The Application of Modified Graphene with KH570 Used in Semiconductive Shielding Material of Power Cable

Hetian Ying; Zuoguo Yang; Yifei Wang; Ming Zhu; Yiyi Yao; Lecai Zeng

doi:doi:10.11648/j.cbe.20170203.14

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The Application of Modified Graphene with KH570 Used in Semiconductive Shielding Material of Power Cable

Hetian Ying, Zuoguo Yang, Yifei Wang, Ming Zhu, Yiyi Yao, Lecai Zeng

Published in Chemical and Biomolecular Engineering (Volume 2, Issue 3)

Received: 13 January 2017 Accepted: 11 May 2017 Published: 10 July 2017

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Abstract

In order to reduce the content of conductive filler and improve the smoothness of semiconductive shielding layer of power cable, Graphene was used as a better kind of conductive filler to replace a part of carbon black (CB). In the meantime, in order to improve the consistency between the graphene and ethylene-vinyl acetate copolymer (EVA), γ-methacryloxypropyl trimethoxy silane (KH570) was used to modify the graphene. The result shows that modified reduced graphene oxide (MrGO) has a better compatibility and dispersability with EVA matrix. A qualified composite can be obtained only by adding 6% of MrGO and 10% of CB, compared with traditional semiconductive shielding material, the conductive filler content of which has been reduced greatly. In addition, this kind of new material has a good mechanical, electrical, thermal properties.

Published in	Chemical and Biomolecular Engineering (Volume 2, Issue 3)
DOI	10.11648/j.cbe.20170203.14
Page(s)	152-158
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Modified Grapheme, Semiconductive Shielding Material, KH570, EVA

References

[1]	Boggs, Steven A. 500 Ω-m low enough resistivity for a cable ground shield semicon? IEEE Electrical Insulation Magazine, 2001;17:26-32.
[2]	Burns N M, Eichhorn R M, Reid C G. Stress controlling semiconductive shields in medium voltage power distribution cables. Electrical Insulation Magazine, IEEE. 1992;8:8-24.
[3]	Park S, He S, Wang J, et al. Graphene-polyethylene nanocomposites: Effect of graphene functionalization. Polymer. 2006;104:1-9.
[4]	Gargan K, Raju A, Peter C, et al. Graphene/polyurethane composites: fabrication and evaluation of electrical conductivity, mechanical properties and cell viability. RSC Advances. 2015;5:98762-98772.
[5]	Xiao S J, Yu S W, Tan X Y. Study on preparation and properties of EVA/graphene composites. Chemistry Word. 2015;8:501-505.
[6]	Kotal M, Banerjee S S, Bhowmick A K. Functionalized graphene with polymer as unique strategy in tailoring the properties of bromobutyl rubber nanocomposites. Polymer. 2016;82:121-132.
[7]	Fu J F, Zong P S, Chen L Y, et al. A Facile Approach to Covalently Functionalized Graphene Nanosheet Hybrids and Polymer Nanocomposites. ACES. 2016;2: 830-839.
[8]	Yang W, Miao J, Xia R, et al. On surface modification of nano-TiN with graft copolymer LMPB-g-KH570. Journal of Dispersion Science and Technology. 2012;33:827-834.
[9]	Moon I K, Lee J, Rodney S, et al. Reduced graphene oxide by chemical graphitization. Nature Communications.2010;1:73-79.
[10]	Shao L S, Li J J, Guang Y, et al. PVA/polyethyleneimine-functionalized graphene composites with optimized properties. Materials and Design. 2016;99:235-242.
[11]	Halder A, Zhang M W, Chi Q J. Electroactive and biocompatible functionalization of graphene for the development of biosensing platforms. Biosensors and Bioelectronics. 2017;87:764-771.
[12]	Shi J J, Ma W S, Lin X D. Synthesis and characterization of functionalized graphene with KH-570. Chinese Journal of Inorganic Chemistry. 2012;28:131-136.
[13]	Halder A, Zhang M W, Chi Q J. Electroactive and biocompatible functionalization of graphene for the development of biosensing platforms. Biosensors and Bioelectronics. 2017;87:764-771.
[14]	Maultzsch J, Reich S, Thomsen C, et al. Phonon dispersion in graphite. Physical Review Letters. 2004;92:075501.
[15]	Ferrari A C, Robertson J. Interpretation of Raman spectra of disordered and amorphous carbon. Physical Review. Series B. 2000;61:14095-14107.
[16]	Ganganahalli, Ramesha K, Sampath S. Electrochemical reduction of oriented graphene oxide films: an in situ Raman spectroelectrochemical study. The Journal of Physical Chemistry. C. 2009;113:7985-7989.
[17]	Ramanathan T, Stankovich S, Dikin D A, et al. Graphitic nanofillers in PMMA nanocomposites - an investigation of particle size influence on nanocomposite and dispersion and their properties. Journal of Polymer Science Part B: Polymer Physics. 2007;45:2097-2112.
[18]	Chen H Y, Chen M, Du C Y, et al. Synthesis and electrochemical performance of hierarchical nanocomposite of carbon coated LiCoPO4 crosslinked by graphene. Materials Chemistry and Physics. 2016;171:6-10.
[19]	Mallakpour S, Madani M. The Effect of the coupling agents KH550 and KH570 on the nanostructure and interfacial interaction of zinc oxide/chiral poly(amide–imide) nanocomposites containing L-leucine amino acid moieties. Journal of Materials Science. 2014;49:5112-5118.
[20]	Wu G H, Liu S Q, Wu X Y, et al. Influence of MWCNTs modified by silane coupling agent KH570 on the properties and structure of MWCNTs/PLA composite film. Journal of Polymer Research. 2016;23:155-163.
[21]	Valentinia L, Bona S B, Lopez-Manchadob M A, et al. Synergistic effect of graphene nanoplatelets and carbon black in multifunctional EPDM nanocomposites. Composites Science and Technology. 2016;128:123-130.
[22]	Iliut M, Silva C, Herrick S, et al. Graphene and water-based elastomers thin-film composites by dipmoulding. Carbon. 2016;106:228-232.
[23]	Li J Q, Xiao P T, Li H F, et al. Crystalline structures and crystallization behaviors of poly(L-lactide) in poly(L-lactide)/graphene nanosheet composites. Polymer Chemistry. 2015;6:3988-4002.
[24]	Kim J H, Lee S W, Kim B C, et al. Effect of VA and MWNT contents on the rheological and physical properties of EVA. Korea-Australia Rheology Journal. 2016;28:41-49.
[25]	Chae D W, Kim B C, Kim D K. Effects of shearing and comonomer content on the crystallization behavior of poly (butylene succinate-co-butylene 2-ethyl-2-methyl succinate). Polymer. 2004;53:1266-1273.

