Synthesis and Properties of Bio-based Adhesives Derived from Plant Oil Residues

Xiaosheng Liu; Huidong Su; Yanfang Pang; Dianji Yang; Yongqiang Jiang; An Mao; Yifu Yuan; Weitao Xu

doi:doi:10.11648/j.ajme.20190506.12

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Synthesis and Properties of Bio-based Adhesives Derived from Plant Oil Residues

Xiaosheng Liu, Huidong Su, Yanfang Pang, Dianji Yang, Yongqiang Jiang, An Mao, Yifu Yuan, Weitao Xu

Published in American Journal of Modern Energy (Volume 5, Issue 6)

Received: 16 December 2019 Accepted: 25 December 2019 Published: 8 January 2020

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Abstract

Cottonseed oil residue (COR) is a by-product of cottonseed extracted by prepressing or direct solvent extraction. The protein content of COR can reach 50% and higher, but it has not been effectively utilized. In this study, bio-based adhesives were synthesized from COR, maleic anhydride, and urea. The obtained adhesives were then analyzed by Fourier transform infrared (FTIR) and Thermogravimetric (TG), and tested as wood composite panel binders. The results indicated that the optimal synthesis conditions of the modified COR adhesive were: the urea concentration was 2 mol/L, the maleic anhydride content was 6%, and the reaction temperature was 70°C. Infrared spectrum revealed a new characteristic peak appeared at 2216 cm^-1, which indicated that the protein in cottonseed reacted with maleic anhydride to form a stable structure, which improved the water resistance of the adhesive. The TG curve of maleic anhydride/urea modified COR adhesive showed that the peak value of the adhesive shifted back in the second and third stages, which indicated that the modified adhesive had better thermal stability and improved water resistance than those of unmodified ones. The study results could provide a theoretical basis and scientific guidance for the appropriate processing method and application technology development of COR.

Published in	American Journal of Modern Energy (Volume 5, Issue 6)
DOI	10.11648/j.ajme.20190506.12
Page(s)	94-99
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Bio-based Adhesive, Oil Residue, Bonding Strength, Composite Panel, Modification

References

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[3]	A. Mao, E. B. Hassan, and M. G. Kim, Low mole ratio UF and UMF resins entailing uron-type methylene-ether groups and their low formaldehyde emission potentials. BioResources, 8 (2), 2470-2486, 2013.
[4]	A. Mao, E. B. Hassan, and M. G. Kim, Low mole ratio urea-melamine-formaldehyde resins entailing increased methylene-ether group contents and their formaldehyde emission potentials of wood composite boards. BioResources, 8 (3), 4659-4675, 2013.
[5]	A. Mao, E. B. Hassan, and M. G. Kim, The effects of adding melamine at different resin synthesis points of low mole ratio urea-melamine-formaldehyde (UMF) resins. BioResources, 8 (4), 5733-5748, 2013.
[6]	X. Li, J. Luo, J. Li, Q. Gao. Effects of diatomite inorganic fillers on the properties of a melamine–urea–formaldehyde resin. Journal of Applied Polymer Science, 133 (41): 44095-44103, 2016.
[7]	Y. F. Pang, W. T. Xu, Q. Li, C. Li, and A. Mao, Research progress of bio-based wood adhesives. China Forest Products Industry, 45 (4), 3-7, 2018.
[8]	A. Mao, R. Shmulky, Q. Li, and H. Wan, Recycling polyurethane materials A comparison of polyol from glycolysis with micronized polyurethane powder in particleboard applications. BioResources, 9 (3), 4253-4265, 2014.
[9]	A. Mao, W. Xu, E. Xi, Q. Li, and H. Wan, Evaluation of phenol-formaldehyde resins modified and blended with pyrolysis bio-oil for plywood. Forest Products Journal, 68 (2), 113-119, 2018.
[10]	Q. Li. M. Li, C. Chen, G. Cao, A. Mao, and H. Wan, Adhesives from polymeric methylene diphenyl diisocyanate resin and recycled polyols for plywood. Forest Products Journal, 67 (3/4), 275-282, 2017.
[11]	P. Qu, H. Huang, G. Wu, E. Sun, and Z. Chang. Effects of hydrolysis degree of soy protein isolate on the structure and performance of hydrolyzed soy protein isolate/urea/formaldehyde copolymer resin. Journal of Applied Polymer Science, 132 (7): 41469-41477, 2015.
[12]	P. Qu, H. Huang, G. Wu, E. Sun, and Z. Chang. The effect of hydrolyzed soy protein isolate on the structure and biodegradability of urea–formaldehyde adhesives. Journal of Adhesion Science and Technology, 29 (6): 502-517, 2015.
[13]	L. C, Y. Zhang, and X. N. Li. A high-performance bio-adhesive derived from soy protein isolate and condensed tannins. RSC Advances, 7 (34): 21226-21233, 2017.
[14]	P. Wei, X. Rao, J. Yang, Y. Guo, H. Chen, Y. Zhang, S. Chen, X. Deng, and X. Wang, Hot pressing of wood-based composites: a review. Forest Products Journal, 66 (7/8): 419-427, 2016.
[15]	Y. Li, M. Zhang, Y. Zhang, Q. Gao, A. Mao, and J. Li, Effects of different denaturants on properties and performance of soy protein-based adhesive. Polymers, 11, 1262-1275, 2019.

