Preparation of Carboxymethyl Cellulose-g-Poly (Acrylic Acid - 2-Acrylamido-2-Methylpropane Sulfonic Acid)/Attapulgite Superabsorbent Composite

Fathelrahman Mohammed Soliman; Wu Yang; Hao Guo; Mahgoub Ibrahim Shinger; Ahmed Mahmoud Idris; Emtenan Suliman Hassan

doi:doi:10.11648/j.ajpst.20160201.12

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Preparation of Carboxymethyl Cellulose-g-Poly (Acrylic Acid - 2-Acrylamido-2-Methylpropane Sulfonic Acid)/Attapulgite Superabsorbent Composite

Fathelrahman Mohammed Soliman, Wu Yang, Hao Guo, Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, Emtenan Suliman Hassan

Published in American Journal of Polymer Science and Technology (Volume 2, Issue 1)

Received: 13 July 2016 Accepted: 29 August 2016 Published: 13 September 2016

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Abstract

An eco-friendly high-swelling superabsorbent composite CMC-g-poly(acrylic acid - 2-acrylamido-2-methylpropane sulfonic acid)/Attapulgite based on carboxymethyl cellulose (CMC) and inorganic clay Attapulgite (ATP) was prepared via a grafting copolymerization of acrylic acid (AA) and 2-acrylamido-2-methylpropanesulfonic acid (AMPS), using with N, N-methylenebisacrylamide (MBA) as a cross-linking agent, ammonium persulfate (APS) as an initiator and polyethylene glycol(PEG) as a phase transfer catalyst. The effects of polymerization conditions on the swelling ability of the superabsorbent composite were investigated. The results indicated that the prepared superabsorbent had high water absorbency. Saturated water absorbencies of the superabsorbent reached (864 g.g^-1) for distilled water and (72 g.g^-1) for 0.9 wt% NaCl aqueous solution respectively. The water absorbency of the composites was dependent on the pH of external solutions and used saline solutions.

Published in	American Journal of Polymer Science and Technology (Volume 2, Issue 1)
DOI	10.11648/j.ajpst.20160201.12
Page(s)	11-19
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2016. Published by Science Publishing Group

Keywords

Superabsorbent Composite, Carboxymethyl Cellulose, Attapulgite, Swelling Behavior

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APA Style

Fathelrahman Mohammed Soliman, Wu Yang, Hao Guo, Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, et al. (2016). Preparation of Carboxymethyl Cellulose-g-Poly (Acrylic Acid - 2-Acrylamido-2-Methylpropane Sulfonic Acid)/Attapulgite Superabsorbent Composite. American Journal of Polymer Science and Technology, 2(1), 11-19. https://doi.org/10.11648/j.ajpst.20160201.12

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ACS Style

Fathelrahman Mohammed Soliman; Wu Yang; Hao Guo; Mahgoub Ibrahim Shinger; Ahmed Mahmoud Idris, et al. Preparation of Carboxymethyl Cellulose-g-Poly (Acrylic Acid - 2-Acrylamido-2-Methylpropane Sulfonic Acid)/Attapulgite Superabsorbent Composite. Am. J. Polym. Sci. Technol. 2016, 2(1), 11-19. doi: 10.11648/j.ajpst.20160201.12

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AMA Style

Fathelrahman Mohammed Soliman, Wu Yang, Hao Guo, Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, et al. Preparation of Carboxymethyl Cellulose-g-Poly (Acrylic Acid - 2-Acrylamido-2-Methylpropane Sulfonic Acid)/Attapulgite Superabsorbent Composite. Am J Polym Sci Technol. 2016;2(1):11-19. doi: 10.11648/j.ajpst.20160201.12

