Urban rivers are increasingly impacted by anthropogenic activities, leading to significant changes in water quality and pollutant levels. These rivers are subject to multiple environmental pressures, such as industrial discharge, urban runoff, and domestic wastewater, all of which affect the ecological health of the water systems and surrounding communities. To assess the impacts of these pollutants and to guide appropriate water management strategies, reliable and efficient indicators are required. This study introduces a novel Biodegradability Index (BI) designed specifically for urban rivers, based on the ratio of Biochemical Oxygen Demand (BOD5) to Chemical Oxygen Demand (COD). The proposed BI allows for better monitoring and management of organic pollution by considering the biodegradability of pollutants, which is an important factor in assessing a water body’s self-purification potential. The index was developed using water samples collected across the metropolitan area of Tehran, Iran, and the relationship between the BI and various water quality variables (WQVs) was explored using statistical and machine learning techniques. The results show a strong correlation between detergent concentrations and the BI, with a Spearman correlation coefficient of 0.82 and an R² value of 0.63. A predictive model for BI was also developed using detergent concentrations, achieving an R² of 0.7, thus suggesting that detergent levels can serve as a reliable, low-cost predictor of biodegradability in urban rivers. This study offers a practical approach to estimating the BI, which could significantly improve water quality assessments in urban areas by providing a simpler and faster method for evaluating river health. The findings underscore the importance of using a dedicated biodegradability index tailored to urban rivers, which are subject to unique and complex pollutant profiles compared to natural water systems. The proposed method has potential applications for sustainable urban river management and pollution mitigation strategies.
Published in | American Journal of Environmental Science and Engineering (Volume 9, Issue 3) |
DOI | 10.11648/j.ajese.20250903.17 |
Page(s) | 147-156 |
Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
Copyright |
Copyright © The Author(s), 2025. Published by Science Publishing Group |
Urban Rivers, Biodegradability Index (BI), BOD5/COD, Water Quality, Detergents, Machine Learning, SHAP, Random Forest, Tehran
Element | Metal | Heavy Metal | Toxic | Non-Metal |
---|---|---|---|---|
Potassium (K) | * | |||
Sodium (Na) | * | |||
Phosphate (PO4) | * | |||
Ammonia (NH₃) | * | |||
Fluorine (F) | * | |||
Chlorine (Cl) | * | |||
Detergent | * | |||
Chemical Oxygen Demand (COD) | * (unit) | |||
Biochemical Oxygen Demand (BOD5) | * (unit) | |||
Manganese (Mn) | * | |||
Iron (Fe) | * | |||
Zinc (Zn) | * | |||
Nickel (Ni) | * | * | * | |
Lead (Pb) | * | * | * | |
Copper (Cu) | * | * | ||
Chromium (Cr) | * | * | * | |
Arsenic (As) | * | * | ||
Magnesium (Mg) | * | |||
Oil (OIL) | * |
BOD5 | Biochemical Oxygen Demand (5-Day) |
COD | Chemical Oxygen Demand |
BI | Biodegradability Index |
WQVs | Water Quality Variables |
SHAP | SHapley Additive exPlanations |
R² | Coefficient of Determination |
EPA | Environmental Protection Agency |
DO | Dissolved Oxygen |
ORCID | Open Researcher and Contributor ID |
SOP | Standard Operating Procedure |
BOD5/TOC | Biochemical Oxygen Demand to Total Organic Carbon |
COD/TOC | Chemical Oxygen Demand to Total Organic Carbon |
BOD5/TN | Biochemical Oxygen Demand to Total Nitrogen |
BOD5/TP | Biochemical Oxygen Demand to Total Phosphorus |
BOD5/COD | Biochemical Oxygen Demand to Chemical Oxygen Demand |
K | Potassium |
Na | Sodium |
PO4 | Phosphate |
NH₃ | Ammonia |
F | Fluorine |
Cl | Chlorine |
Mn | Manganese |
Fe | Iron |
Zn | Zinc |
Ni | Nickel |
Pb | Lead |
Cu | Copper |
Cr | Chromium |
As | Arsenic |
Mg | Magnesium |
OIL | Oil |
[1] | Papa, F., J.-F. Crétaux, M. Grippa, E. Robert, M. Trigg, R. M. Tshimanga, B. Kitambo, A. Paris, A. Carr, A. S. Fleischmann, et al., 2023, Water Resources in Africa under Global Change: Monitoring Surface Waters from Space, Surveys in Geophysics, 44, 43-93, |
[2] | Newson, M., 2008, Land, Water and Development: Sustainable and Adaptive Management of Rivers, |