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APA Style

Xiaosheng Liu, Huidong Su, Yanfang Pang, Dianji Yang, Yongqiang Jiang, et al. (2020). Synthesis and Properties of Bio-based Adhesives Derived from Plant Oil Residues. American Journal of Modern Energy, 5(6), 94-99. https://doi.org/10.11648/j.ajme.20190506.12

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ACS Style

Xiaosheng Liu; Huidong Su; Yanfang Pang; Dianji Yang; Yongqiang Jiang, et al. Synthesis and Properties of Bio-based Adhesives Derived from Plant Oil Residues. Am. J. Mod. Energy 2020, 5(6), 94-99. doi: 10.11648/j.ajme.20190506.12

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AMA Style

Xiaosheng Liu, Huidong Su, Yanfang Pang, Dianji Yang, Yongqiang Jiang, et al. Synthesis and Properties of Bio-based Adhesives Derived from Plant Oil Residues. Am J Mod Energy. 2020;5(6):94-99. doi: 10.11648/j.ajme.20190506.12

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@article{10.11648/j.ajme.20190506.12,
  author = {Xiaosheng Liu and Huidong Su and Yanfang Pang and Dianji Yang and Yongqiang Jiang and An Mao and Yifu Yuan and Weitao Xu},
  title = {Synthesis and Properties of Bio-based Adhesives Derived from Plant Oil Residues},
  journal = {American Journal of Modern Energy},
  volume = {5},
  number = {6},
  pages = {94-99},
  doi = {10.11648/j.ajme.20190506.12},
  url = {https://doi.org/10.11648/j.ajme.20190506.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajme.20190506.12},
  abstract = {Cottonseed oil residue (COR) is a by-product of cottonseed extracted by prepressing or direct solvent extraction. The protein content of COR can reach 50% and higher, but it has not been effectively utilized. In this study, bio-based adhesives were synthesized from COR, maleic anhydride, and urea. The obtained adhesives were then analyzed by Fourier transform infrared (FTIR) and Thermogravimetric (TG), and tested as wood composite panel binders. The results indicated that the optimal synthesis conditions of the modified COR adhesive were: the urea concentration was 2 mol/L, the maleic anhydride content was 6%, and the reaction temperature was 70°C. Infrared spectrum revealed a new characteristic peak appeared at 2216 cm-1, which indicated that the protein in cottonseed reacted with maleic anhydride to form a stable structure, which improved the water resistance of the adhesive. The TG curve of maleic anhydride/urea modified COR adhesive showed that the peak value of the adhesive shifted back in the second and third stages, which indicated that the modified adhesive had better thermal stability and improved water resistance than those of unmodified ones. The study results could provide a theoretical basis and scientific guidance for the appropriate processing method and application technology development of COR.},
 year = {2020}
}