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APA Style

Hetian Ying, Zuoguo Yang, Yifei Wang, Ming Zhu, Yiyi Yao, et al. (2017). The Application of Modified Graphene with KH570 Used in Semiconductive Shielding Material of Power Cable. Chemical and Biomolecular Engineering, 2(3), 152-158. https://doi.org/10.11648/j.cbe.20170203.14

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ACS Style

Hetian Ying; Zuoguo Yang; Yifei Wang; Ming Zhu; Yiyi Yao, et al. The Application of Modified Graphene with KH570 Used in Semiconductive Shielding Material of Power Cable. Chem. Biomol. Eng. 2017, 2(3), 152-158. doi: 10.11648/j.cbe.20170203.14

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AMA Style

Hetian Ying, Zuoguo Yang, Yifei Wang, Ming Zhu, Yiyi Yao, et al. The Application of Modified Graphene with KH570 Used in Semiconductive Shielding Material of Power Cable. Chem Biomol Eng. 2017;2(3):152-158. doi: 10.11648/j.cbe.20170203.14

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@article{10.11648/j.cbe.20170203.14,
  author = {Hetian Ying and Zuoguo Yang and Yifei Wang and Ming Zhu and Yiyi Yao and Lecai Zeng},
  title = {The Application of Modified Graphene with KH570 Used in Semiconductive Shielding Material of Power Cable},
  journal = {Chemical and Biomolecular Engineering},
  volume = {2},
  number = {3},
  pages = {152-158},
  doi = {10.11648/j.cbe.20170203.14},
  url = {https://doi.org/10.11648/j.cbe.20170203.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.cbe.20170203.14},
  abstract = {In order to reduce the content of conductive filler and improve the smoothness of semiconductive shielding layer of power cable, Graphene was used as a better kind of conductive filler to replace a part of carbon black (CB). In the meantime, in order to improve the consistency between the graphene and ethylene-vinyl acetate copolymer (EVA), γ-methacryloxypropyl trimethoxy silane (KH570) was used to modify the graphene. The result shows that modified reduced graphene oxide (MrGO) has a better compatibility and dispersability with EVA matrix. A qualified composite can be obtained only by adding 6% of MrGO and 10% of CB, compared with traditional semiconductive shielding material, the conductive filler content of which has been reduced greatly. In addition, this kind of new material has a good mechanical, electrical, thermal properties.},
 year = {2017}
}

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TY  - JOUR
T1  - The Application of Modified Graphene with KH570 Used in Semiconductive Shielding Material of Power Cable
AU  - Hetian Ying
AU  - Zuoguo Yang
AU  - Yifei Wang
AU  - Ming Zhu
AU  - Yiyi Yao
AU  - Lecai Zeng
Y1  - 2017/07/10
PY  - 2017
N1  - https://doi.org/10.11648/j.cbe.20170203.14
DO  - 10.11648/j.cbe.20170203.14
T2  - Chemical and Biomolecular Engineering
JF  - Chemical and Biomolecular Engineering
JO  - Chemical and Biomolecular Engineering
SP  - 152
EP  - 158
PB  - Science Publishing Group
SN  - 2578-8884
UR  - https://doi.org/10.11648/j.cbe.20170203.14
AB  - In order to reduce the content of conductive filler and improve the smoothness of semiconductive shielding layer of power cable, Graphene was used as a better kind of conductive filler to replace a part of carbon black (CB). In the meantime, in order to improve the consistency between the graphene and ethylene-vinyl acetate copolymer (EVA), γ-methacryloxypropyl trimethoxy silane (KH570) was used to modify the graphene. The result shows that modified reduced graphene oxide (MrGO) has a better compatibility and dispersability with EVA matrix. A qualified composite can be obtained only by adding 6% of MrGO and 10% of CB, compared with traditional semiconductive shielding material, the conductive filler content of which has been reduced greatly. In addition, this kind of new material has a good mechanical, electrical, thermal properties.
VL  - 2
IS  - 3
ER  -