[3] | Formery, S., M. Laprise, E. Rey, 2023, Promoting a city-river balance within neighborhoods in transition along the Rhone, City and Environment Interactions, 17, 100093, |
[4] | Andrade-Suárez, M. J., U. López-Mejuto, M. García-Docampo, F.-A. Varela-García, 2025, Exploring Indirect Links between Green Space Use and Health in the Urban Context: Is There More to It than Meets the Eye? Ecosystem Health and Sustainability, |
[5] | Lv, Z., X. Ran, J. Liu, Y. Feng, X. Zhong, N. Jiao, 2024, Effectiveness of Chemical Oxygen Demand as an Indicator of Organic Pollution in Aquatic Environments, Ocean-Land-Atmosphere Research, |
[6] | Hilaire, S. S., C. Chen, J. Radolinski, T. Leventhal, H. Preisendanz, P. J. A. Kleinman, R. Maguire, R. D. Stewart, L. S. Saporito, K. Xia, 2022, Culturable antibiotic-resistant fecal coliform bacteria in soil and surface runoff after liquid dairy manure surface application and subsurface injection, Journal of Environmental Quality, 51, 288-300, |
[7] | Uddin, M. G., S. Nash, A. Rahman, A. I. Olbert, 2022, A comprehensive method for improvement of water quality index (WQI) models for coastal water quality assessment, Water Research, 219, 118532, |
[8] | Ugbebor, J. N., J. C. Agunwamba, V. E. Amah, 2012, Determination of Reaeration Coefficient K2 for Polluted Stream as a Function of Depth, Hydraulic Radius, Temperature and Velocity, Nigerian Journal of Technology, 31, 174-180. |
[9] | 2021, Improvement of Biodegradability Index of Industrial Wastewater Using Different Pretreatment Techniques, Wastewater Treatment, 103-136, |
[10] | Vannarath, A., A. K. Thalla, 2022, Effects of chemical pretreatments on material solubilization of Areca catechu L. husk: Digestion, biodegradability, and kinetic studies for biogas yield, Journal of Environmental Management, 316, 115322, |
[11] | 2025, Biomass for sustainable air quality, Biomass for Environmental Remediation, 123-137, |
[12] | Siddique, S. H., P. J. Hazell, H. Wang, J. P. Escobedo, A. A. H. Ameri, 2022, Lessons from nature: 3D printed bio-inspired porous structures for impact energy absorption - A review, Additive Manufacturing, 58, 103051, |
[13] | Xiao, C., J. Chen, D. Chen, R. Chen, X. Song, 2023, Mechanism of sinuosity effect on self-purification capacity of rivers, Environmental Science and Pollution Research, 30, 112184-112193, |
[14] | Elahian, M., N. Ahmadi, A. A. Heidari, N. Mengelizadeh, D. Balarak, 2025, Preparation of a polyaniline-supported Ce-Ag-doped ZnO nanocomposite for efficient photocatalytic degradation of acid blue 113 dye, Results in Engineering, 25, 103824, |
[15] | Grossule, V., D. Fang, D. Yue, M. C. Lavagnolo, 2022, Treatment of wastewater using black soldier fly larvae, under different degrees of biodegradability and oxidation of organic content, Journal of Environmental Management, 319, 115734, |
[16] | Faggiano, A., M. De Carluccio, F. Cerrato, C. A. Garcia Junior, A. Proto, A. Fiorentino, L. Rizzo, 2023, Improving organic matter and nutrients removal and minimizing sludge production in landfill leachate pre-treatment by Fenton process through a comprehensive response surface methodology approach, Journal of Environmental Management, 340, 117950, |
[17] | Lai, H.-T., Y.-M. Kuo, 2025, Environmental Variability and its Impact on Phytoplankton Communities in Taiwan’s Aogu Wetland, Water, Air, & Soil Pollution, 236, 190, |
[18] | Javaid, R., A. Ikhlaq, O. S. Rizvi, M. Abid, F. Qi, U. Y. Qazi, 2025, Enhancing biodegradability of landfill leachate by hybrid treatment process: coagulation followed by catalytic ozonation with Z5Å-Fe-Zn for environmental sustainability, Journal of Water Process Engineering, 75, 107938, |
[19] | National Research and Development Institute for Industrial Ecology, D. G. Rudaru, I. E. Lucaciu, National Research and Development Institute for Industrial Ecology, A. M. Fulgheci, National Research and Development Institute for Industrial Ecology, 2022, Correlation between BOD5 and COD - biodegradability indicator of wastewater, Romanian Journal of Ecology & Environmental Chemistry, 4, 80-86, |
[20] | Diwyanjalee, G. R., B. K. A. Bellanthudawa, D. K. N. S. De Silva, A. R. Gunawardena, 2024, Biodegradability index (BDI) as an indicator for effluents quality measurement: A case study based on different industry sectors in Matara District, Sri Lanka, Water Practice and Technology, 19, 3092-3108, |