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TY  - JOUR
T1  - Synthesis and Properties of Bio-based Adhesives Derived from Plant Oil Residues
AU  - Xiaosheng Liu
AU  - Huidong Su
AU  - Yanfang Pang
AU  - Dianji Yang
AU  - Yongqiang Jiang
AU  - An Mao
AU  - Yifu Yuan
AU  - Weitao Xu
Y1  - 2020/01/08
PY  - 2020
N1  - https://doi.org/10.11648/j.ajme.20190506.12
DO  - 10.11648/j.ajme.20190506.12
T2  - American Journal of Modern Energy
JF  - American Journal of Modern Energy
JO  - American Journal of Modern Energy
SP  - 94
EP  - 99
PB  - Science Publishing Group
SN  - 2575-3797
UR  - https://doi.org/10.11648/j.ajme.20190506.12
AB  - Cottonseed oil residue (COR) is a by-product of cottonseed extracted by prepressing or direct solvent extraction. The protein content of COR can reach 50% and higher, but it has not been effectively utilized. In this study, bio-based adhesives were synthesized from COR, maleic anhydride, and urea. The obtained adhesives were then analyzed by Fourier transform infrared (FTIR) and Thermogravimetric (TG), and tested as wood composite panel binders. The results indicated that the optimal synthesis conditions of the modified COR adhesive were: the urea concentration was 2 mol/L, the maleic anhydride content was 6%, and the reaction temperature was 70°C. Infrared spectrum revealed a new characteristic peak appeared at 2216 cm-1, which indicated that the protein in cottonseed reacted with maleic anhydride to form a stable structure, which improved the water resistance of the adhesive. The TG curve of maleic anhydride/urea modified COR adhesive showed that the peak value of the adhesive shifted back in the second and third stages, which indicated that the modified adhesive had better thermal stability and improved water resistance than those of unmodified ones. The study results could provide a theoretical basis and scientific guidance for the appropriate processing method and application technology development of COR.
VL  - 5
IS  - 6
ER  -

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Author Information

Xiaosheng Liu

Key Laboratory of State Forestry Administration for Silviculture of the lower Yellow River, College of Forestry, Shandong Agricultural University, Taian, China
Huidong Su

Key Laboratory of State Forestry Administration for Silviculture of the lower Yellow River, College of Forestry, Shandong Agricultural University, Taian, China
Yanfang Pang

Key Laboratory of State Forestry Administration for Silviculture of the lower Yellow River, College of Forestry, Shandong Agricultural University, Taian, China
Dianji Yang

Dongying Shengji Environmental Protection Engineering Co., Ltd, Dongying, China
Yongqiang Jiang

Key Laboratory of State Forestry Administration for Silviculture of the lower Yellow River, College of Forestry, Shandong Agricultural University, Taian, China
An Mao

Key Laboratory of State Forestry Administration for Silviculture of the lower Yellow River, College of Forestry, Shandong Agricultural University, Taian, China
Yifu Yuan

Key Laboratory of State Forestry Administration for Silviculture of the lower Yellow River, College of Forestry, Shandong Agricultural University, Taian, China
Weitao Xu

Planning and Design Institute of Forest Products Industry of National Forestry and Grassland Administration, Beiijing, China

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Plain Text BibTeX RIS

APA Style

Xiaosheng Liu, Huidong Su, Yanfang Pang, Dianji Yang, Yongqiang Jiang, et al. (2020). Synthesis and Properties of Bio-based Adhesives Derived from Plant Oil Residues. American Journal of Modern Energy, 5(6), 94-99. https://doi.org/10.11648/j.ajme.20190506.12

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ACS Style

Xiaosheng Liu; Huidong Su; Yanfang Pang; Dianji Yang; Yongqiang Jiang, et al. Synthesis and Properties of Bio-based Adhesives Derived from Plant Oil Residues. Am. J. Mod. Energy 2020, 5(6), 94-99. doi: 10.11648/j.ajme.20190506.12

