On Novel Aspects of Hydrogen Effects on Applied Stress - Coupled Micromagnetic Activity in a Mild Steel After Exposure to NaCl – Water Solution: A Combined Approach

Victor Kytopoulos; Alexandros Altzoumailis

doi:doi:10.11648/j.ajche.20210905.12

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On Novel Aspects of Hydrogen Effects on Applied Stress - Coupled Micromagnetic Activity in a Mild Steel After Exposure to NaCl – Water Solution: A Combined Approach

Victor Kytopoulos, Alexandros Altzoumailis

Published in American Journal of Chemical Engineering (Volume 9, Issue 5)

Received: 13 March 2021 Accepted: 27 March 2021 Published: 30 October 2021

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Abstract

Hydrogen produced after exposure of a low – carbon steel to corrosive NaCl – Water solution may affect various its tensile mechanical and magnetic microstructural behaviour in a complex manner. This was investigated by introducing a relevant micromagnetic specific emission (ME) - response of this ferromagnetic material, where related processes and parameters of micromagnetic activity and mechanical response were implemented. In this manner, it was demonstrated that an increase in the hydrogen accumulation with corrosion time leads to an associated increase in the embrittling effect expressed by a substantial loss in the ductility of material. The competive and opposing effects of cumulative hydrogen, applied stress and plastic strain – induced microstructural damage were related to the specific ME- response parameter by which an increased magnetic hardening tendency of material with corrosion time was possible to establish. In this fashion and by using a stress as well as strain mode of presentation- aided combined approach, the complex interplay between micromagnetic activity, hydrogen accumulation and applied stress-strain was better revieled and analysed. It was also shown that the embrittlement is a product of hydrogen accumulation introduced by two highly localized processes. As such, accumulation occurs in two characteristic parallel ways: one of a common lattice diffusion and one of hydrogen transport and redistribution by moving dislocation towards the affected sites. Concerning the highly localized effects the dominating role of hydrogen – induced damage in form void initiation and growth over the hydrogen – assisted stress relief was reasonably demonstrated by using a simple modelling approach. Based on a mechanism of moving dislocation – assisted interaction between commulative hydrogen and magnetic domain walls, a Portervin – Le Chatelier – type micromagnetic process of a cooperative-corelated domain wall transport was proposed to explain certain subtle, quasiperiodic behaviour of ME- response. In the frame of the above findings the superior sensivity of ME – response compared to the mechanical one in early detecting cumulative hydrogen – assisted microstructural damage changes can be d educed.

Published in	American Journal of Chemical Engineering (Volume 9, Issue 5)
DOI	10.11648/j.ajche.20210905.12
Page(s)	119-133
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2021. Published by Science Publishing Group

Keywords

J - Parameter, Hydrogen, Embrittlement, Void, Domain Wall, Pinning Strength, Dislocation, Stress- Strain