[21] | Koda, E., A. Miszkowska, A. Sieczka, 2017, Levels of Organic Pollution Indicators in Groundwater at the Old Landfill and Waste Management Site, Applied Sciences, 7, 638, |
[22] | 2010, Monitoring of organic load in a tropical urban river basin (Cameroon) by means of BOD and oxydability measurements, Ecohydrology & Hydrobiology, 10, 71-80, |
[23] | Yang, G., M. Ryo, J. Roy, D. R. Lammel, M.-B. Ballhausen, X. Jing, X. Zhu, M. C. Rillig, 2022, Multiple anthropogenic pressures eliminate the effects of soil microbial diversity on ecosystem functions in experimental microcosms, Nature Communications, 13, 1-8, |
[24] | Turschwell, M. P., R. M. Connolly, J. C. Dunic, M. Sievers, C. A. Buelow, R. M. Pearson, V. J. D. Tulloch, I. M. Côté, R. K. F. Unsworth, C. J. Collier, et al., 2021, Anthropogenic pressures and life history predict trajectories of seagrass meadow extent at a global scale, Proceedings of the National Academy of Sciences, 118, e2110802118, |
[25] | Partani, S., A. D. Mehr, F. Bostanmaneshrad, A. Arzhangi, K. P. Niavol, H.-P. Nachtnebel, 2024, Determining the main driver of hypoxia potential in freshwater inland lakes, Journal of Cleaner Production, 142521, |
[26] | El Mrabet, Z., N. Sugunaraj, P. Ranganathan, S. Abhyankar, 2022, Random Forest Regressor-Based Approach for Detecting Fault Location and Duration in Power Systems, Sensors, 22, 458, |
[27] | Partani, S., A. D. Mehr, M. Maghrebi, R. Mokhtari, H.-P. Nachtnebel, R. H. Taniwaki, A. Arzhangi, 2023, A new spatial estimation model and source apportionment of aliphatic hydrocarbons in coastal surface sediments of the Nayband Bay, Persian Gulf, Science of The Total Environment, 904, 166746, |
[28] | Ariapak, S., A. Jalalian, N. Honarjoo, 2022, Source identification, seasonal and spatial variations of airborne dust trace elements pollution in Tehran, the capital of Iran, Urban Climate, 42, 101049, |
[29] | Jones, E. R., M. F. P. Bierkens, P. J. T. M. van Puijenbroek, L. (Rens) P. H. van Beek, N. Wanders, E. H. Sutanudjaja, M. T. H. van Vliet, 2023, Sub-Saharan Africa will increasingly become the dominant hotspot of surface water pollution, Nature Water, 1, 602-613, |
[30] | Partani, S., A. Rashidi, H. Jarahi, A. Jafari, A. Arzhangi, 2024, Evaluation of the ecological risk of heavy metals in the sediments of coastal wetlandsCase study: coastal wetlands of Chabahar Bay, mangrove ecosystem, Iranian Journal of Soil and Water Research, |
[31] | Ekanayake, I. U., D. P. P. Meddage, U. Rathnayake, 2022, A novel approach to explain the black-box nature of machine learning in compressive strength predictions of concrete using Shapley additive explanations (SHAP), Case Studies in Construction Materials, 16, e01059, |
[32] | Li, Z., X. Gao, D. Lu, 2021, Correlation analysis and statistical assessment of early hydration characteristics and compressive strength for multi-composite cement paste, Construction and Building Materials, 310, 125260, |
APA Style
Arzhangi, A., Partani, S. (2025). Development of a Biodegradability Index for Urban Rivers Using Detergent Concentration: A Case Study from Tehran, Iran. American Journal of Environmental Science and Engineering, 9(3), 147-156. https://doi.org/10.11648/j.ajese.20250903.17
ACS Style
Arzhangi, A.; Partani, S. Development of a Biodegradability Index for Urban Rivers Using Detergent Concentration: A Case Study from Tehran, Iran. Am. J. Environ. Sci. Eng. 2025, 9(3), 147-156. doi: 10.11648/j.ajese.20250903.17
@article{10.11648/j.ajese.20250903.17, author = {Amin Arzhangi and Sadegh Partani}, title = {Development of a Biodegradability Index for Urban Rivers Using Detergent Concentration: A Case Study from Tehran, Iran }, journal = {American Journal of Environmental Science and Engineering}, volume = {9}, number = {3}, pages = {147-156}, doi = {10.11648/j.ajese.20250903.17}, url = {https://doi.org/10.11648/j.ajese.20250903.17}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajese.20250903.17}, abstract = {Urban rivers are increasingly impacted by anthropogenic activities, leading to significant changes in water quality and pollutant levels. These rivers are subject to multiple environmental pressures, such as industrial discharge, urban runoff, and domestic wastewater, all of which affect the ecological health of the water systems and surrounding communities. To assess the impacts of these