To increase heavy oil conversion by hydrocracking, the larger pore opening mesoporous materials with enhanced acidity and hydrothermal stability are required. A series of mesoporous Al-SBA-15 was studied in acid-free and different HCl concentration solutions with various initial SiO2/Al2O3 molar ratio. The final product samples were characterized with N2 adsorption, SAXS/XRD, NH3-TPD, TEM, 28Si NMR, and 27Al NMR. The results concluded that the acid-free and weak acidic medium favor the formation of the Al-SBA-15 with better textual properties, higher acidity, and higher wall-thickness. A considerable amount of Al was present in the tetrahedral form.
Published in | American Journal of Materials Synthesis and Processing (Volume 3, Issue 3) |
DOI | 10.11648/j.ajmsp.20180303.11 |
Page(s) | 39-46 |
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Copyright © The Author(s), 2018. Published by Science Publishing Group |
Mesoporous Materials, SBA-15, Synthesis, Hydrocracking
[1] | A. Corma, A. Martinez, V. Martinez-Soria, J. B. Monton, J. of Catal. 153 (1995) 25-31. |
[2] | R. Huirache-Acuna, R. Nava, C. L. Peza-Ledesma, J. Lara-Romero, G. Alonso-Ninez, B. Pawele, E. M. Rivera-Munoz, Materials (2013) 4139-4167. |
[3] | A. M. Alsobaai, R. Zakaria, B. H. Hameed, Fuel Processing Technology 88 (2007) 921–928. |
[4] | K. Kohli, R. Prajapati, M. Sau, S. K. Maity, Procedia Earth and Planetary Science 11 (2015) 325-331. |
[5] | C. T. Kresge, M. E. leonowicz, W. J. Roth, J. C. Vartuli, J. S. Beck, Nature 359 (1992) 710. |
[6] | A. Corma, Chem. Rev. 97 (1997) 2373. |
[7] | D. Zhao, Q. Huo, J. Feng, B. F. Chmelka, G. D. Stucky, J. Am. Chem. Soc. 120 (1998)6024Al introduce into SBA-15. |
[8] | W. Hua, Y. Yue, Zi, Gao, J. Molecular Catalysis A: Chemical 170 (2001) 195-202. |
[9] | C. Han, H. Wang, L. Zhang, R. Li, Y. Zhang, Y. Luo, X. Zheng, Advanced Powder Technology 22(2011)20-25. |
[10] | A. A. Campos, L. Martins, L. L. Oliverira, C. R. Silva, M. Wallau, E. A. Urquieta-Gonzalez, Catalysis Today 107-108(2005) 759-767. |
[11] | H. Kao, C. Ting, S. Chao, J. of Molecular Catalysis A: chemical 235 (2005) 200-208. |
[12] | K. K. Cheralathan, T. Hayashi, M. Ogura, Microporous and Mesoporous Materials, 116 (2008) 406-415. |
[13] | M. Baca, E. de la Rochefoucauld, E. Ambroise, J. M. Krafit, R. Hajjar, P. P. Man, X. Carrier, J. Blanchard, Microporous and Mesoporous Materials 110 (2008) 232-241. |
[14] | J. Wang, H. Ge, W. Bao, Materials letters 145 (2015) 312-315. |
[15] | S. Lin, L. Shi, T. Yu, X. Li, X. Yi, A. Zheng, Microporous Mesoporous Material 207 (2015) 111-119. |
[16] | S. Lin, L. Shi, M. M. L. Ribeiro Carrott, P. J. M. Carrott, J. Rocha, M. R. Li, X. D. Zou, Microporous Mesoporous Material 142(2011) 526-534. |
[17] | L. Shi, Y, Xu, N. Zhang, S. Lin, X. Li, P. Guo, X. Li, Journal of Solid State Chemistry 203 (2013) 281-290. |
[18] | C. Marquez-Alvarez, N. Zikova, J. Perez-Pariente, J. Cejka, Catal. Rev. 50(2008) 222. |
[19] | Y. Yue, A. Gefeon, J. L. Bonardet, N. Melosh, J. B. D’ Espinose, J. Fraisard, Chem. Commun. (1999) 1967-1968). |
[20] | B. Dragoi, E. Dumitriu, C. Guimon, A. Auroux, Micropor. Mesopor. Mater. 121(2009) 7-17). |
[21] | Y. Li, W. Zhang, L. Zhang, Q. Yang, Z. Wei, Z. Feng, C. Li, J. Phys. Chem. B 108 (2004) 9739–9744. |
[22] | T. Jiang, H. Tao, J. Ren, X. Liu, Y. Wang, G. Lu, Micropor. Mesopor. Mater. 142 (2011) 341–346. |
[23] | S. Lin, L. Shi, M. M. L. Ribeiro, Carrott, P. J. M. Carrott, J. Rocha, M. R. Li, X. D. Zou, Micro. Meso. Mater. 142 (2011) 526-534. |
