Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology

Tahereh Taherzadeh Lari; Hamid Reza Bozorgzadeh; Hossein Atashi; Abdol Mahmood Davarpanah; Ali Akbar Mirzaei

doi:doi:10.11648/j.ajche.20190702.13

| Peer-Reviewed

Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology

Tahereh Taherzadeh Lari, Hamid Reza Bozorgzadeh, Hossein Atashi, Abdol Mahmood Davarpanah, Ali Akbar Mirzaei

Published in American Journal of Chemical Engineering (Volume 7, Issue 2)

Received: 29 May 2019 Accepted: 1 July 2019 Published: 12 July 2019

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

The Fe-Co-Ce nanocatalyst was synthesized by a solvothermal method and used in Fischer-Tropsch synthesis. This paper represents a statistical analysis to illustrate the effects of oleylamine concentration and operating variables (temperature, pressure, inlet H₂/CO molar ratio) on light olefin (C₂⁼-C₄⁼), paraffin (C₁ + C₂-C₄) selectivity and CO conversion (catalyst activity) in a fixed bed micro reactor was done. In order to evaluate variable effects, analysis of variance (ANOVA) was applied for modeling and optimization of goal products using response surface methodology (RSM). The result showed that by increasing both amine concentration and pressure at lower temperature and inlet H₂/CO molar ratio, olefin selectivity and CO conversion rises, while paraffin selectivity reduces. Comparison of optimization results to maximum olefin selectivity and CO conversion and minimum paraffin selectivity for predicted and experimental data indicate a desirable agreement.

Published in	American Journal of Chemical Engineering (Volume 7, Issue 2)
DOI	10.11648/j.ajche.20190702.13
Page(s)	71-80
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

"Fischer-Tropsch Synthesis, Response Surface Methodology, Optimization, Fe-Co-Ce Nanocatalyst, Oleylamine Concentration, Operating Conditions "

References

[1]	A. Shamil Albazzaz, A. Ghassan Alsultan, S. Ali, Y. H. Taufiq-Yaq, M. A. Mohd Salleh, W. A. W. A. K. Ghani, Crbon Monoxide Hydrogenation on Activated Carbon Supported Co-Ni Bimetallic Catalysts Via Fischer-Tropsch Reaction to Produce Gasoline, Journal of Energy, Environmental & Chemical Engineering, 3 (2018) 40-53.
[2]	U. P. M. Ashik, A. Viswan, Sh. Kudo, J-I. Hayashi, Nanomaterials as Catalysts, Applications of Nanomaterials, 2018, https://doi.org/10.1016/B978-0-08-101971-9.00003-X.
[3]	H. Pan, L. Wang, Sh. He, J. Wang, Improvement of Sol-gel Method and Influence of Calcination Conditions on Properties of MnOx-CeOx/WO₃/TiO₂-ZrO₂ Catalyst, Science Discovery, 5 (2017) 463-468.
[4]	M. Abdouss, M. Arsalanfar, N. Mirzaei, and Y. Zamani, "Effect of Drying Conditions on the Catalytic Performance, Structure, and Reaction Rates over the Fe-Co-Mn/MgO Catalyst for Production of Light Olefins," Bulletin of Chemical Reaction Engineering & Catalysis, vol. 13, no. 1, pp. 97-112, Apr. 2018. https://doi.org/10.9767/bcrec.13.1.1222.97-112
[5]	A. Guerrero-Ruiz, A. Sepulveda-Escribano, I. Rodriguez-Ramos, Mangesium, vanadium and cerium oxides. Appl Catal A, 1994, 120, 71.
[6]	C. Perego, P. Villa, Catalyst preparation methods, Chapter 3, Catalysis Today 34 (1997) 281-305.
[7]	M. Shakouri-Arani, M. Salavati-Niasari, Synthesis and characterization of wurtzite ZnS nanoplates through simple solvothermal method with a novel approach, J. Ind. Eng. Chem, 20 (2014) 3179-3185.
[8]	S. Peng, C. Wang, J. Xie, S. Sun, Synthesis and stabilization of monodisperse Fe nanoparticles, J. Am. Chem. Soc, 128 (2006) 10676-10677.
[9]	A. D. Ostrowski, E. M. Chan, D. J. Gargas, E. M. Katz, G. Han, P. J. Schuck, D. J. Milliron, B. E. Cohen, controlled synthesis and single-particle Imaging of Bright, Sub-10 nm Lanthanide-Doped Upconverting Nanocrystals, ACS Nano, 6 (2012) 2686-2692.
[10]	Fermoso, J.; Gil, M. V.; Arias, B.; Plaza, M. G.; Pevida, C.; Pis, J. J.; Rubiera, F. Application of response surface methodology to assess the combined effect of operating variables on high-pressure coal gasification for H2-rich gas production. Int. J. Hydrogen Energy 2010, 35, 1191.
[11]	Y. Zhang, L. Ma, T. Wang, X. Li, Synthesis of Ag promoted porous Fe₃O₄ microspheres with tunable pore size as catalysts for Fischer-Tropsch production of lower olefins, Catal. Commun, 64 (2015) 32-36.
[12]	J. Tu, M. Ding, Y. Zhang, Y. Li, T. Wang, L. Ma, CH. Wang, X. Li, Synthesis of Fe₃O₄-nanocatalysts with different morphologies and its promotion on shifting C₅⁺ hydrocarbons for Fischer-Tropsch synthesis, Catal. Commun, 59 (2015) 211-215.
[13]	Gunaraj, V.; Murugan, N. Application of response surface methodologies for predicting weld base quality in submerged arc welding of pipes. J. Mater. Process. Technol. 1999, 88, 266.
[14]	H. Atashi, F. Rezaeian, Modelling and optimization of Fischer-Tropsch products through iron catalyst in fixed-bed reactor, Int. J. Hyd. Eng.
[15]	Y. Sun, J. Wei, J. Ping Zhang, G. Yang, Optimization using respoce surface methodology and kinetic study of Fischer-Tropsch synthesis using SiO2 supported bimetallic Co-Ni catalyst, J. Nat. Gas. Sci & Eng. 28 (2016) 173-183.

