Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent

Vijayarani Allam; Sailaja Budati Bala Venkata; Sirisha David

doi:doi:10.11648/j.ajcbe.20210501.14

| Peer-Reviewed

Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent

Vijayarani Allam, Sailaja Budati Bala Venkata, Sirisha David

Published in American Journal of Chemical and Biochemical Engineering (Volume 5, Issue 1)

Received: 4 May 2021 Accepted: 21 May 2021 Published: 27 May 2021

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

This research study focuses at the use of fenugreek seed powder as a bio adsorbent for removing arsenic from aqueous media. Metal biosorption research on Fenugreek seed powder has been studied in just a few studies. SEM, FTIR, and XRD were used to investigate the constituents and properties of fenugreek seed powder, which revealed the constituents and properties that enabled the arsenic biosorption process to succeed. To investigate the strength of arsenic adsorption using Fenugreek seed powder as a bioadsorbent, the effects of primary parameters including contact time, dose, concentration, pH, and temperature were used. The report of these parameters suggested that as the parameters increased, the efficient removal of arsenic increased until equilibrium was reached, but no successful results were seen after gaining the equilibrium. The biosorption process to Freundlich isotherm and pseudo kinetic order in liner form with better correlation coefficients was verified by a survey of biosorption isotherms and kinetic results. The system was endothermic, random, and favourable with biosorption characteristics at various temperatures, as determined by the thermodynamic constants. As a result of these findings, fenugreek seed powder has been modified for arsenic adsorption.

Published in	American Journal of Chemical and Biochemical Engineering (Volume 5, Issue 1)
DOI	10.11648/j.ajcbe.20210501.14
Page(s)	26-31
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

Arsenic, Fenugreek, Biosorption, Isotherms, Kinetic Order, Thermodynamics

References

[1]	Ishinishi N, Tsuchiya K, Vahter M, Fowler BA (1986) Handbook on the Toxicology of Metals. Elsevier, Amsterdam. Google Scholar.
[2]	IARC (1982) Evaluation of the Carcinogenic Risk of Chemicals to Humans, Industrial Processes and Industries Associated with Cancer in Human. International Agency for Research on Cancer, Lyon. Google Scholar.
[3]	ATSDR (2000) Toxicological Profile for Arsenic (update). U.S. Department of Health and Human Services, Atlanta. Google Scholar.
[4]	IPCS (2001) Environmental Health Criteria 224. Arsenic and Arsenic Compounds, 2nd Ed. World Health Organization, Geneva. Google Scholar.
[5]	Chatterjee. S, Variyar. S. P, Sharma. A, (2010), Bioactive lipid constituents of fenugreek Food Chem., 119, pp. 349-353.
[6]	Deepa Basrur and Ishwara Bhat. J, (2017), “Activated Carbon from Fenugreek Seed: Characterization and Dyes Adsorption Properties”. Iranian Journal of Energy & Environment Journal, Homepage: www.ijee.net.
[7]	Dhaif-Allah MAH, Taqui SN, Syed UT, Syed AA (2019) Development of sustainable acid blue 113 dye adsorption system using nutraceutical industrial Tribulus terrestrisspent. SN Appl. Sci 1 (4): 330.
[8]	Mohammed A. H. Dhaif-Allah, Syed Noeman Taqui, Usman Taqui Syed, Akheel Ahmed Syed. (2020). “Kinetic and isotherm modeling for acidblue113 dye adsorption onto low-cost nutraceutical industrial fenugreek seed spent” Applied Water Science 10: 58 https://doi.org/10.1007/s13201-020-1141-3.
[9]	Gupta. S. S, and Bhattacharyya, K. G, (2008), “Immobilization of Pb(II), Cd(II) and Ni(II) ions on kaolinite and montmorillonite surfaces from aqueous medium, ” Journal of Environmental Management, vol. 87, no. 1, pp. 46–58. View at: Publisher Site \| Google Scholar.
[10]	Kannan, N. and Veemaraj, T., (2009). Removal of Lead (II) Ions by Adsorption onto Bamboo Dust and Commercial Activated Carbons–a comparative Study. E-Journal of Chemistry, 6 (2): 247–56, Available at: http://www.e-journals.net [Accessed 19 August 2011].
[11]	Nomanbhay, S. M. and Palanisamy, K, (2005). Removal of heavy metal from industrial wastewater using chitosan coated oil palm shell charcoal. Electronic Journal of Biotechnology, Available at: http://www.ejbiotechnology.info/content/vol8/issue1/full/7/ [Accessed 4April 2011].
[12]	Asma Saeed, Mehwish Sharif, Muhammad Iqbal, (2010), Application potential of grape fruit peel as dye adsorbent: Kinetics, equilibrium and mechanism of crystal violet adsorption, Journal of Hazardous Materials. 179: 564-572.
[13]	Maedeh Mohammadi, Ali J. Hassani, Abdul Rahman Mohamed and Ghasem D. Najafpur, (2010), Removal of Rhodamine B from aqueous solution using palm shell based activated carbon: Adsorption and kinetic studies. Journal of Chemical and Engineering Data. 55: 5777–5785.
[14]	Sharma, Y. C, (2011), Adsorption characteristics of a low-cost activated carbon for the reclamation of coloured effluents containing malachite Green. Journal of Chemical and Engineering Data. 56: 478–484.
[15]	Ravindra Kumar Gautam, Ackmez Mudhoo, Mahesh Chandra Chattopadhya, (2013), Kinetic, equilibrium, thermodynamic studies and spectroscopic analysis of Alizarin Red S by removal by mustard husk. Journal of environmental Chemical Engineering. 1: 1283-1291.
[16]	Eftekhari, S. Habibi–Yangjeh, A., Sohrabnezhad. S., (2010), Application of AIMCM-41 for competitive adsorption of methylene blue and rhodamine B: Thermodynmic and Kinetic studies. Journal of Hazardous Materials. 178 (1-3): 349-355.
[17]	Yu Liu, (2009), Is the free energy change of Adsorption correctly calculated? Journal of Chemical and Engineering Data. 54: 1981-1985.
[18]	Yu Liu, Hui Xu, (2007), Equilibrium thermodynamics and mechanism of Ni²⁺ biosorption by aerobic granules, Biochemical Engineering Journal 35: 174-182.
[19]	Ramakrishanan. K, Namasivayam. C, (2011), Zinc chloride activated jatropha husk carbon for removal of phenol from water by adsorption; equilibrium and kinetic studies. Toxicology Environmental Chemistry 93 (6): 1111-1122.