References

[1]	H. Möller, E. T. Boshoff and H. Froneman; “The corrosion behavior of low carbon steel in natural and synthetic seawaters” The Journal of South African Institute of Mining and Metallurgy, Vol. 106, p. 585 – 592, 2006.
[2]	A. W. Thomson and I. M. Bernstein, Advances in corrosion Science and Technology, vol. 17, R. W. staehle and M. G. Fontana, Eds. Plenum, New York, 1980, p. 53.
[3]	Jingwei Zhao, Young Soo Chun and Cong Soo Lee; “Hydrogen embrittlement of low carbon steel during slow strain rate Test” Advanced Materials Research, Vols. 197 – 198, p. 642 – 645, 2011.
[4]	A. K. Das, “Metallurgy of Failure Analysis”, Mc Graw – Hill, 1996.
[5]	C. L. Briant, “Metallurgical Aspects of Environmental Failures”, Materials Science Monographs, Vol 12, Elsevier, 1985.
[6]	R. W. Hertzberg “Deformation and Fracture Mechanics of engineering materials” 3d Ed., Willey, 1989.
[7]	D. O. Hagard and B. M. Trapnell, “Chemisorption”, 2d Ed. Butterworth, Washington, DC, 1964.
[8]	T. Alan Place, T. Srinivas Sudarhan, Cindy K. Waters and M. R. Louthan, Jr. “Fractographic Studies of the ductile – to – brittle Transition in Austenitic stainless steels”, in Fractography of Modern engineering materials: Composites and Metals, Editors Masters, J and Au, J, ASTM 1987, p 350 – 365.
[9]	Yoneo Kikuta, Takao Araki and Toshio Kuroda, “Analysis of Fracture Morphology of Hydrogen – assisted Cracking in steel and its Welds” in Fractography in Failure Analysis, ASTM STP 645, B. M. Strauss and W. H. Cullen, Jr. eds 1978, p 107 – 127.
[10]	R. P. Gangloff and R. P. Wei:” Fractographic analysis of gaseous hydrogen induced cracking in 18 N Maraging steel”, in Fractography and Failure Analysis, Strauss/ Culler, Eds., ASTM-STP, 645, p 87-106, (1978).
[11]	HG. R. Caskey, Jr.: “Hydrogen- induced brittle fracture of Type 304 L. Austentic stainless steel” in “Fractography and Materials Scince” Gilbertson/Zipp, Eds. ASTM-STP, 733, p 86-114, (1993).
[12]	V. Provenzano, K. T’orr’ohen, D. Sturm and W. H. Culler, “Fractographic and Microstructural Analysis of Stress-Corrosion Cracking of ASTM, A-533 Grade B-class1 plate and ASTM, A-508 class 2 forging in pressurized Reactor-grade Water 93C”, in Fractography and Materials Science, ASTM-STP-733, Gibbers ton /Zipp, Eds, 1981.
[13]	Mein, D. A. and Bayles, R. A. “ Fractographic Analysis of hydrogen-assisted cracking in Alpha – Beta Titanium alloys”, in Fractography of Modern Engineering Materials, Composites and Metals ASTM-STP 948, P400, Masters/Au, Eds. (1987).
[14]	West, A. J. and Hlbrook, J. H. in “Hydrogen effects in Metals”, I. M. Bernstein and A. W. Thomson, Eds. American Jnst. of Mining s Metallurgical and Petroleum Engineering, p. 607, New York, 1981.
[15]	Carber, R. and Bernstein, I. M. in “Environmental Degradation of Engineering Materials”, M. R. Louthan, Jr. and R. P. Mc Nitt, Eds., Virginia Polytechnic Institute, Blacksburg, VA, 1977, p. 463.
[16]	May L. Martin, Mohsen Dadfarnia, Akihide Nago, Shuai Wanag and Petros Sofronis “Enumeration of hydrogen – on hanced loclized plasticitg mechanisms for hydrogen embritzlement in structural steels” Acta Materialia, Vol. 156, February 2019, pp. 734-750.
[17]	Mohamad Blaow, Jahn Terence and Brian A. Shaw, “The effect of microstructure and applied stress on magnetic Barkhausen emission in induction hardened steel, J. Mat. Sci. Val 42, p. 4364-4371, (2007).
[18]	C. E. Stefanita, L. Clapham and D. L. Atherton, “Subtle changes in magnetic Barkhausen noise before the macroscopic elastic limit” J. Mat. sc. 35, p 2675-(2000).
[19]	P. Polukhin, S. Gorelic and V. Vorontsov, “Physical Principles of Plastic Deformation”, (in English), Mir Publishers, Moscow. 1983.
[20]	Thomas W. Krause, L. CLAPHAM, Andreas Pttantyus and Davied L. Atherton,” Investigation on the stress- dependent magnetic easy axis in steel using magnetic Barkhausen noise”. J. Appl. phys. Vol. 79 (8), 15 April 1996, p 4242-4252.
[21]	H. Träuble in “Moderne Probleme der Metallphysik”, A Seeger Ed. Springer Verlag 1966.
[22]	S. Chikazumi, Physics of Ferromagnetis, Oxford, Science Publications Reprint 2005.
[23]	A. Hubert and R. Schäfer: “Magnetic Domains: The Analysis of Magnetic Microstructure”, Springer, Corrected Printing 2000.
[24]	D. C. Jilles and D. L. Atherton, “Theory of the magnetization process in ferromagnets and its application to the magnetomechanical effect” J. Phys. D., 17 (1984), p. 1265 – 1281.
[25]	V. N. Kytopoulos, A. Altzoumailis, Chr. Panagopoulos, Chr. Riga. “Hydrogen influence on certain mechanical and magnetic properties of a stressed Low-Carbon Steel after Corrosion in NaCl-water solution”, Procedia Structural Integrity 26 (2020), p. p. 113-119. www.sciencedirect.com
[26]	D Gwang and H C Kim the influence of plastc deformations on Barkhausen effects and magnetic properties in mild steel Journal of Phys D applied physics, 1988 21 p 1807 – 1813.
[27]	Tadao Nozawa, Masato Mizogami, Hisai Mogi and Yukio Matsuo, ‘Domain structures and magnetic properties of advanced grain- oriented silicon steel” J. Magn. Mater. 133, (1994) p. 115-122.
[28]	E. K. Ioakeimidis, V. N. Kytopoulos, E. Hristoforou “Investigation of magnetic, mechanical and micro failure behavior of ARMCO – type low carbon steel corroded in 3.5%NaCl-aqueous solution” - Materials Science and Engineering: A, Volume 583, 2013, p 254-260.
[29]	J. Degauque, B. Astie and L. P. Kubin,”Evidence for Interaction between Magnetic domain walls and Dislocations in high-purity Iron from Magnetomechanical damping measurements.” Phys. state so. (a), 45, p 493-501 (1978).
[30]	Martha Pardavi-Horvath, “Magnetic Noise Barkhausen Effect “in Wiley Encyclopedia of Electrical and Electronic Engineering, Val. 12, p. 52-64, y. E. Webster Ed., 1999.