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AMA Style

Xiaosheng Liu, Huidong Su, Yanfang Pang, Dianji Yang, Yongqiang Jiang, et al. Synthesis and Properties of Bio-based Adhesives Derived from Plant Oil Residues. Am J Mod Energy. 2020;5(6):94-99. doi: 10.11648/j.ajme.20190506.12

Copy | Download

@article{10.11648/j.ajme.20190506.12,
  author = {Xiaosheng Liu and Huidong Su and Yanfang Pang and Dianji Yang and Yongqiang Jiang and An Mao and Yifu Yuan and Weitao Xu},
  title = {Synthesis and Properties of Bio-based Adhesives Derived from Plant Oil Residues},
  journal = {American Journal of Modern Energy},
  volume = {5},
  number = {6},
  pages = {94-99},
  doi = {10.11648/j.ajme.20190506.12},
  url = {https://doi.org/10.11648/j.ajme.20190506.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajme.20190506.12},
  abstract = {Cottonseed oil residue (COR) is a by-product of cottonseed extracted by prepressing or direct solvent extraction. The protein content of COR can reach 50% and higher, but it has not been effectively utilized. In this study, bio-based adhesives were synthesized from COR, maleic anhydride, and urea. The obtained adhesives were then analyzed by Fourier transform infrared (FTIR) and Thermogravimetric (TG), and tested as wood composite panel binders. The results indicated that the optimal synthesis conditions of the modified COR adhesive were: the urea concentration was 2 mol/L, the maleic anhydride content was 6%, and the reaction temperature was 70°C. Infrared spectrum revealed a new characteristic peak appeared at 2216 cm-1, which indicated that the protein in cottonseed reacted with maleic anhydride to form a stable structure, which improved the water resistance of the adhesive. The TG curve of maleic anhydride/urea modified COR adhesive showed that the peak value of the adhesive shifted back in the second and third stages, which indicated that the modified adhesive had better thermal stability and improved water resistance than those of unmodified ones. The study results could provide a theoretical basis and scientific guidance for the appropriate processing method and application technology development of COR.},
 year = {2020}
}

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TY  - JOUR
T1  - Synthesis and Properties of Bio-based Adhesives Derived from Plant Oil Residues
AU  - Xiaosheng Liu
AU  - Huidong Su
AU  - Yanfang Pang
AU  - Dianji Yang
AU  - Yongqiang Jiang
AU  - An Mao
AU  - Yifu Yuan
AU  - Weitao Xu
Y1  - 2020/01/08
PY  - 2020
N1  - https://doi.org/10.11648/j.ajme.20190506.12
DO  - 10.11648/j.ajme.20190506.12
T2  - American Journal of Modern Energy
JF  - American Journal of Modern Energy
JO  - American Journal of Modern Energy
SP  - 94
EP  - 99
PB  - Science Publishing Group
SN  - 2575-3797
UR  - https://doi.org/10.11648/j.ajme.20190506.12
AB  - Cottonseed oil residue (COR) is a by-product of cottonseed extracted by prepressing or direct solvent extraction. The protein content of COR can reach 50% and higher, but it has not been effectively utilized. In this study, bio-based adhesives were synthesized from COR, maleic anhydride, and urea. The obtained adhesives were then analyzed by Fourier transform infrared (FTIR) and Thermogravimetric (TG), and tested as wood composite panel binders. The results indicated that the optimal synthesis conditions of the modified COR adhesive were: the urea concentration was 2 mol/L, the maleic anhydride content was 6%, and the reaction temperature was 70°C. Infrared spectrum revealed a new characteristic peak appeared at 2216 cm-1, which indicated that the protein in cottonseed reacted with maleic anhydride to form a stable structure, which improved the water resistance of the adhesive. The TG curve of maleic anhydride/urea modified COR adhesive showed that the peak value of the adhesive shifted back in the second and third stages, which indicated that the modified adhesive had better thermal stability and improved water resistance than those of unmodified ones. The study results could provide a theoretical basis and scientific guidance for the appropriate processing method and application technology development of COR.
VL  - 5
IS  - 6
ER  -

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