pollutants and to guide appropriate water management strategies, reliable and efficient indicators are required. This study introduces a novel Biodegradability Index (BI) designed specifically for urban rivers, based on the ratio of Biochemical Oxygen Demand (BOD5) to Chemical Oxygen Demand (COD). The proposed BI allows for better monitoring and management of organic pollution by considering the biodegradability of pollutants, which is an important factor in assessing a water body’s self-purification potential. The index was developed using water samples collected across the metropolitan area of Tehran, Iran, and the relationship between the BI and various water quality variables (WQVs) was explored using statistical and machine learning techniques. The results show a strong correlation between detergent concentrations and the BI, with a Spearman correlation coefficient of 0.82 and an R² value of 0.63. A predictive model for BI was also developed using detergent concentrations, achieving an R² of 0.7, thus suggesting that detergent levels can serve as a reliable, low-cost predictor of biodegradability in urban rivers. This study offers a practical approach to estimating the BI, which could significantly improve water quality assessments in urban areas by providing a simpler and faster method for evaluating river health. The findings underscore the importance of using a dedicated biodegradability index tailored to urban rivers, which are subject to unique and complex pollutant profiles compared to natural water systems. The proposed method has potential applications for sustainable urban river management and pollution mitigation strategies.}, year = {2025} }
TY - JOUR T1 - Development of a Biodegradability Index for Urban Rivers Using Detergent Concentration: A Case Study from Tehran, Iran AU - Amin Arzhangi AU - Sadegh Partani Y1 - 2025/08/12 PY - 2025 N1 - https://doi.org/10.11648/j.ajese.20250903.17 DO - 10.11648/j.ajese.20250903.17 T2 - American Journal of Environmental Science and Engineering JF - American Journal of Environmental Science and Engineering JO - American Journal of Environmental Science and Engineering SP - 147 EP - 156 PB - Science Publishing Group SN - 2578-7993 UR - https://doi.org/10.11648/j.ajese.20250903.17 AB - Urban rivers are increasingly impacted by anthropogenic activities, leading to significant changes in water quality and pollutant levels. These rivers are subject to multiple environmental pressures, such as industrial discharge, urban runoff, and domestic wastewater, all of which affect the ecological health of the water systems and surrounding communities. To assess the impacts of these pollutants and to guide appropriate water management strategies, reliable and efficient indicators are required. This study introduces a novel Biodegradability Index (BI) designed specifically for urban rivers, based on the ratio of Biochemical Oxygen Demand (BOD5) to Chemical Oxygen Demand (COD). The proposed BI allows for better monitoring and management of organic pollution by considering the biodegradability of pollutants, which is an important factor in assessing a water body’s self-purification potential. The index was developed using water samples collected across the metropolitan area of Tehran, Iran, and the relationship between the BI and various water quality variables (WQVs) was explored using statistical and machine learning techniques. The results show a strong correlation between detergent concentrations and the BI, with a Spearman correlation coefficient of 0.82 and an R² value of 0.63. A predictive model for BI was also developed using detergent concentrations, achieving an R² of 0.7, thus suggesting that detergent levels can serve as a reliable, low-cost predictor of biodegradability in urban rivers. This study offers a practical approach to estimating the BI, which could significantly improve water quality assessments in urban areas by providing a simpler and faster method for evaluating river health. The findings underscore the importance of using a dedicated biodegradability index tailored to urban rivers, which are subject to unique and complex pollutant profiles compared to natural water systems. The proposed method has potential applications for sustainable urban river management and pollution mitigation strategies. VL - 9 IS - 3 ER -