Synthesis of Silver Nanoparticles in Aqueous Solution: Ionic Liquid Used as a Shape Transformer

Rohit L. Vekariya; Abhishek Dhar; Jignesh Lunagariya

doi:doi:10.11648/j.css.20160101.11

| Peer-Reviewed

Synthesis of Silver Nanoparticles in Aqueous Solution: Ionic Liquid Used as a Shape Transformer

Rohit L. Vekariya, Abhishek Dhar, Jignesh Lunagariya

Published in Colloid and Surface Science (Volume 1, Issue 1)

Received: 23 October 2016 Accepted: 14 November 2016 Published: 16 December 2016

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

Silver nanoparticles were synthesized using block copolymer (Pluronic^® P123) spherical micelles as a template. In aqueous Ag⁺ ions may be electrostatically complexed with the anionic surfactant or ionic liquids. The silver ions were reduced in situ by introducing sodium borohydride as a reducing agent. We found that the size of the silver nanoparticles was exclusively depends on the size of block copolymer micelles. Addition of ionic liquid (IL) (1-decyl-3-methyl imidazolium dodecyl sulphate (C₁₀MimDs)) induced sphere – ribbon transition of Silver nanoparticles. The size of the nano ribbon can be tuned by controlling concentration of ionic liquid as well as reducing agents. The silver nanoparticles were observed to be extremely stable in solution suggesting that the modified IL molecules stabilized them. The nanoparticles were characterized by UV-Vis absorbance, dynamic light scattering (DLS) as well as Transmission electron microscope (TEM).

Published in	Colloid and Surface Science (Volume 1, Issue 1)
DOI	10.11648/j.css.20160101.11
Page(s)	1-5
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2016. Published by Science Publishing Group

Keywords

Silver Nanoparticles, Ionic Liquids, Block Copolymer

References

[1]	Alexandridis P; Spontak R. J; cuurr. Opin. Colloid Interface Sci.; 1999, 4, 130.
[2]	Hamley I. W.; Developments in Block copolymer Science and Technology; Hamley I. W. Ed.; John Wiley and Sons Ltd.; Chichester, U. K., 2004.
[3]	Alexandridis P; Olsson U; Lindman B; Langmuir; 1998, 14, 2627.
[4]	Sakai T; Alexandridis P; J. Phys. Chem. B.; 2005, 109, 7766.
[5]	Liu C; Yang X; Yuan H; Zhou Z; Xiao D; Sensor, 2007, 7, 708.
[6]	Abou-Okeil A; Amr A; Abdel-Mohdy A. F.; Carbohyd. Polym.; 2012, 89, 1.
[7]	Hu S; Hsieh Y; Inter. J. Biolog. Macromol.; 2016, 82, 856.
[8]	Velhal S. G; Kulkarni S. D; Latpate R. V.; Int Nano Lett; 2016, DOI 10.1007/s40089-016-0192-9.
[9]	Chowdhury S; Yusof F; Faruck MO; Sulaiman N; Proc. Eng.; 2016, 148, 992.
[10]	Sulochana S; Palaniyandi K; Sivaranjani K; J. Pharm. & Toxic.; 2012, 7, 251.
[11]	Patil R. S.; Kokate M. R.; Salvi P. P.; Kolekar S. S.; C. R. Chimie, 2011, 14, 1122.
[12]	Tran Q. H.; Nguyen V. Q.; Le A.; Adv. Nat. Sci.: Nanosci. Nanotechnol.; 2013, 4, 033001.
[13]	Balan K.; Qing W.; Wang Y.; Liu X.; Palvannan T.; Wang Y.; Maa F; Zhang Y.; RSC Adv., 2016, 6, 40162.
[14]	Guzman M. G.; Dille J.; Godet S.; World Acad. Sci. Eng. Technol.; 2008, 43, 357.
[15]	Safaepour M.; Shahverdi A. R.; Shahverdi H. R.; Khorramizadeh M. R.; Gohari A. R.; Avicenna J. Med. Biotechnol.; 2009, 1, 111.
[16]	Yin H; Yamamoto T; Wada Y; Mater. Chem. Phys.; 2004, 83, 66.
[17]	Navaladian S; Viswanathan B; Viswanath R. P. Nanoscale Res. Lett; 2007, 2, 44.
[18]	Mallick K; Witcomb M. J.; Scurrell M. S.; J. Mater. Sci.; 2004, 39, 4459.
[19]	Vekariya R. L.; JCBPS Section A; 2016, 6, 1133.
[20]	Sreeram K. J.; Nidhin M.; Nair B. U.; Bull. Mater. Sci.; 2008, 31, 937.
[21]	Mandal S.; Arumugam S. K.; Pasricha R.; Sastry M.; Bull. Mater. Sci.; 2005, 28, 503.
[22]	Saxena A.; Tripathi R. M.; Singh R. P.; Digest J. Nanomater. Biostr.; 2010, 5, 427.
[23]	Guo L.; Nei J.; Du B.; Peng Z.; Tesche B.; Kleinermanns K.; J. Colloid Inter. Sci.; 2008, 319, 175.

