Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules

Mauricio Guilherme Vieira; Angélica Machi Lazarin

doi:doi:10.11648/j.ajpst.20160202.15

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Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules

Mauricio Guilherme Vieira, Angélica Machi Lazarin

Published in American Journal of Polymer Science and Technology (Volume 2, Issue 2)

Received: 16 September 2016 Accepted: 2 November 2016 Published: 13 January 2017

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Abstract

This work describes the synthesis and characterization of crystalline lamellar calcium phosphate intercalated with m-aminobenzoic acid (CaP/MABA), and results of a study of adsorption and preconcentration of Zn(II), Ni(II), Co(II) and Cu(II), and in ethanol medium. The adsorption isotherms from ethanol gave the maximum adsorption capacities of 1.43, 1.04, .030 and 0.19 mmol g^-1 for copper, nickel, cobalt and zinc, respectively, which average stability constants followed Zn(II) > Ni(II) > Co(II) > Cu(II); the number of ligands was determined as four for both cations. The results obtained in flow experiments showed a retention and recovery of ca. 100% of the metal ion with packed CaP/MABA columns from solution containing a mixture of these cations.

Published in	American Journal of Polymer Science and Technology (Volume 2, Issue 2)
DOI	10.11648/j.ajpst.20160202.15
Page(s)	47-53
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Inorganic Compounds, Chemical Synthesis, Adsorption, Preconcentration

References

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APA Style

Mauricio Guilherme Vieira, Angélica Machi Lazarin. (2017). Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules. American Journal of Polymer Science and Technology, 2(2), 47-53. https://doi.org/10.11648/j.ajpst.20160202.15

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ACS Style

Mauricio Guilherme Vieira; Angélica Machi Lazarin. Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules. Am. J. Polym. Sci. Technol. 2017, 2(2), 47-53. doi: 10.11648/j.ajpst.20160202.15

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AMA Style

Mauricio Guilherme Vieira, Angélica Machi Lazarin. Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules. Am J Polym Sci Technol. 2017;2(2):47-53. doi: 10.11648/j.ajpst.20160202.15

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@article{10.11648/j.ajpst.20160202.15,
  author = {Mauricio Guilherme Vieira and Angélica Machi Lazarin},
  title = {Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules},
  journal = {American Journal of Polymer Science and Technology},
  volume = {2},
  number = {2},
  pages = {47-53},
  doi = {10.11648/j.ajpst.20160202.15},
  url = {https://doi.org/10.11648/j.ajpst.20160202.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20160202.15},
  abstract = {This work describes the synthesis and characterization of crystalline lamellar calcium phosphate intercalated with m-aminobenzoic acid (CaP/MABA), and results of a study of adsorption and preconcentration of Zn(II), Ni(II), Co(II) and Cu(II), and in ethanol medium. The adsorption isotherms from ethanol gave the maximum adsorption capacities of 1.43, 1.04, .030 and 0.19 mmol g-1 for copper, nickel, cobalt and zinc, respectively, which average stability constants followed Zn(II) > Ni(II) > Co(II) > Cu(II); the number of ligands was determined as four for both cations. The results obtained in flow experiments showed a retention and recovery of ca. 100% of the metal ion with packed CaP/MABA columns from solution containing a mixture of these cations.},
 year = {2017}
}

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TY  - JOUR
T1  - Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules
AU  - Mauricio Guilherme Vieira
AU  - Angélica Machi Lazarin
Y1  - 2017/01/13
PY  - 2017
N1  - https://doi.org/10.11648/j.ajpst.20160202.15
DO  - 10.11648/j.ajpst.20160202.15
T2  - American Journal of Polymer Science and Technology
JF  - American Journal of Polymer Science and Technology
JO  - American Journal of Polymer Science and Technology
SP  - 47
EP  - 53
PB  - Science Publishing Group
SN  - 2575-5986
UR  - https://doi.org/10.11648/j.ajpst.20160202.15
AB  - This work describes the synthesis and characterization of crystalline lamellar calcium phosphate intercalated with m-aminobenzoic acid (CaP/MABA), and results of a study of adsorption and preconcentration of Zn(II), Ni(II), Co(II) and Cu(II), and in ethanol medium. The adsorption isotherms from ethanol gave the maximum adsorption capacities of 1.43, 1.04, .030 and 0.19 mmol g-1 for copper, nickel, cobalt and zinc, respectively, which average stability constants followed Zn(II) > Ni(II) > Co(II) > Cu(II); the number of ligands was determined as four for both cations. The results obtained in flow experiments showed a retention and recovery of ca. 100% of the metal ion with packed CaP/MABA columns from solution containing a mixture of these cations.
VL  - 2
IS  - 2
ER  -