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@article{10.11648/j.ajpst.20160201.12,
  author = {Fathelrahman Mohammed Soliman and Wu Yang and Hao Guo and Mahgoub Ibrahim Shinger and Ahmed Mahmoud Idris and Emtenan Suliman Hassan},
  title = {Preparation of Carboxymethyl Cellulose-g-Poly (Acrylic Acid - 2-Acrylamido-2-Methylpropane Sulfonic Acid)/Attapulgite Superabsorbent Composite},
  journal = {American Journal of Polymer Science and Technology},
  volume = {2},
  number = {1},
  pages = {11-19},
  doi = {10.11648/j.ajpst.20160201.12},
  url = {https://doi.org/10.11648/j.ajpst.20160201.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20160201.12},
  abstract = {An eco-friendly high-swelling superabsorbent composite CMC-g-poly(acrylic acid - 2-acrylamido-2-methylpropane sulfonic acid)/Attapulgite based on carboxymethyl cellulose (CMC) and inorganic clay Attapulgite (ATP) was prepared via a grafting copolymerization of acrylic acid (AA) and 2-acrylamido-2-methylpropanesulfonic acid (AMPS), using with N, N-methylenebisacrylamide (MBA) as a cross-linking agent, ammonium persulfate (APS) as an initiator and polyethylene glycol(PEG) as a phase transfer catalyst. The effects of polymerization conditions on the swelling ability of the superabsorbent composite were investigated. The results indicated that the prepared superabsorbent had high water absorbency. Saturated water absorbencies of the superabsorbent reached (864 g.g-1) for distilled water and (72 g.g-1) for 0.9 wt% NaCl aqueous solution respectively. The water absorbency of the composites was dependent on the pH of external solutions and used saline solutions.},
 year = {2016}
}

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TY  - JOUR
T1  - Preparation of Carboxymethyl Cellulose-g-Poly (Acrylic Acid - 2-Acrylamido-2-Methylpropane Sulfonic Acid)/Attapulgite Superabsorbent Composite
AU  - Fathelrahman Mohammed Soliman
AU  - Wu Yang
AU  - Hao Guo
AU  - Mahgoub Ibrahim Shinger
AU  - Ahmed Mahmoud Idris
AU  - Emtenan Suliman Hassan
Y1  - 2016/09/13
PY  - 2016
N1  - https://doi.org/10.11648/j.ajpst.20160201.12
DO  - 10.11648/j.ajpst.20160201.12
T2  - American Journal of Polymer Science and Technology
JF  - American Journal of Polymer Science and Technology
JO  - American Journal of Polymer Science and Technology
SP  - 11
EP  - 19
PB  - Science Publishing Group
SN  - 2575-5986
UR  - https://doi.org/10.11648/j.ajpst.20160201.12
AB  - An eco-friendly high-swelling superabsorbent composite CMC-g-poly(acrylic acid - 2-acrylamido-2-methylpropane sulfonic acid)/Attapulgite based on carboxymethyl cellulose (CMC) and inorganic clay Attapulgite (ATP) was prepared via a grafting copolymerization of acrylic acid (AA) and 2-acrylamido-2-methylpropanesulfonic acid (AMPS), using with N, N-methylenebisacrylamide (MBA) as a cross-linking agent, ammonium persulfate (APS) as an initiator and polyethylene glycol(PEG) as a phase transfer catalyst. The effects of polymerization conditions on the swelling ability of the superabsorbent composite were investigated. The results indicated that the prepared superabsorbent had high water absorbency. Saturated water absorbencies of the superabsorbent reached (864 g.g-1) for distilled water and (72 g.g-1) for 0.9 wt% NaCl aqueous solution respectively. The water absorbency of the composites was dependent on the pH of external solutions and used saline solutions.
VL  - 2
IS  - 1
ER  -

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Author Information

Fathelrahman Mohammed Soliman

Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Wu Yang

Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Hao Guo

Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Mahgoub Ibrahim Shinger

Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Ahmed Mahmoud Idris

Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China
Emtenan Suliman Hassan

Key Lab of Eco-environment Related Polymer Materials of MOE, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, China

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Fathelrahman Mohammed Soliman, Wu Yang, Hao Guo, Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, et al. (2016). Preparation of Carboxymethyl Cellulose-g-Poly (Acrylic Acid - 2-Acrylamido-2-Methylpropane Sulfonic Acid)/Attapulgite Superabsorbent Composite. American Journal of Polymer Science and Technology, 2(1), 11-19. https://doi.org/10.11648/j.ajpst.20160201.12

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ACS Style

Fathelrahman Mohammed Soliman; Wu Yang; Hao Guo; Mahgoub Ibrahim Shinger; Ahmed Mahmoud Idris, et al. Preparation of Carboxymethyl Cellulose-g-Poly (Acrylic Acid - 2-Acrylamido-2-Methylpropane Sulfonic Acid)/Attapulgite Superabsorbent Composite. Am. J. Polym. Sci. Technol. 2016, 2(1), 11-19. doi: 10.11648/j.ajpst.20160201.12