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APA Style

Victor Kytopoulos, Alexandros Altzoumailis. (2021). On Novel Aspects of Hydrogen Effects on Applied Stress - Coupled Micromagnetic Activity in a Mild Steel After Exposure to NaCl – Water Solution: A Combined Approach. American Journal of Chemical Engineering, 9(5), 119-133. https://doi.org/10.11648/j.ajche.20210905.12

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ACS Style

Victor Kytopoulos; Alexandros Altzoumailis. On Novel Aspects of Hydrogen Effects on Applied Stress - Coupled Micromagnetic Activity in a Mild Steel After Exposure to NaCl – Water Solution: A Combined Approach. Am. J. Chem. Eng. 2021, 9(5), 119-133. doi: 10.11648/j.ajche.20210905.12

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AMA Style

Victor Kytopoulos, Alexandros Altzoumailis. On Novel Aspects of Hydrogen Effects on Applied Stress - Coupled Micromagnetic Activity in a Mild Steel After Exposure to NaCl – Water Solution: A Combined Approach. Am J Chem Eng. 2021;9(5):119-133. doi: 10.11648/j.ajche.20210905.12

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@article{10.11648/j.ajche.20210905.12,
  author = {Victor Kytopoulos and Alexandros Altzoumailis},
  title = {On Novel Aspects of Hydrogen Effects on Applied Stress - Coupled Micromagnetic Activity in a Mild Steel After Exposure to NaCl – Water Solution: A Combined Approach},
  journal = {American Journal of Chemical Engineering},
  volume = {9},
  number = {5},
  pages = {119-133},
  doi = {10.11648/j.ajche.20210905.12},
  url = {https://doi.org/10.11648/j.ajche.20210905.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20210905.12},
  abstract = {Hydrogen produced after exposure of a low – carbon steel to corrosive NaCl – Water solution may affect various its tensile mechanical and magnetic microstructural behaviour in a complex manner. This was investigated by introducing a relevant micromagnetic specific emission (ME) - response of this ferromagnetic material, where related processes and parameters of micromagnetic activity and mechanical response were implemented. In this manner, it was demonstrated that an increase in the hydrogen accumulation with corrosion time leads to an associated increase in the embrittling effect expressed by a substantial loss in the ductility of material. The competive and opposing effects of cumulative hydrogen, applied stress and plastic strain – induced microstructural damage were related to the specific ME- response parameter by which an increased magnetic hardening tendency of material with corrosion time was possible to establish. In this fashion and by using a stress as well as strain mode of presentation- aided combined approach, the complex interplay between micromagnetic activity, hydrogen accumulation and applied stress-strain was better revieled and analysed. It was also shown that the embrittlement is a product of hydrogen accumulation introduced by two highly localized processes. As such, accumulation occurs in two characteristic parallel ways: one of a common lattice diffusion and one of hydrogen transport and redistribution by moving dislocation towards the affected sites. Concerning the highly localized effects the dominating role of hydrogen – induced damage in form void initiation and growth over the hydrogen – assisted stress relief was reasonably demonstrated by using a simple modelling approach. Based on a mechanism of moving dislocation – assisted interaction between commulative hydrogen and magnetic domain walls, a Portervin – Le Chatelier – type micromagnetic process of a cooperative-corelated domain wall transport was proposed to explain certain subtle, quasiperiodic behaviour of ME- response. In the frame of the above findings the superior sensivity of ME – response compared to the mechanical one in early detecting cumulative hydrogen – assisted microstructural damage changes can be d educed.},
 year = {2021}
}