Cite This Article

Plain Text BibTeX RIS

APA Style

Vijayarani Allam, Sailaja Budati Bala Venkata, Sirisha David. (2021). Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent. American Journal of Chemical and Biochemical Engineering, 5(1), 26-31. https://doi.org/10.11648/j.ajcbe.20210501.14

Copy | Download

ACS Style

Vijayarani Allam; Sailaja Budati Bala Venkata; Sirisha David. Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent. Am. J. Chem. Biochem. Eng. 2021, 5(1), 26-31. doi: 10.11648/j.ajcbe.20210501.14

Copy | Download

AMA Style

Vijayarani Allam, Sailaja Budati Bala Venkata, Sirisha David. Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent. Am J Chem Biochem Eng. 2021;5(1):26-31. doi: 10.11648/j.ajcbe.20210501.14

Copy | Download

@article{10.11648/j.ajcbe.20210501.14,
  author = {Vijayarani Allam and Sailaja Budati Bala Venkata and Sirisha David},
  title = {Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent},
  journal = {American Journal of Chemical and Biochemical Engineering},
  volume = {5},
  number = {1},
  pages = {26-31},
  doi = {10.11648/j.ajcbe.20210501.14},
  url = {https://doi.org/10.11648/j.ajcbe.20210501.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajcbe.20210501.14},
  abstract = {This research study focuses at the use of fenugreek seed powder as a bio adsorbent for removing arsenic from aqueous media. Metal biosorption research on Fenugreek seed powder has been studied in just a few studies. SEM, FTIR, and XRD were used to investigate the constituents and properties of fenugreek seed powder, which revealed the constituents and properties that enabled the arsenic biosorption process to succeed. To investigate the strength of arsenic adsorption using Fenugreek seed powder as a bioadsorbent, the effects of primary parameters including contact time, dose, concentration, pH, and temperature were used. The report of these parameters suggested that as the parameters increased, the efficient removal of arsenic increased until equilibrium was reached, but no successful results were seen after gaining the equilibrium. The biosorption process to Freundlich isotherm and pseudo kinetic order in liner form with better correlation coefficients was verified by a survey of biosorption isotherms and kinetic results. The system was endothermic, random, and favourable with biosorption characteristics at various temperatures, as determined by the thermodynamic constants. As a result of these findings, fenugreek seed powder has been modified for arsenic adsorption.},
 year = {2021}
}

Copy | Download

TY  - JOUR
T1  - Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent
AU  - Vijayarani Allam
AU  - Sailaja Budati Bala Venkata
AU  - Sirisha David
Y1  - 2021/05/27
PY  - 2021
N1  - https://doi.org/10.11648/j.ajcbe.20210501.14
DO  - 10.11648/j.ajcbe.20210501.14
T2  - American Journal of Chemical and Biochemical Engineering
JF  - American Journal of Chemical and Biochemical Engineering
JO  - American Journal of Chemical and Biochemical Engineering
SP  - 26
EP  - 31
PB  - Science Publishing Group
SN  - 2639-9989
UR  - https://doi.org/10.11648/j.ajcbe.20210501.14
AB  - This research study focuses at the use of fenugreek seed powder as a bio adsorbent for removing arsenic from aqueous media. Metal biosorption research on Fenugreek seed powder has been studied in just a few studies. SEM, FTIR, and XRD were used to investigate the constituents and properties of fenugreek seed powder, which revealed the constituents and properties that enabled the arsenic biosorption process to succeed. To investigate the strength of arsenic adsorption using Fenugreek seed powder as a bioadsorbent, the effects of primary parameters including contact time, dose, concentration, pH, and temperature were used. The report of these parameters suggested that as the parameters increased, the efficient removal of arsenic increased until equilibrium was reached, but no successful results were seen after gaining the equilibrium. The biosorption process to Freundlich isotherm and pseudo kinetic order in liner form with better correlation coefficients was verified by a survey of biosorption isotherms and kinetic results. The system was endothermic, random, and favourable with biosorption characteristics at various temperatures, as determined by the thermodynamic constants. As a result of these findings, fenugreek seed powder has been modified for arsenic adsorption.
VL  - 5
IS  - 1
ER  -

