Equilibrium and Kinetic Studies on Biosorption of Iron (II) and Iron (III) Ions onto Eggshell Powder from Aqueous Solution

Eman Aly Ashour; Maha Abdelbaset Tony

doi:doi:10.11648/j.ae.20170101.14

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Equilibrium and Kinetic Studies on Biosorption of Iron (II) and Iron (III) Ions onto Eggshell Powder from Aqueous Solution

Eman Aly Ashour, Maha Abdelbaset Tony

Published in Applied Engineering (Volume 1, Issue 1)

Received: 28 February 2017 Accepted: 12 April 2017 Published: 2 June 2017

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Abstract

As a consequence of modernization, industry is spread in the whole world, one of the industries that producing a wastewater as a by-product, iron and steel industry. The result is a huge amount of wastewater that contaminated with iron and steel. Biosorption techniques especially with a natural low cost adsorbent material, namely chicken eggshell is gaining an important goal for treating with a cost efficient material. This present investigation, eggshell (untreated natural eggshell and the treated one which is burned to 500°C) was applied for two types of iron removal from wastewater (Fe²⁺ and Fe³⁺). The adsorption capacity of Fe³⁺ and Fe²⁺ verified 105.4 and 165.6 mg/g, respectively within 120 minutes for the unmodified eggshell, which enhanced to 129.7 and 181.3 mg/g, respectively, for the modified eggshell. Different parameters were studied such as initial iron concentration in wastewater, agitation speed and the mass of the biosorbent. The isotherm study revealed that the data well fitted for linearized forms of Langmuir. The kinetic study followed the pseudo-second order reaction rate.

Published in	Applied Engineering (Volume 1, Issue 1)
DOI	10.11648/j.ae.20170101.14
Page(s)	32-40
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Biorbent, Chicken Eggshell By-Product, Iron, Wastewater

References

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APA Style

Eman Aly Ashour, Maha Abdelbaset Tony. (2017). Equilibrium and Kinetic Studies on Biosorption of Iron (II) and Iron (III) Ions onto Eggshell Powder from Aqueous Solution. Applied Engineering, 1(1), 32-40. https://doi.org/10.11648/j.ae.20170101.14

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ACS Style

Eman Aly Ashour; Maha Abdelbaset Tony. Equilibrium and Kinetic Studies on Biosorption of Iron (II) and Iron (III) Ions onto Eggshell Powder from Aqueous Solution. Appl. Eng. 2017, 1(1), 32-40. doi: 10.11648/j.ae.20170101.14

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AMA Style

Eman Aly Ashour, Maha Abdelbaset Tony. Equilibrium and Kinetic Studies on Biosorption of Iron (II) and Iron (III) Ions onto Eggshell Powder from Aqueous Solution. Appl Eng. 2017;1(1):32-40. doi: 10.11648/j.ae.20170101.14

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@article{10.11648/j.ae.20170101.14,
  author = {Eman Aly Ashour and Maha Abdelbaset Tony},
  title = {Equilibrium and Kinetic Studies on Biosorption of Iron (II) and Iron (III) Ions onto Eggshell Powder from Aqueous Solution},
  journal = {Applied Engineering},
  volume = {1},
  number = {1},
  pages = {32-40},
  doi = {10.11648/j.ae.20170101.14},
  url = {https://doi.org/10.11648/j.ae.20170101.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ae.20170101.14},
  abstract = {As a consequence of modernization, industry is spread in the whole world, one of the industries that producing a wastewater as a by-product, iron and steel industry. The result is a huge amount of wastewater that contaminated with iron and steel. Biosorption techniques especially with a natural low cost adsorbent material, namely chicken eggshell is gaining an important goal for treating with a cost efficient material. This present investigation, eggshell (untreated natural eggshell and the treated one which is burned to 500°C) was applied for two types of iron removal from wastewater (Fe2+ and Fe3+). The adsorption capacity of Fe3+ and Fe2+ verified 105.4 and 165.6 mg/g, respectively within 120 minutes for the unmodified eggshell, which enhanced to 129.7 and 181.3 mg/g, respectively, for the modified eggshell. Different parameters were studied such as initial iron concentration in wastewater, agitation speed and the mass of the biosorbent. The isotherm study revealed that the data well fitted for linearized forms of Langmuir. The kinetic study followed the pseudo-second order reaction rate.},
 year = {2017}
}

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TY  - JOUR
T1  - Equilibrium and Kinetic Studies on Biosorption of Iron (II) and Iron (III) Ions onto Eggshell Powder from Aqueous Solution
AU  - Eman Aly Ashour
AU  - Maha Abdelbaset Tony
Y1  - 2017/06/02
PY  - 2017
N1  - https://doi.org/10.11648/j.ae.20170101.14
DO  - 10.11648/j.ae.20170101.14
T2  - Applied Engineering
JF  - Applied Engineering
JO  - Applied Engineering
SP  - 32
EP  - 40
PB  - Science Publishing Group
SN  - 2994-7456
UR  - https://doi.org/10.11648/j.ae.20170101.14
AB  - As a consequence of modernization, industry is spread in the whole world, one of the industries that producing a wastewater as a by-product, iron and steel industry. The result is a huge amount of wastewater that contaminated with iron and steel. Biosorption techniques especially with a natural low cost adsorbent material, namely chicken eggshell is gaining an important goal for treating with a cost efficient material. This present investigation, eggshell (untreated natural eggshell and the treated one which is burned to 500°C) was applied for two types of iron removal from wastewater (Fe2+ and Fe3+). The adsorption capacity of Fe3+ and Fe2+ verified 105.4 and 165.6 mg/g, respectively within 120 minutes for the unmodified eggshell, which enhanced to 129.7 and 181.3 mg/g, respectively, for the modified eggshell. Different parameters were studied such as initial iron concentration in wastewater, agitation speed and the mass of the biosorbent. The isotherm study revealed that the data well fitted for linearized forms of Langmuir. The kinetic study followed the pseudo-second order reaction rate.
VL  - 1
IS  - 1
ER  -