Cite This Article

Plain Text BibTeX RIS

APA Style

Rohit L. Vekariya, Abhishek Dhar, Jignesh Lunagariya. (2016). Synthesis of Silver Nanoparticles in Aqueous Solution: Ionic Liquid Used as a Shape Transformer. Colloid and Surface Science, 1(1), 1-5. https://doi.org/10.11648/j.css.20160101.11

Copy | Download

ACS Style

Rohit L. Vekariya; Abhishek Dhar; Jignesh Lunagariya. Synthesis of Silver Nanoparticles in Aqueous Solution: Ionic Liquid Used as a Shape Transformer. Colloid Surf. Sci. 2016, 1(1), 1-5. doi: 10.11648/j.css.20160101.11

Copy | Download

AMA Style

Rohit L. Vekariya, Abhishek Dhar, Jignesh Lunagariya. Synthesis of Silver Nanoparticles in Aqueous Solution: Ionic Liquid Used as a Shape Transformer. Colloid Surf Sci. 2016;1(1):1-5. doi: 10.11648/j.css.20160101.11

Copy | Download

@article{10.11648/j.css.20160101.11,
  author = {Rohit L. Vekariya and Abhishek Dhar and Jignesh Lunagariya},
  title = {Synthesis of Silver Nanoparticles in Aqueous Solution: Ionic Liquid Used as a Shape Transformer},
  journal = {Colloid and Surface Science},
  volume = {1},
  number = {1},
  pages = {1-5},
  doi = {10.11648/j.css.20160101.11},
  url = {https://doi.org/10.11648/j.css.20160101.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.css.20160101.11},
  abstract = {Silver nanoparticles were synthesized using block copolymer (Pluronic® P123) spherical micelles as a template. In aqueous Ag+ ions may be electrostatically complexed with the anionic surfactant or ionic liquids. The silver ions were reduced in situ by introducing sodium borohydride as a reducing agent. We found that the size of the silver nanoparticles was exclusively depends on the size of block copolymer micelles. Addition of ionic liquid (IL) (1-decyl-3-methyl imidazolium dodecyl sulphate (C10MimDs)) induced sphere – ribbon transition of Silver nanoparticles. The size of the nano ribbon can be tuned by controlling concentration of ionic liquid as well as reducing agents. The silver nanoparticles were observed to be extremely stable in solution suggesting that the modified IL molecules stabilized them. The nanoparticles were characterized by UV-Vis absorbance, dynamic light scattering (DLS) as well as Transmission electron microscope (TEM).},
 year = {2016}
}

Copy | Download

TY  - JOUR
T1  - Synthesis of Silver Nanoparticles in Aqueous Solution: Ionic Liquid Used as a Shape Transformer
AU  - Rohit L. Vekariya
AU  - Abhishek Dhar
AU  - Jignesh Lunagariya
Y1  - 2016/12/16
PY  - 2016
N1  - https://doi.org/10.11648/j.css.20160101.11
DO  - 10.11648/j.css.20160101.11
T2  - Colloid and Surface Science
JF  - Colloid and Surface Science
JO  - Colloid and Surface Science
SP  - 1
EP  - 5
PB  - Science Publishing Group
SN  - 2578-9236
UR  - https://doi.org/10.11648/j.css.20160101.11
AB  - Silver nanoparticles were synthesized using block copolymer (Pluronic® P123) spherical micelles as a template. In aqueous Ag+ ions may be electrostatically complexed with the anionic surfactant or ionic liquids. The silver ions were reduced in situ by introducing sodium borohydride as a reducing agent. We found that the size of the silver nanoparticles was exclusively depends on the size of block copolymer micelles. Addition of ionic liquid (IL) (1-decyl-3-methyl imidazolium dodecyl sulphate (C10MimDs)) induced sphere – ribbon transition of Silver nanoparticles. The size of the nano ribbon can be tuned by controlling concentration of ionic liquid as well as reducing agents. The silver nanoparticles were observed to be extremely stable in solution suggesting that the modified IL molecules stabilized them. The nanoparticles were characterized by UV-Vis absorbance, dynamic light scattering (DLS) as well as Transmission electron microscope (TEM).
VL  - 1
IS  - 1
ER  -