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Author Information

Mauricio Guilherme Vieira

Department of Chemistry, State University of Maringá, Avenue Colombo, Maringá, PR, Brazil
Angélica Machi Lazarin

Department of Chemistry, State University of Maringá, Avenue Colombo, Maringá, PR, Brazil

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APA Style

Mauricio Guilherme Vieira, Angélica Machi Lazarin. (2017). Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules. American Journal of Polymer Science and Technology, 2(2), 47-53. https://doi.org/10.11648/j.ajpst.20160202.15

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ACS Style

Mauricio Guilherme Vieira; Angélica Machi Lazarin. Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules. Am. J. Polym. Sci. Technol. 2017, 2(2), 47-53. doi: 10.11648/j.ajpst.20160202.15

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AMA Style

Mauricio Guilherme Vieira, Angélica Machi Lazarin. Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules. Am J Polym Sci Technol. 2017;2(2):47-53. doi: 10.11648/j.ajpst.20160202.15

Copy | Download

@article{10.11648/j.ajpst.20160202.15,
  author = {Mauricio Guilherme Vieira and Angélica Machi Lazarin},
  title = {Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules},
  journal = {American Journal of Polymer Science and Technology},
  volume = {2},
  number = {2},
  pages = {47-53},
  doi = {10.11648/j.ajpst.20160202.15},
  url = {https://doi.org/10.11648/j.ajpst.20160202.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20160202.15},
  abstract = {This work describes the synthesis and characterization of crystalline lamellar calcium phosphate intercalated with m-aminobenzoic acid (CaP/MABA), and results of a study of adsorption and preconcentration of Zn(II), Ni(II), Co(II) and Cu(II), and in ethanol medium. The adsorption isotherms from ethanol gave the maximum adsorption capacities of 1.43, 1.04, .030 and 0.19 mmol g-1 for copper, nickel, cobalt and zinc, respectively, which average stability constants followed Zn(II) > Ni(II) > Co(II) > Cu(II); the number of ligands was determined as four for both cations. The results obtained in flow experiments showed a retention and recovery of ca. 100% of the metal ion with packed CaP/MABA columns from solution containing a mixture of these cations.},
 year = {2017}
}

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TY  - JOUR
T1  - Adsorption of Metallic Ions in Lamellar Crystalline Compounds Intercalated with Organic Molecules
AU  - Mauricio Guilherme Vieira
AU  - Angélica Machi Lazarin
Y1  - 2017/01/13
PY  - 2017
N1  - https://doi.org/10.11648/j.ajpst.20160202.15
DO  - 10.11648/j.ajpst.20160202.15
T2  - American Journal of Polymer Science and Technology
JF  - American Journal of Polymer Science and Technology
JO  - American Journal of Polymer Science and Technology
SP  - 47
EP  - 53
PB  - Science Publishing Group
SN  - 2575-5986
UR  - https://doi.org/10.11648/j.ajpst.20160202.15
AB  - This work describes the synthesis and characterization of crystalline lamellar calcium phosphate intercalated with m-aminobenzoic acid (CaP/MABA), and results of a study of adsorption and preconcentration of Zn(II), Ni(II), Co(II) and Cu(II), and in ethanol medium. The adsorption isotherms from ethanol gave the maximum adsorption capacities of 1.43, 1.04, .030 and 0.19 mmol g-1 for copper, nickel, cobalt and zinc, respectively, which average stability constants followed Zn(II) > Ni(II) > Co(II) > Cu(II); the number of ligands was determined as four for both cations. The results obtained in flow experiments showed a retention and recovery of ca. 100% of the metal ion with packed CaP/MABA columns from solution containing a mixture of these cations.
VL  - 2
IS  - 2
ER  -

Copy | Download