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AMA Style

Fathelrahman Mohammed Soliman, Wu Yang, Hao Guo, Mahgoub Ibrahim Shinger, Ahmed Mahmoud Idris, et al. Preparation of Carboxymethyl Cellulose-g-Poly (Acrylic Acid - 2-Acrylamido-2-Methylpropane Sulfonic Acid)/Attapulgite Superabsorbent Composite. Am J Polym Sci Technol. 2016;2(1):11-19. doi: 10.11648/j.ajpst.20160201.12

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@article{10.11648/j.ajpst.20160201.12,
  author = {Fathelrahman Mohammed Soliman and Wu Yang and Hao Guo and Mahgoub Ibrahim Shinger and Ahmed Mahmoud Idris and Emtenan Suliman Hassan},
  title = {Preparation of Carboxymethyl Cellulose-g-Poly (Acrylic Acid - 2-Acrylamido-2-Methylpropane Sulfonic Acid)/Attapulgite Superabsorbent Composite},
  journal = {American Journal of Polymer Science and Technology},
  volume = {2},
  number = {1},
  pages = {11-19},
  doi = {10.11648/j.ajpst.20160201.12},
  url = {https://doi.org/10.11648/j.ajpst.20160201.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20160201.12},
  abstract = {An eco-friendly high-swelling superabsorbent composite CMC-g-poly(acrylic acid - 2-acrylamido-2-methylpropane sulfonic acid)/Attapulgite based on carboxymethyl cellulose (CMC) and inorganic clay Attapulgite (ATP) was prepared via a grafting copolymerization of acrylic acid (AA) and 2-acrylamido-2-methylpropanesulfonic acid (AMPS), using with N, N-methylenebisacrylamide (MBA) as a cross-linking agent, ammonium persulfate (APS) as an initiator and polyethylene glycol(PEG) as a phase transfer catalyst. The effects of polymerization conditions on the swelling ability of the superabsorbent composite were investigated. The results indicated that the prepared superabsorbent had high water absorbency. Saturated water absorbencies of the superabsorbent reached (864 g.g-1) for distilled water and (72 g.g-1) for 0.9 wt% NaCl aqueous solution respectively. The water absorbency of the composites was dependent on the pH of external solutions and used saline solutions.},
 year = {2016}
}

Copy | Download

TY  - JOUR
T1  - Preparation of Carboxymethyl Cellulose-g-Poly (Acrylic Acid - 2-Acrylamido-2-Methylpropane Sulfonic Acid)/Attapulgite Superabsorbent Composite
AU  - Fathelrahman Mohammed Soliman
AU  - Wu Yang
AU  - Hao Guo
AU  - Mahgoub Ibrahim Shinger
AU  - Ahmed Mahmoud Idris
AU  - Emtenan Suliman Hassan
Y1  - 2016/09/13
PY  - 2016
N1  - https://doi.org/10.11648/j.ajpst.20160201.12
DO  - 10.11648/j.ajpst.20160201.12
T2  - American Journal of Polymer Science and Technology
JF  - American Journal of Polymer Science and Technology
JO  - American Journal of Polymer Science and Technology
SP  - 11
EP  - 19
PB  - Science Publishing Group
SN  - 2575-5986
UR  - https://doi.org/10.11648/j.ajpst.20160201.12
AB  - An eco-friendly high-swelling superabsorbent composite CMC-g-poly(acrylic acid - 2-acrylamido-2-methylpropane sulfonic acid)/Attapulgite based on carboxymethyl cellulose (CMC) and inorganic clay Attapulgite (ATP) was prepared via a grafting copolymerization of acrylic acid (AA) and 2-acrylamido-2-methylpropanesulfonic acid (AMPS), using with N, N-methylenebisacrylamide (MBA) as a cross-linking agent, ammonium persulfate (APS) as an initiator and polyethylene glycol(PEG) as a phase transfer catalyst. The effects of polymerization conditions on the swelling ability of the superabsorbent composite were investigated. The results indicated that the prepared superabsorbent had high water absorbency. Saturated water absorbencies of the superabsorbent reached (864 g.g-1) for distilled water and (72 g.g-1) for 0.9 wt% NaCl aqueous solution respectively. The water absorbency of the composites was dependent on the pH of external solutions and used saline solutions.
VL  - 2
IS  - 1
ER  -

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