Copy | Download

Author Information

Rohit L. Vekariya

School of Chemical Engineering, Fuzhou University, Fuzhou, P. R. China
Abhishek Dhar

Department of Chemical Technology, University of Calcutta, Kolkata, India
Jignesh Lunagariya

Department of Chemistry, College of Chemistry and Material Science, Jinan University, Guangzhou, P. R. China

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Rohit L. Vekariya, Abhishek Dhar, Jignesh Lunagariya. (2016). Synthesis of Silver Nanoparticles in Aqueous Solution: Ionic Liquid Used as a Shape Transformer. Colloid and Surface Science, 1(1), 1-5. https://doi.org/10.11648/j.css.20160101.11

Copy | Download

ACS Style

Rohit L. Vekariya; Abhishek Dhar; Jignesh Lunagariya. Synthesis of Silver Nanoparticles in Aqueous Solution: Ionic Liquid Used as a Shape Transformer. Colloid Surf. Sci. 2016, 1(1), 1-5. doi: 10.11648/j.css.20160101.11

Copy | Download

AMA Style

Rohit L. Vekariya, Abhishek Dhar, Jignesh Lunagariya. Synthesis of Silver Nanoparticles in Aqueous Solution: Ionic Liquid Used as a Shape Transformer. Colloid Surf Sci. 2016;1(1):1-5. doi: 10.11648/j.css.20160101.11

Copy | Download

@article{10.11648/j.css.20160101.11,
  author = {Rohit L. Vekariya and Abhishek Dhar and Jignesh Lunagariya},
  title = {Synthesis of Silver Nanoparticles in Aqueous Solution: Ionic Liquid Used as a Shape Transformer},
  journal = {Colloid and Surface Science},
  volume = {1},
  number = {1},
  pages = {1-5},
  doi = {10.11648/j.css.20160101.11},
  url = {https://doi.org/10.11648/j.css.20160101.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.css.20160101.11},
  abstract = {Silver nanoparticles were synthesized using block copolymer (Pluronic® P123) spherical micelles as a template. In aqueous Ag+ ions may be electrostatically complexed with the anionic surfactant or ionic liquids. The silver ions were reduced in situ by introducing sodium borohydride as a reducing agent. We found that the size of the silver nanoparticles was exclusively depends on the size of block copolymer micelles. Addition of ionic liquid (IL) (1-decyl-3-methyl imidazolium dodecyl sulphate (C10MimDs)) induced sphere – ribbon transition of Silver nanoparticles. The size of the nano ribbon can be tuned by controlling concentration of ionic liquid as well as reducing agents. The silver nanoparticles were observed to be extremely stable in solution suggesting that the modified IL molecules stabilized them. The nanoparticles were characterized by UV-Vis absorbance, dynamic light scattering (DLS) as well as Transmission electron microscope (TEM).},
 year = {2016}
}

Copy | Download

TY  - JOUR
T1  - Synthesis of Silver Nanoparticles in Aqueous Solution: Ionic Liquid Used as a Shape Transformer
AU  - Rohit L. Vekariya
AU  - Abhishek Dhar
AU  - Jignesh Lunagariya
Y1  - 2016/12/16
PY  - 2016
N1  - https://doi.org/10.11648/j.css.20160101.11
DO  - 10.11648/j.css.20160101.11
T2  - Colloid and Surface Science
JF  - Colloid and Surface Science
JO  - Colloid and Surface Science
SP  - 1
EP  - 5
PB  - Science Publishing Group
SN  - 2578-9236
UR  - https://doi.org/10.11648/j.css.20160101.11
AB  - Silver nanoparticles were synthesized using block copolymer (Pluronic® P123) spherical micelles as a template. In aqueous Ag+ ions may be electrostatically complexed with the anionic surfactant or ionic liquids. The silver ions were reduced in situ by introducing sodium borohydride as a reducing agent. We found that the size of the silver nanoparticles was exclusively depends on the size of block copolymer micelles. Addition of ionic liquid (IL) (1-decyl-3-methyl imidazolium dodecyl sulphate (C10MimDs)) induced sphere – ribbon transition of Silver nanoparticles. The size of the nano ribbon can be tuned by controlling concentration of ionic liquid as well as reducing agents. The silver nanoparticles were observed to be extremely stable in solution suggesting that the modified IL molecules stabilized them. The nanoparticles were characterized by UV-Vis absorbance, dynamic light scattering (DLS) as well as Transmission electron microscope (TEM).
VL  - 1
IS  - 1
ER  -

Copy | Download