Cite This Article

Plain Text BibTeX RIS

APA Style

Tahereh Taherzadeh Lari, Hamid Reza Bozorgzadeh, Hossein Atashi, Abdol Mahmood Davarpanah, Ali Akbar Mirzaei. (2019). Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology. American Journal of Chemical Engineering, 7(2), 71-80. https://doi.org/10.11648/j.ajche.20190702.13

Copy | Download

ACS Style

Tahereh Taherzadeh Lari; Hamid Reza Bozorgzadeh; Hossein Atashi; Abdol Mahmood Davarpanah; Ali Akbar Mirzaei. Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology. Am. J. Chem. Eng. 2019, 7(2), 71-80. doi: 10.11648/j.ajche.20190702.13

Copy | Download

AMA Style

Tahereh Taherzadeh Lari, Hamid Reza Bozorgzadeh, Hossein Atashi, Abdol Mahmood Davarpanah, Ali Akbar Mirzaei. Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology. Am J Chem Eng. 2019;7(2):71-80. doi: 10.11648/j.ajche.20190702.13

Copy | Download

@article{10.11648/j.ajche.20190702.13,
  author = {Tahereh Taherzadeh Lari and Hamid Reza Bozorgzadeh and Hossein Atashi and Abdol Mahmood Davarpanah and Ali Akbar Mirzaei},
  title = {Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology},
  journal = {American Journal of Chemical Engineering},
  volume = {7},
  number = {2},
  pages = {71-80},
  doi = {10.11648/j.ajche.20190702.13},
  url = {https://doi.org/10.11648/j.ajche.20190702.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20190702.13},
  abstract = {The Fe-Co-Ce nanocatalyst was synthesized by a solvothermal method and used in Fischer-Tropsch synthesis. This paper represents a statistical analysis to illustrate the effects of oleylamine concentration and operating variables (temperature, pressure, inlet H2/CO molar ratio) on light olefin (C2=-C4=), paraffin (C1 + C2-C4) selectivity and CO conversion (catalyst activity) in a fixed bed micro reactor was done. In order to evaluate variable effects, analysis of variance (ANOVA) was applied for modeling and optimization of goal products using response surface methodology (RSM). The result showed that by increasing both amine concentration and pressure at lower temperature and inlet H2/CO molar ratio, olefin selectivity and CO conversion rises, while paraffin selectivity reduces. Comparison of optimization results to maximum olefin selectivity and CO conversion and minimum paraffin selectivity for predicted and experimental data indicate a desirable agreement.},
 year = {2019}
}

Copy | Download

TY  - JOUR
T1  - Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology
AU  - Tahereh Taherzadeh Lari
AU  - Hamid Reza Bozorgzadeh
AU  - Hossein Atashi
AU  - Abdol Mahmood Davarpanah
AU  - Ali Akbar Mirzaei
Y1  - 2019/07/12
PY  - 2019
N1  - https://doi.org/10.11648/j.ajche.20190702.13
DO  - 10.11648/j.ajche.20190702.13
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 71
EP  - 80
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20190702.13
AB  - The Fe-Co-Ce nanocatalyst was synthesized by a solvothermal method and used in Fischer-Tropsch synthesis. This paper represents a statistical analysis to illustrate the effects of oleylamine concentration and operating variables (temperature, pressure, inlet H2/CO molar ratio) on light olefin (C2=-C4=), paraffin (C1 + C2-C4) selectivity and CO conversion (catalyst activity) in a fixed bed micro reactor was done. In order to evaluate variable effects, analysis of variance (ANOVA) was applied for modeling and optimization of goal products using response surface methodology (RSM). The result showed that by increasing both amine concentration and pressure at lower temperature and inlet H2/CO molar ratio, olefin selectivity and CO conversion rises, while paraffin selectivity reduces. Comparison of optimization results to maximum olefin selectivity and CO conversion and minimum paraffin selectivity for predicted and experimental data indicate a desirable agreement.
VL  - 7
IS  - 2
ER  -