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TY  - JOUR
T1  - On Novel Aspects of Hydrogen Effects on Applied Stress - Coupled Micromagnetic Activity in a Mild Steel After Exposure to NaCl – Water Solution: A Combined Approach
AU  - Victor Kytopoulos
AU  - Alexandros Altzoumailis
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PY  - 2021
N1  - https://doi.org/10.11648/j.ajche.20210905.12
DO  - 10.11648/j.ajche.20210905.12
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
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UR  - https://doi.org/10.11648/j.ajche.20210905.12
AB  - Hydrogen produced after exposure of a low – carbon steel to corrosive NaCl – Water solution may affect various its tensile mechanical and magnetic microstructural behaviour in a complex manner. This was investigated by introducing a relevant micromagnetic specific emission (ME) - response of this ferromagnetic material, where related processes and parameters of micromagnetic activity and mechanical response were implemented. In this manner, it was demonstrated that an increase in the hydrogen accumulation with corrosion time leads to an associated increase in the embrittling effect expressed by a substantial loss in the ductility of material. The competive and opposing effects of cumulative hydrogen, applied stress and plastic strain – induced microstructural damage were related to the specific ME- response parameter by which an increased magnetic hardening tendency of material with corrosion time was possible to establish. In this fashion and by using a stress as well as strain mode of presentation- aided combined approach, the complex interplay between micromagnetic activity, hydrogen accumulation and applied stress-strain was better revieled and analysed. It was also shown that the embrittlement is a product of hydrogen accumulation introduced by two highly localized processes. As such, accumulation occurs in two characteristic parallel ways: one of a common lattice diffusion and one of hydrogen transport and redistribution by moving dislocation towards the affected sites. Concerning the highly localized effects the dominating role of hydrogen – induced damage in form void initiation and growth over the hydrogen – assisted stress relief was reasonably demonstrated by using a simple modelling approach. Based on a mechanism of moving dislocation – assisted interaction between commulative hydrogen and magnetic domain walls, a Portervin – Le Chatelier – type micromagnetic process of a cooperative-corelated domain wall transport was proposed to explain certain subtle, quasiperiodic behaviour of ME- response. In the frame of the above findings the superior sensivity of ME – response compared to the mechanical one in early detecting cumulative hydrogen – assisted microstructural damage changes can be d educed.
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Author Information

Victor Kytopoulos

School of Applied Mathematical and Physical Sciences, National Technical University of Athens, Athens, Greece
Alexandros Altzoumailis

School of Chemical Engineering, National Technical University of Athens, Athens, Greece

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Victor Kytopoulos, Alexandros Altzoumailis. (2021). On Novel Aspects of Hydrogen Effects on Applied Stress - Coupled Micromagnetic Activity in a Mild Steel After Exposure to NaCl – Water Solution: A Combined Approach. American Journal of Chemical Engineering, 9(5), 119-133. https://doi.org/10.11648/j.ajche.20210905.12

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ACS Style

Victor Kytopoulos; Alexandros Altzoumailis. On Novel Aspects of Hydrogen Effects on Applied Stress - Coupled Micromagnetic Activity in a Mild Steel After Exposure to NaCl – Water Solution: A Combined Approach. Am. J. Chem. Eng. 2021, 9(5), 119-133. doi: 10.11648/j.ajche.20210905.12

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AMA Style

Victor Kytopoulos, Alexandros Altzoumailis. On Novel Aspects of Hydrogen Effects on Applied Stress - Coupled Micromagnetic Activity in a Mild Steel After Exposure to NaCl – Water Solution: A Combined Approach. Am J Chem Eng. 2021;9(5):119-133. doi: 10.11648/j.ajche.20210905.12

