Reactions of Immobilized Palladium (II) Complexes with Carbon Monoxide

Alexander Fedorovich Novikov

doi:doi:10.11648/j.cbe.20160101.11

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Reactions of Immobilized Palladium (II) Complexes with Carbon Monoxide

Alexander Fedorovich Novikov

Published in Chemical and Biomolecular Engineering (Volume 1, Issue 1)

Received: 15 March 2016 Accepted: 11 April 2016 Published: 9 May 2016

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Abstract

Palladium (II) complex compounds were immobilized on the dried inner surface of nanoporous silicate glass. The solid specimens containing the Pd(II) salts and organic complexes were fabricated and tested in respect to their spectral reaction on carbon monoxide in atmosphere. The specimens have demonstrated reversible color changes while interacting with carbon monoxide. The reaction mechanisms are supposed to be connected with formation and dissociation of the coordination compounds on the pore surface. Chemical interpretation of the processes is given.

Published in	Chemical and Biomolecular Engineering (Volume 1, Issue 1)
DOI	10.11648/j.cbe.20160101.11
Page(s)	1-4
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2016. Published by Science Publishing Group

Keywords

Palladium (II) Complex Compounds, Carbon Monoxide, Spectrochemistry of Surface Complexes

References

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[2]	S. A. Livingstone, The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium, and Platinum. Oxford: Pergamon Press, 1973.
[3]	T. H. Allen, W. S. Root, ― Colorimetric Determination of Carbon Monoxide in Air by an Improved Palladium Chloride Method, ‖ J. Biol. Chem., vol. 216(1), pp. 309–317, 1955.
[4]	F. Yanowski, W. Heyer, Poröse Gläser. Herstellung, Eigenschaften, Anwendung. 1ste Auflage. Leipzig: VEB Deutscher Verlag fűr Grundstoffindustrie, 1981.
[5]	D. Enke, F. Janowski, W. Schwieger, ―Porous glasses in the 21st century − a short review, ‖ Microporous and Mesoporous Materials, vol. 60(1−3), pp. 19−30, 2003.
[6]	P. B. Macedo, T. A. Litovits, Method of precipitation of dopants in a porous silicate glass, ―Patent USA No. 4110096, publ. 29.08.78.
[7]	A. F. Novikov, ―Nanoporous silica glass sensibilisation in respect to the gas components detection, ‖ Optica Applicata, vol. 38(1), 2008, pp. 65-69.
[8]	T. H. Elmer, Porous and Reconstructed Glasses. In: S. J. Schneider (ed.). Engineered Materials Handbook (4): Ceramics and Glasses. Materials Park, OH: ASM International. 1991, pp, 427–432.
[9]	A. F. Novikov, ―Characterization of the inner structure and surface of nano-porous sodium-borate-silicate glasses. ‖ Optica Applicata, vol. 35(4), 2005, pp. 702-708.
[10]	T. Basche (ed.), Single-Molecule Optical Detection, Imaging, and Spectroscopy, VCH Publ., 1997.
[11]	S. Gregg, C. Sing, Adsorption, Surface Area & Porosity, L. – N.Y.: Academic Press, 1967.
[12]	A. B. P. Lever, Inorganic Electronic Spectroscopy, 2nd ed., part 2, section 6.2.8. Amsterdam etc.: Elsevier, ser. Studies in Physical and Theoretical Chemistry 33, 1985.
[13]	R. M. Rush, D. S. Martin, Jr., R. G. Le Grand, Electronic spectra of the Pd complexes. ‖ Inorg. Chem., vol. 10, 1975, pp. 2543–2550.
[14]	P. M. Maitlis, The Organic Chemistry of Palladium. N. Y.: Academic Press, 1971.
[15]	J. P. Candlin, K. A. Taylor, D. T. Thompson, Reactions of Transition-Metal Complexes. N. Y.: Elsevier, 1968.
[16]	R. G. Pearson. Hard and Soft Acids and Bases. ‖ Journ. Amer. Chem. Soc., vol. 85, № 22, 1963. pp. 3533-3539.
[17]	R. G. Pearson (ed.), Hard and Soft Acids and Bases. Northwestern Univ. Dowden, Hutchinson & Ross, Inc. Stroutburg, Penn.: Benchmark in Inorganic Chemistry, 1973.

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Alexander Fedorovich Novikov. (2016). Reactions of Immobilized Palladium (II) Complexes with Carbon Monoxide. Chemical and Biomolecular Engineering, 1(1), 1-4. https://doi.org/10.11648/j.cbe.20160101.11

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Alexander Fedorovich Novikov. Reactions of Immobilized Palladium (II) Complexes with Carbon Monoxide. Chem. Biomol. Eng. 2016, 1(1), 1-4. doi: 10.11648/j.cbe.20160101.11

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Alexander Fedorovich Novikov. Reactions of Immobilized Palladium (II) Complexes with Carbon Monoxide. Chem Biomol Eng. 2016;1(1):1-4. doi: 10.11648/j.cbe.20160101.11