Copy | Download

Author Information

Vijayarani Allam

Department of Inorganic and Analytical Chemistry, Andhra University, Visakhapatnam, India
Sailaja Budati Bala Venkata

Department of Inorganic and Analytical Chemistry, Andhra University, Visakhapatnam, India
Sirisha David

Department of Chemistry, St. Ann’s Degree College for Women, Osmania University, Hyderabad, India

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Vijayarani Allam, Sailaja Budati Bala Venkata, Sirisha David. (2021). Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent. American Journal of Chemical and Biochemical Engineering, 5(1), 26-31. https://doi.org/10.11648/j.ajcbe.20210501.14

Copy | Download

ACS Style

Vijayarani Allam; Sailaja Budati Bala Venkata; Sirisha David. Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent. Am. J. Chem. Biochem. Eng. 2021, 5(1), 26-31. doi: 10.11648/j.ajcbe.20210501.14

Copy | Download

AMA Style

Vijayarani Allam, Sailaja Budati Bala Venkata, Sirisha David. Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent. Am J Chem Biochem Eng. 2021;5(1):26-31. doi: 10.11648/j.ajcbe.20210501.14

Copy | Download

@article{10.11648/j.ajcbe.20210501.14,
  author = {Vijayarani Allam and Sailaja Budati Bala Venkata and Sirisha David},
  title = {Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent},
  journal = {American Journal of Chemical and Biochemical Engineering},
  volume = {5},
  number = {1},
  pages = {26-31},
  doi = {10.11648/j.ajcbe.20210501.14},
  url = {https://doi.org/10.11648/j.ajcbe.20210501.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajcbe.20210501.14},
  abstract = {This research study focuses at the use of fenugreek seed powder as a bio adsorbent for removing arsenic from aqueous media. Metal biosorption research on Fenugreek seed powder has been studied in just a few studies. SEM, FTIR, and XRD were used to investigate the constituents and properties of fenugreek seed powder, which revealed the constituents and properties that enabled the arsenic biosorption process to succeed. To investigate the strength of arsenic adsorption using Fenugreek seed powder as a bioadsorbent, the effects of primary parameters including contact time, dose, concentration, pH, and temperature were used. The report of these parameters suggested that as the parameters increased, the efficient removal of arsenic increased until equilibrium was reached, but no successful results were seen after gaining the equilibrium. The biosorption process to Freundlich isotherm and pseudo kinetic order in liner form with better correlation coefficients was verified by a survey of biosorption isotherms and kinetic results. The system was endothermic, random, and favourable with biosorption characteristics at various temperatures, as determined by the thermodynamic constants. As a result of these findings, fenugreek seed powder has been modified for arsenic adsorption.},
 year = {2021}
}

Copy | Download

TY  - JOUR
T1  - Arsenic (III) Biosorption with Fenugreek (Methi) Seed Powder as a Low-cost Biosorbent
AU  - Vijayarani Allam
AU  - Sailaja Budati Bala Venkata
AU  - Sirisha David
Y1  - 2021/05/27
PY  - 2021
N1  - https://doi.org/10.11648/j.ajcbe.20210501.14
DO  - 10.11648/j.ajcbe.20210501.14
T2  - American Journal of Chemical and Biochemical Engineering
JF  - American Journal of Chemical and Biochemical Engineering
JO  - American Journal of Chemical and Biochemical Engineering
SP  - 26
EP  - 31
PB  - Science Publishing Group
SN  - 2639-9989
UR  - https://doi.org/10.11648/j.ajcbe.20210501.14
AB  - This research study focuses at the use of fenugreek seed powder as a bio adsorbent for removing arsenic from aqueous media. Metal biosorption research on Fenugreek seed powder has been studied in just a few studies. SEM, FTIR, and XRD were used to investigate the constituents and properties of fenugreek seed powder, which revealed the constituents and properties that enabled the arsenic biosorption process to succeed. To investigate the strength of arsenic adsorption using Fenugreek seed powder as a bioadsorbent, the effects of primary parameters including contact time, dose, concentration, pH, and temperature were used. The report of these parameters suggested that as the parameters increased, the efficient removal of arsenic increased until equilibrium was reached, but no successful results were seen after gaining the equilibrium. The biosorption process to Freundlich isotherm and pseudo kinetic order in liner form with better correlation coefficients was verified by a survey of biosorption isotherms and kinetic results. The system was endothermic, random, and favourable with biosorption characteristics at various temperatures, as determined by the thermodynamic constants. As a result of these findings, fenugreek seed powder has been modified for arsenic adsorption.
VL  - 5
IS  - 1
ER  -

Copy | Download