahola David; Enenche Elaigwu Daniel; Adie Agorye Peter; Enyi Ogor Simeon. Adsorption Isotherms and Kinetics of Pb (II) and Cd (II) Ions onto Carbonised Sugarcane Bagasse. Adv. Biochem. 2021, 9(3), 44-49. doi: 10.11648/j.ab.20210903.12

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AMA Style

Oklo Ahola David, Enenche Elaigwu Daniel, Adie Agorye Peter, Enyi Ogor Simeon. Adsorption Isotherms and Kinetics of Pb (II) and Cd (II) Ions onto Carbonised Sugarcane Bagasse. Adv Biochem. 2021;9(3):44-49. doi: 10.11648/j.ab.20210903.12

Copy | Download

@article{10.11648/j.ab.20210903.12,
  author = {Oklo Ahola David and Enenche Elaigwu Daniel and Adie Agorye Peter and Enyi Ogor Simeon},
  title = {Adsorption Isotherms and Kinetics of Pb (II) and Cd (II) Ions onto Carbonised Sugarcane Bagasse},
  journal = {Advances in Biochemistry},
  volume = {9},
  number = {3},
  pages = {44-49},
  doi = {10.11648/j.ab.20210903.12},
  url = {https://doi.org/10.11648/j.ab.20210903.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ab.20210903.12},
  abstract = {In the present study, the adsorption of Pb (II) and Cd (II) ions from aqueous solution of lead (II) nitrate and cadmium chloride onto carbonized sugarcane bagasse was investigated. The physicochemical attributes of the adsorbent were: bulk density =0.58 g/mL, Ash content =21%, Attrition =31.33% and moisture =0.79%. The effects of adsorption dosage, effect of concentration, effect of ion concentration, effect of adsorbent contact time and effect of pH was discussed and detailed. Batch adsorption experiments revealed that the amount of ion adsorbed decreased with increase in adsorbent dosage; the effect of concentration on ion uptake increased with increase in concentration; there was a rapid increase in amount adsorbed as contact time increased with maximum adsorption reached at 80 minutes before subsequent reduction. The effect of pH showed that there was effective removal of ions at acidic pH than in alkaline pH level. The linearized form of Langmuir model revealed isotherm parameters that confirmed the sorptive capacity of the sugarcane bagasse and thus fit for heavy metal remediation from aqueous solution. Besides, the adsorption isotherm indicated that the adsorption occurred at homogeneous sites and form a monolayer. The Langmuir model was also able to explain the sorption equilibrium with maximum biosorption capacity.},
 year = {2021}
}

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TY  - JOUR
T1  - Adsorption Isotherms and Kinetics of Pb (II) and Cd (II) Ions onto Carbonised Sugarcane Bagasse
AU  - Oklo Ahola David
AU  - Enenche Elaigwu Daniel
AU  - Adie Agorye Peter
AU  - Enyi Ogor Simeon
Y1  - 2021/08/18
PY  - 2021
N1  - https://doi.org/10.11648/j.ab.20210903.12
DO  - 10.11648/j.ab.20210903.12
T2  - Advances in Biochemistry
JF  - Advances in Biochemistry
JO  - Advances in Biochemistry
SP  - 44
EP  - 49
PB  - Science Publishing Group
SN  - 2329-0862
UR  - https://doi.org/10.11648/j.ab.20210903.12
AB  - In the present study, the adsorption of Pb (II) and Cd (II) ions from aqueous solution of lead (II) nitrate and cadmium chloride onto carbonized sugarcane bagasse was investigated. The physicochemical attributes of the adsorbent were: bulk density =0.58 g/mL, Ash content =21%, Attrition =31.33% and moisture =0.79%. The effects of adsorption dosage, effect of concentration, effect of ion concentration, effect of adsorbent contact time and effect of pH was discussed and detailed. Batch adsorption experiments revealed that the amount of ion adsorbed decreased with increase in adsorbent dosage; the effect of concentration on ion uptake increased with increase in concentration; there was a rapid increase in amount adsorbed as contact time increased with maximum adsorption reached at 80 minutes before subsequent reduction. The effect of pH showed that there was effective removal of ions at acidic pH than in alkaline pH level. The linearized form of Langmuir model revealed isotherm parameters that confirmed the sorptive capacity of the sugarcane bagasse and thus fit for heavy metal remediation from aqueous solution. Besides, the adsorption isotherm indicated that the adsorption occurred at homogeneous sites and form a monolayer. The Langmuir model was also able to explain the sorption equilibrium with maximum biosorption capacity.
VL  - 9
IS  - 3
ER  -

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