Copy | Download

Author Information

Tahereh Taherzadeh Lari

Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, Zahedan, Iran
Hamid Reza Bozorgzadeh

Catalyst Division, Research Institute of Petroleum Industry (RIPI), Tehran, Iran
Hossein Atashi

Department of Chemical Engineering, Faculty of Engineering, University of Sistan and Baluchestan, Zahedan, Iran
Abdol Mahmood Davarpanah

Department of Physics, Faculty of Science, University of Sistan and Baluchestan, Zahedan, Iran
Ali Akbar Mirzaei

Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, Zahedan, Iran

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Tahereh Taherzadeh Lari, Hamid Reza Bozorgzadeh, Hossein Atashi, Abdol Mahmood Davarpanah, Ali Akbar Mirzaei. (2019). Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology. American Journal of Chemical Engineering, 7(2), 71-80. https://doi.org/10.11648/j.ajche.20190702.13

Copy | Download

ACS Style

Tahereh Taherzadeh Lari; Hamid Reza Bozorgzadeh; Hossein Atashi; Abdol Mahmood Davarpanah; Ali Akbar Mirzaei. Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology. Am. J. Chem. Eng. 2019, 7(2), 71-80. doi: 10.11648/j.ajche.20190702.13

Copy | Download

AMA Style

Tahereh Taherzadeh Lari, Hamid Reza Bozorgzadeh, Hossein Atashi, Abdol Mahmood Davarpanah, Ali Akbar Mirzaei. Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology. Am J Chem Eng. 2019;7(2):71-80. doi: 10.11648/j.ajche.20190702.13

Copy | Download

@article{10.11648/j.ajche.20190702.13,
  author = {Tahereh Taherzadeh Lari and Hamid Reza Bozorgzadeh and Hossein Atashi and Abdol Mahmood Davarpanah and Ali Akbar Mirzaei},
  title = {Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology},
  journal = {American Journal of Chemical Engineering},
  volume = {7},
  number = {2},
  pages = {71-80},
  doi = {10.11648/j.ajche.20190702.13},
  url = {https://doi.org/10.11648/j.ajche.20190702.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20190702.13},
  abstract = {The Fe-Co-Ce nanocatalyst was synthesized by a solvothermal method and used in Fischer-Tropsch synthesis. This paper represents a statistical analysis to illustrate the effects of oleylamine concentration and operating variables (temperature, pressure, inlet H2/CO molar ratio) on light olefin (C2=-C4=), paraffin (C1 + C2-C4) selectivity and CO conversion (catalyst activity) in a fixed bed micro reactor was done. In order to evaluate variable effects, analysis of variance (ANOVA) was applied for modeling and optimization of goal products using response surface methodology (RSM). The result showed that by increasing both amine concentration and pressure at lower temperature and inlet H2/CO molar ratio, olefin selectivity and CO conversion rises, while paraffin selectivity reduces. Comparison of optimization results to maximum olefin selectivity and CO conversion and minimum paraffin selectivity for predicted and experimental data indicate a desirable agreement.},
 year = {2019}
}

Copy | Download

TY  - JOUR
T1  - Effect of Oleylamine Concentration and Operating Conditions on Ternary Nanocatalyst for Fischer-Tropsch Synthesis Using Response Surface Methodology
AU  - Tahereh Taherzadeh Lari
AU  - Hamid Reza Bozorgzadeh
AU  - Hossein Atashi
AU  - Abdol Mahmood Davarpanah
AU  - Ali Akbar Mirzaei
Y1  - 2019/07/12
PY  - 2019
N1  - https://doi.org/10.11648/j.ajche.20190702.13
DO  - 10.11648/j.ajche.20190702.13
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 71
EP  - 80
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20190702.13
AB  - The Fe-Co-Ce nanocatalyst was synthesized by a solvothermal method and used in Fischer-Tropsch synthesis. This paper represents a statistical analysis to illustrate the effects of oleylamine concentration and operating variables (temperature, pressure, inlet H2/CO molar ratio) on light olefin (C2=-C4=), paraffin (C1 + C2-C4) selectivity and CO conversion (catalyst activity) in a fixed bed micro reactor was done. In order to evaluate variable effects, analysis of variance (ANOVA) was applied for modeling and optimization of goal products using response surface methodology (RSM). The result showed that by increasing both amine concentration and pressure at lower temperature and inlet H2/CO molar ratio, olefin selectivity and CO conversion rises, while paraffin selectivity reduces. Comparison of optimization results to maximum olefin selectivity and CO conversion and minimum paraffin selectivity for predicted and experimental data indicate a desirable agreement.
VL  - 7
IS  - 2
ER  -

Copy | Download