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Author Information

Eman Aly Ashour

Chemical Engineering Department, Faculty of Engineering, Minia University, EL-Minia, Egypt
Maha Abdelbaset Tony

Advanced Materials / Solar Energy and Environmental Sustainability Laboratory, Basic Engineering Science Department, Faculty of Engineering, Minoufia University, Shbin El-koum, Minoufia, Egypt

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Plain Text BibTeX RIS

APA Style

Eman Aly Ashour, Maha Abdelbaset Tony. (2017). Equilibrium and Kinetic Studies on Biosorption of Iron (II) and Iron (III) Ions onto Eggshell Powder from Aqueous Solution. Applied Engineering, 1(1), 32-40. https://doi.org/10.11648/j.ae.20170101.14

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ACS Style

Eman Aly Ashour; Maha Abdelbaset Tony. Equilibrium and Kinetic Studies on Biosorption of Iron (II) and Iron (III) Ions onto Eggshell Powder from Aqueous Solution. Appl. Eng. 2017, 1(1), 32-40. doi: 10.11648/j.ae.20170101.14

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AMA Style

Eman Aly Ashour, Maha Abdelbaset Tony. Equilibrium and Kinetic Studies on Biosorption of Iron (II) and Iron (III) Ions onto Eggshell Powder from Aqueous Solution. Appl Eng. 2017;1(1):32-40. doi: 10.11648/j.ae.20170101.14

Copy | Download

@article{10.11648/j.ae.20170101.14,
  author = {Eman Aly Ashour and Maha Abdelbaset Tony},
  title = {Equilibrium and Kinetic Studies on Biosorption of Iron (II) and Iron (III) Ions onto Eggshell Powder from Aqueous Solution},
  journal = {Applied Engineering},
  volume = {1},
  number = {1},
  pages = {32-40},
  doi = {10.11648/j.ae.20170101.14},
  url = {https://doi.org/10.11648/j.ae.20170101.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ae.20170101.14},
  abstract = {As a consequence of modernization, industry is spread in the whole world, one of the industries that producing a wastewater as a by-product, iron and steel industry. The result is a huge amount of wastewater that contaminated with iron and steel. Biosorption techniques especially with a natural low cost adsorbent material, namely chicken eggshell is gaining an important goal for treating with a cost efficient material. This present investigation, eggshell (untreated natural eggshell and the treated one which is burned to 500°C) was applied for two types of iron removal from wastewater (Fe2+ and Fe3+). The adsorption capacity of Fe3+ and Fe2+ verified 105.4 and 165.6 mg/g, respectively within 120 minutes for the unmodified eggshell, which enhanced to 129.7 and 181.3 mg/g, respectively, for the modified eggshell. Different parameters were studied such as initial iron concentration in wastewater, agitation speed and the mass of the biosorbent. The isotherm study revealed that the data well fitted for linearized forms of Langmuir. The kinetic study followed the pseudo-second order reaction rate.},
 year = {2017}
}

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TY  - JOUR
T1  - Equilibrium and Kinetic Studies on Biosorption of Iron (II) and Iron (III) Ions onto Eggshell Powder from Aqueous Solution
AU  - Eman Aly Ashour
AU  - Maha Abdelbaset Tony
Y1  - 2017/06/02
PY  - 2017
N1  - https://doi.org/10.11648/j.ae.20170101.14
DO  - 10.11648/j.ae.20170101.14
T2  - Applied Engineering
JF  - Applied Engineering
JO  - Applied Engineering
SP  - 32
EP  - 40
PB  - Science Publishing Group
SN  - 2994-7456
UR  - https://doi.org/10.11648/j.ae.20170101.14
AB  - As a consequence of modernization, industry is spread in the whole world, one of the industries that producing a wastewater as a by-product, iron and steel industry. The result is a huge amount of wastewater that contaminated with iron and steel. Biosorption techniques especially with a natural low cost adsorbent material, namely chicken eggshell is gaining an important goal for treating with a cost efficient material. This present investigation, eggshell (untreated natural eggshell and the treated one which is burned to 500°C) was applied for two types of iron removal from wastewater (Fe2+ and Fe3+). The adsorption capacity of Fe3+ and Fe2+ verified 105.4 and 165.6 mg/g, respectively within 120 minutes for the unmodified eggshell, which enhanced to 129.7 and 181.3 mg/g, respectively, for the modified eggshell. Different parameters were studied such as initial iron concentration in wastewater, agitation speed and the mass of the biosorbent. The isotherm study revealed that the data well fitted for linearized forms of Langmuir. The kinetic study followed the pseudo-second order reaction rate.
VL  - 1
IS  - 1
ER  -

Copy | Download