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@article{10.11648/j.ajche.20210905.12,
  author = {Victor Kytopoulos and Alexandros Altzoumailis},
  title = {On Novel Aspects of Hydrogen Effects on Applied Stress - Coupled Micromagnetic Activity in a Mild Steel After Exposure to NaCl – Water Solution: A Combined Approach},
  journal = {American Journal of Chemical Engineering},
  volume = {9},
  number = {5},
  pages = {119-133},
  doi = {10.11648/j.ajche.20210905.12},
  url = {https://doi.org/10.11648/j.ajche.20210905.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20210905.12},
  abstract = {Hydrogen produced after exposure of a low – carbon steel to corrosive NaCl – Water solution may affect various its tensile mechanical and magnetic microstructural behaviour in a complex manner. This was investigated by introducing a relevant micromagnetic specific emission (ME) - response of this ferromagnetic material, where related processes and parameters of micromagnetic activity and mechanical response were implemented. In this manner, it was demonstrated that an increase in the hydrogen accumulation with corrosion time leads to an associated increase in the embrittling effect expressed by a substantial loss in the ductility of material. The competive and opposing effects of cumulative hydrogen, applied stress and plastic strain – induced microstructural damage were related to the specific ME- response parameter by which an increased magnetic hardening tendency of material with corrosion time was possible to establish. In this fashion and by using a stress as well as strain mode of presentation- aided combined approach, the complex interplay between micromagnetic activity, hydrogen accumulation and applied stress-strain was better revieled and analysed. It was also shown that the embrittlement is a product of hydrogen accumulation introduced by two highly localized processes. As such, accumulation occurs in two characteristic parallel ways: one of a common lattice diffusion and one of hydrogen transport and redistribution by moving dislocation towards the affected sites. Concerning the highly localized effects the dominating role of hydrogen – induced damage in form void initiation and growth over the hydrogen – assisted stress relief was reasonably demonstrated by using a simple modelling approach. Based on a mechanism of moving dislocation – assisted interaction between commulative hydrogen and magnetic domain walls, a Portervin – Le Chatelier – type micromagnetic process of a cooperative-corelated domain wall transport was proposed to explain certain subtle, quasiperiodic behaviour of ME- response. In the frame of the above findings the superior sensivity of ME – response compared to the mechanical one in early detecting cumulative hydrogen – assisted microstructural damage changes can be d educed.},
 year = {2021}
}

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TY  - JOUR
T1  - On Novel Aspects of Hydrogen Effects on Applied Stress - Coupled Micromagnetic Activity in a Mild Steel After Exposure to NaCl – Water Solution: A Combined Approach
AU  - Victor Kytopoulos
AU  - Alexandros Altzoumailis
Y1  - 2021/10/30
PY  - 2021
N1  - https://doi.org/10.11648/j.ajche.20210905.12
DO  - 10.11648/j.ajche.20210905.12
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 119
EP  - 133
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20210905.12
AB  - Hydrogen produced after exposure of a low – carbon steel to corrosive NaCl – Water solution may affect various its tensile mechanical and magnetic microstructural behaviour in a complex manner. This was investigated by introducing a relevant micromagnetic specific emission (ME) - response of this ferromagnetic material, where related processes and parameters of micromagnetic activity and mechanical response were implemented. In this manner, it was demonstrated that an increase in the hydrogen accumulation with corrosion time leads to an associated increase in the embrittling effect expressed by a substantial loss in the ductility of material. The competive and opposing effects of cumulative hydrogen, applied stress and plastic strain – induced microstructural damage were related to the specific ME- response parameter by which an increased magnetic hardening tendency of material with corrosion time was possible to establish. In this fashion and by using a stress as well as strain mode of presentation- aided combined approach, the complex interplay between micromagnetic activity, hydrogen accumulation and applied stress-strain was better revieled and analysed. It was also shown that the embrittlement is a product of hydrogen accumulation introduced by two highly localized processes. As such, accumulation occurs in two characteristic parallel ways: one of a common lattice diffusion and one of hydrogen transport and redistribution by moving dislocation towards the affected sites. Concerning the highly localized effects the dominating role of hydrogen – induced damage in form void initiation and growth over the hydrogen – assisted stress relief was reasonably demonstrated by using a simple modelling approach. Based on a mechanism of moving dislocation – assisted interaction between commulative hydrogen and magnetic domain walls, a Portervin – Le Chatelier – type micromagnetic process of a cooperative-corelated domain wall transport was proposed to explain certain subtle, quasiperiodic behaviour of ME- response. In the frame of the above findings the superior sensivity of ME – response compared to the mechanical one in early detecting cumulative hydrogen – assisted microstructural damage changes can be d educed.
VL  - 9
IS  - 5
ER  -

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