APA Style
Lianhui Ding, Hanaa Habboubi, Essam Sayed, Sitepu Husinsyah, Hameed Badairy, et al. (2018). Study on Mesoporous Al-SBA-15 with Enhanced Acidity and Hydrothermal Stability for Heavy Oil Hydrocracking Conversion. American Journal of Materials Synthesis and Processing, 3(3), 39-46. https://doi.org/10.11648/j.ajmsp.20180303.11
ACS Style
Lianhui Ding; Hanaa Habboubi; Essam Sayed; Sitepu Husinsyah; Hameed Badairy, et al. Study on Mesoporous Al-SBA-15 with Enhanced Acidity and Hydrothermal Stability for Heavy Oil Hydrocracking Conversion. Am. J. Mater. Synth. Process. 2018, 3(3), 39-46. doi: 10.11648/j.ajmsp.20180303.11
AMA Style
Lianhui Ding, Hanaa Habboubi, Essam Sayed, Sitepu Husinsyah, Hameed Badairy, et al. Study on Mesoporous Al-SBA-15 with Enhanced Acidity and Hydrothermal Stability for Heavy Oil Hydrocracking Conversion. Am J Mater Synth Process. 2018;3(3):39-46. doi: 10.11648/j.ajmsp.20180303.11
@article{10.11648/j.ajmsp.20180303.11, author = {Lianhui Ding and Hanaa Habboubi and Essam Sayed and Sitepu Husinsyah and Hameed Badairy and Rasha Alghamdi}, title = {Study on Mesoporous Al-SBA-15 with Enhanced Acidity and Hydrothermal Stability for Heavy Oil Hydrocracking Conversion}, journal = {American Journal of Materials Synthesis and Processing}, volume = {3}, number = {3}, pages = {39-46}, doi = {10.11648/j.ajmsp.20180303.11}, url = {https://doi.org/10.11648/j.ajmsp.20180303.11}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajmsp.20180303.11}, abstract = {To increase heavy oil conversion by hydrocracking, the larger pore opening mesoporous materials with enhanced acidity and hydrothermal stability are required. A series of mesoporous Al-SBA-15 was studied in acid-free and different HCl concentration solutions with various initial SiO2/Al2O3 molar ratio. The final product samples were characterized with N2 adsorption, SAXS/XRD, NH3-TPD, TEM, 28Si NMR, and 27Al NMR. The results concluded that the acid-free and weak acidic medium favor the formation of the Al-SBA-15 with better textual properties, higher acidity, and higher wall-thickness. A considerable amount of Al was present in the tetrahedral form.}, year = {2018} }
TY - JOUR T1 - Study on Mesoporous Al-SBA-15 with Enhanced Acidity and Hydrothermal Stability for Heavy Oil Hydrocracking Conversion AU - Lianhui Ding AU - Hanaa Habboubi AU - Essam Sayed AU - Sitepu Husinsyah AU - Hameed Badairy AU - Rasha Alghamdi Y1 - 2018/09/28 PY - 2018 N1 - https://doi.org/10.11648/j.ajmsp.20180303.11 DO - 10.11648/j.ajmsp.20180303.11 T2 - American Journal of Materials Synthesis and Processing JF - American Journal of Materials Synthesis and Processing JO - American Journal of Materials Synthesis and Processing SP - 39 EP - 46 PB - Science Publishing Group SN - 2575-1530 UR - https://doi.org/10.11648/j.ajmsp.20180303.11 AB - To increase heavy oil conversion by hydrocracking, the larger pore opening mesoporous materials with enhanced acidity and hydrothermal stability are required. A series of mesoporous Al-SBA-15 was studied in acid-free and different HCl concentration solutions with various initial SiO2/Al2O3 molar ratio. The final product samples were characterized with N2 adsorption, SAXS/XRD, NH3-TPD, TEM, 28Si NMR, and 27Al NMR. The results concluded that the acid-free and weak acidic medium favor the formation of the Al-SBA-15 with better textual properties, higher acidity, and higher wall-thickness. A considerable amount of Al was present in the tetrahedral form. VL - 3 IS - 3 ER -