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Author Information

Hetian Ying

School of Chemical Engineering, East China University of Science and Technology, Shanghai, China
Zuoguo Yang

School of Chemical Engineering, East China University of Science and Technology, Shanghai, China
Yifei Wang

Central Academe, Shanghai Electric Group Co., Ltd., Shanghai, China
Ming Zhu

Central Academe, Shanghai Electric Group Co., Ltd., Shanghai, China
Yiyi Yao

Central Academe, Shanghai Electric Group Co., Ltd., Shanghai, China
Lecai Zeng

Central Academe, Shanghai Electric Group Co., Ltd., Shanghai, China

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Plain Text BibTeX RIS

APA Style

Hetian Ying, Zuoguo Yang, Yifei Wang, Ming Zhu, Yiyi Yao, et al. (2017). The Application of Modified Graphene with KH570 Used in Semiconductive Shielding Material of Power Cable. Chemical and Biomolecular Engineering, 2(3), 152-158. https://doi.org/10.11648/j.cbe.20170203.14

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ACS Style

Hetian Ying; Zuoguo Yang; Yifei Wang; Ming Zhu; Yiyi Yao, et al. The Application of Modified Graphene with KH570 Used in Semiconductive Shielding Material of Power Cable. Chem. Biomol. Eng. 2017, 2(3), 152-158. doi: 10.11648/j.cbe.20170203.14

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AMA Style

Hetian Ying, Zuoguo Yang, Yifei Wang, Ming Zhu, Yiyi Yao, et al. The Application of Modified Graphene with KH570 Used in Semiconductive Shielding Material of Power Cable. Chem Biomol Eng. 2017;2(3):152-158. doi: 10.11648/j.cbe.20170203.14

Copy | Download

@article{10.11648/j.cbe.20170203.14,
  author = {Hetian Ying and Zuoguo Yang and Yifei Wang and Ming Zhu and Yiyi Yao and Lecai Zeng},
  title = {The Application of Modified Graphene with KH570 Used in Semiconductive Shielding Material of Power Cable},
  journal = {Chemical and Biomolecular Engineering},
  volume = {2},
  number = {3},
  pages = {152-158},
  doi = {10.11648/j.cbe.20170203.14},
  url = {https://doi.org/10.11648/j.cbe.20170203.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.cbe.20170203.14},
  abstract = {In order to reduce the content of conductive filler and improve the smoothness of semiconductive shielding layer of power cable, Graphene was used as a better kind of conductive filler to replace a part of carbon black (CB). In the meantime, in order to improve the consistency between the graphene and ethylene-vinyl acetate copolymer (EVA), γ-methacryloxypropyl trimethoxy silane (KH570) was used to modify the graphene. The result shows that modified reduced graphene oxide (MrGO) has a better compatibility and dispersability with EVA matrix. A qualified composite can be obtained only by adding 6% of MrGO and 10% of CB, compared with traditional semiconductive shielding material, the conductive filler content of which has been reduced greatly. In addition, this kind of new material has a good mechanical, electrical, thermal properties.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - The Application of Modified Graphene with KH570 Used in Semiconductive Shielding Material of Power Cable
AU  - Hetian Ying
AU  - Zuoguo Yang
AU  - Yifei Wang
AU  - Ming Zhu
AU  - Yiyi Yao
AU  - Lecai Zeng
Y1  - 2017/07/10
PY  - 2017
N1  - https://doi.org/10.11648/j.cbe.20170203.14
DO  - 10.11648/j.cbe.20170203.14
T2  - Chemical and Biomolecular Engineering
JF  - Chemical and Biomolecular Engineering
JO  - Chemical and Biomolecular Engineering
SP  - 152
EP  - 158
PB  - Science Publishing Group
SN  - 2578-8884
UR  - https://doi.org/10.11648/j.cbe.20170203.14
AB  - In order to reduce the content of conductive filler and improve the smoothness of semiconductive shielding layer of power cable, Graphene was used as a better kind of conductive filler to replace a part of carbon black (CB). In the meantime, in order to improve the consistency between the graphene and ethylene-vinyl acetate copolymer (EVA), γ-methacryloxypropyl trimethoxy silane (KH570) was used to modify the graphene. The result shows that modified reduced graphene oxide (MrGO) has a better compatibility and dispersability with EVA matrix. A qualified composite can be obtained only by adding 6% of MrGO and 10% of CB, compared with traditional semiconductive shielding material, the conductive filler content of which has been reduced greatly. In addition, this kind of new material has a good mechanical, electrical, thermal properties.
VL  - 2
IS  - 3
ER  -

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