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@article{10.11648/j.cbe.20160101.11,
  author = {Alexander Fedorovich Novikov},
  title = {Reactions of Immobilized Palladium (II) Complexes with Carbon Monoxide},
  journal = {Chemical and Biomolecular Engineering},
  volume = {1},
  number = {1},
  pages = {1-4},
  doi = {10.11648/j.cbe.20160101.11},
  url = {https://doi.org/10.11648/j.cbe.20160101.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.cbe.20160101.11},
  abstract = {Palladium (II) complex compounds were immobilized on the dried inner surface of nanoporous silicate glass. The solid specimens containing the Pd(II) salts and organic complexes were fabricated and tested in respect to their spectral reaction on carbon monoxide in atmosphere. The specimens have demonstrated reversible color changes while interacting with carbon monoxide. The reaction mechanisms are supposed to be connected with formation and dissociation of the coordination compounds on the pore surface. Chemical interpretation of the processes is given.},
 year = {2016}
}

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TY  - JOUR
T1  - Reactions of Immobilized Palladium (II) Complexes with Carbon Monoxide
AU  - Alexander Fedorovich Novikov
Y1  - 2016/05/09
PY  - 2016
N1  - https://doi.org/10.11648/j.cbe.20160101.11
DO  - 10.11648/j.cbe.20160101.11
T2  - Chemical and Biomolecular Engineering
JF  - Chemical and Biomolecular Engineering
JO  - Chemical and Biomolecular Engineering
SP  - 1
EP  - 4
PB  - Science Publishing Group
SN  - 2578-8884
UR  - https://doi.org/10.11648/j.cbe.20160101.11
AB  - Palladium (II) complex compounds were immobilized on the dried inner surface of nanoporous silicate glass. The solid specimens containing the Pd(II) salts and organic complexes were fabricated and tested in respect to their spectral reaction on carbon monoxide in atmosphere. The specimens have demonstrated reversible color changes while interacting with carbon monoxide. The reaction mechanisms are supposed to be connected with formation and dissociation of the coordination compounds on the pore surface. Chemical interpretation of the processes is given.
VL  - 1
IS  - 1
ER  -

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Author Information

Alexander Fedorovich Novikov

Saint Petersburg National Research University of Information Technologies, Mechanics and Optics (ITMO University), Saint Petersburg, Russia

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Alexander Fedorovich Novikov. (2016). Reactions of Immobilized Palladium (II) Complexes with Carbon Monoxide. Chemical and Biomolecular Engineering, 1(1), 1-4. https://doi.org/10.11648/j.cbe.20160101.11

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ACS Style

Alexander Fedorovich Novikov. Reactions of Immobilized Palladium (II) Complexes with Carbon Monoxide. Chem. Biomol. Eng. 2016, 1(1), 1-4. doi: 10.11648/j.cbe.20160101.11

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AMA Style

Alexander Fedorovich Novikov. Reactions of Immobilized Palladium (II) Complexes with Carbon Monoxide. Chem Biomol Eng. 2016;1(1):1-4. doi: 10.11648/j.cbe.20160101.11

Copy | Download

@article{10.11648/j.cbe.20160101.11,
  author = {Alexander Fedorovich Novikov},
  title = {Reactions of Immobilized Palladium (II) Complexes with Carbon Monoxide},
  journal = {Chemical and Biomolecular Engineering},
  volume = {1},
  number = {1},
  pages = {1-4},
  doi = {10.11648/j.cbe.20160101.11},
  url = {https://doi.org/10.11648/j.cbe.20160101.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.cbe.20160101.11},
  abstract = {Palladium (II) complex compounds were immobilized on the dried inner surface of nanoporous silicate glass. The solid specimens containing the Pd(II) salts and organic complexes were fabricated and tested in respect to their spectral reaction on carbon monoxide in atmosphere. The specimens have demonstrated reversible color changes while interacting with carbon monoxide. The reaction mechanisms are supposed to be connected with formation and dissociation of the coordination compounds on the pore surface. Chemical interpretation of the processes is given.},
 year = {2016}
}

Copy | Download

TY  - JOUR
T1  - Reactions of Immobilized Palladium (II) Complexes with Carbon Monoxide
AU  - Alexander Fedorovich Novikov
Y1  - 2016/05/09
PY  - 2016
N1  - https://doi.org/10.11648/j.cbe.20160101.11
DO  - 10.11648/j.cbe.20160101.11
T2  - Chemical and Biomolecular Engineering
JF  - Chemical and Biomolecular Engineering
JO  - Chemical and Biomolecular Engineering
SP  - 1
EP  - 4
PB  - Science Publishing Group
SN  - 2578-8884
UR  - https://doi.org/10.11648/j.cbe.20160101.11
AB  - Palladium (II) complex compounds were immobilized on the dried inner surface of nanoporous silicate glass. The solid specimens containing the Pd(II) salts and organic complexes were fabricated and tested in respect to their spectral reaction on carbon monoxide in atmosphere. The specimens have demonstrated reversible color changes while interacting with carbon monoxide. The reaction mechanisms are supposed to be connected with formation and dissociation of the coordination compounds on the pore surface. Chemical interpretation of the processes is given.
VL  - 1
IS  - 1
ER  -

Copy | Download