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Effects of Gamma Radiation on the Composition of the Hydrocarbon Mixture Hexane-hexene

Received: 29 October 2019     Accepted: 17 January 2020     Published: 28 June 2020
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Abstract

In work the impact of ionizing radiation on mixes hexane- hexenе was investigated. Laboratory researches were conducted on a gamma source 60Co at the power of dose of P=0.10 of Gy / s in intervals of the absorbed doses D=34-103 kGy. Impact of ionizing radiation on structural and group composition of mix hexane- hexene in static conditions was investigated. Density, viscosity, iodic numbers of mixes hexane- hexenе were determined. before radiation at various absorbed doses. Existence of olefin connections is the main reason for small stability in hydrocarbon fuels. Studying of radiolysis of mixes of saturated and nonsaturated hydrocarbons at various concentration gives the chance to draw conclusions about the nature of the main radiochemical processes. In the fuels containing a large amount of nonsaturated hydrocarbons in the course of radiation the coking behavior increases and color worsens. Structuring is physically shown in organic liquids in change of viscosity and density. The processes which arose in connection with radiolysis for a long time develop after the radiation termination that can lead to change of composition of fuel. As a result of it at ambient temperature operational properties of oil fuels worsen. Communication between the chemical composition of fuel and its stability is still insufficiently well studied. These experiments continue for the purpose of studying of impact of ionizing radiation on changes of physical and chemical properties of hydrocarbons of oil.

Published in Radiation Science and Technology (Volume 6, Issue 2)

This article belongs to the Special Issue Radiolysis of Hexane-Hexene Hydrocarbon Mixture

DOI 10.11648/j.rst.20200602.11
Page(s) 12-18
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Radiolysis, Iodic Numbers, Hexane, Hexene

References
[1] L. Y. Jabbarova, I. Mustafayev. «HIGH-TEMPERATURE RADIOLYSIS OF DIESEL FUEL» Journal of Applied Spectroscopy, Vol. 85, No. 4, 2018, Springer Science+Business Media, LLC p. 686-690.
[2] L. Y. Jabbarova, I. I. Mustafayev, S. Z. Malikova. “Influence of radiation on petroleum fuels”. "International Journal of Applied and Fundamental Research", SIC "Academy of Natural History", Moscow, No. 7 (Part 2) 2017, p. 239-243.
[3] L. Y. Jabbarova, I. I. Mustafayev. Researches of Impact of Ionizing Radiation on Some Characteristics of Diesel Fuel. J. of Energy, Environmental & Chemical Engineering. USA. Volume 2, Issue 4, August 2017, P. 41-45.
[4] I. I Mustafaev,. L. Y. Jabbarova, N. G Gulieva., R. S. Rzaev., and S. F. Alieva. “Effect of Ionizing Radiation on Lube Oil Fractions of Heavy Bituminous Oils.” M.«High Energy Chemistry», 2014, Vol. 48, No. 5, p. 315–320.
[5] I. I. Mustafayev, L. Y. Jabbarova, Z. O. Nabizadeh, N. E. Ibadov. “Study of radiation-chemical transformation of synthetic oil from oil-bituminous rock”. M. “High Energy Chemistry”, 2013, № 6, p. 449-455.
[6] I. I. Mustafaev, L. Y Jabbarova., N. Q., Gulieva K. M. Yagubov. “Radiation thermal refining of oil-bituminous rocks”. Journal of Radioanalytical and Nuclear Chemistry. Budapest, Akademia Kiado, 2004, vol. 262, №2, P. 509-511.
[7] L. Y. Jabbarova, S. M. Aliev, S. Z. Melikova.”The impact of ionizig Radiation on Diezel fuel”. Journal of Radiation Research. Volum 2, № 2, Baku, Azerbaijan, 2015, p. 71-7.
[8] L. Y. Jabbarova., I. I. Mustafaev, Z. O. Nabizade, R. S. Rzayev S. F. Akhmadbayova. “Radiation Chemical Conversion of Oil Derived from Oil–Bitumen Rock.” Chemistry Journal of Moldova. General, Industrial and Ecological Chemistry. 2014, 9 (1), p. 80-84.
[9] L. Y. Jabbarova, N. E. Ibadov. “Alternativ Energy Sources”. Azerbaijan Chemikal. Journal, №3, 2010, p. 128-132.
[10] I. I. Mustafaev., L. Y Jabbarova, N. G. Gulieva, K. M. Yagubov. “Radiation-thermal refining of organic parts of oil-bituminous rocks”. Radiation Safety Problems in the Caspian Region. Kluwer Academic Publishers. Printed in the Nethrlands. 2004, p. 141-146.
[11] L. Y. Jabbarova, I. Mustafayev. “Influence of a Radiation on Technical and Operational Qualities of Petrol”. “Journal of Energy, Environmental & Chemical Engineering.” USA. Vol. 2, No. 4, 2017, p. 62-66.
[12] Tarasevich B. N. IR spectra of the main classes of organic compounds. Reference materials. M. 2012. р. 53.
[13] V. K. Milinchuk “Radiation resistance of organic materials”: Handbook. M.: Energoatomizdat, 1986. Р. 272.
[14] Ibadov N. A., Suleymanov B. A., Gurbanov M. A., Abdullayev E. T., Abbasova D. R. Radiolytic decomposition of polyaromatic carbohydrates//Energy and ecology. 2009. № 5 (73). Page 22-26.
[15] Ponomarev A. V., Civadze A. Y. Conversion of gas-like alkanes into liquid alkanes in case of electronic irradiation//Doc. Academies of Sciences. 2006. T. 411. No. 5. Page 652-658.
[16] Ponomarev A. V., Holodkova E. M., Ershov B. G. Electron-beam synthesis of fuel in the gas phase. Radiation Physics and Chemistry. 2012. V 81. I. 9. P. 1440–1444.
Cite This Article
  • APA Style

    Ramin Akberov, Lala Jabbarova, Islam Mustafayev, Sevinc Melikova. (2020). Effects of Gamma Radiation on the Composition of the Hydrocarbon Mixture Hexane-hexene. Radiation Science and Technology, 6(2), 12-18. https://doi.org/10.11648/j.rst.20200602.11

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    ACS Style

    Ramin Akberov; Lala Jabbarova; Islam Mustafayev; Sevinc Melikova. Effects of Gamma Radiation on the Composition of the Hydrocarbon Mixture Hexane-hexene. Radiat. Sci. Technol. 2020, 6(2), 12-18. doi: 10.11648/j.rst.20200602.11

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    AMA Style

    Ramin Akberov, Lala Jabbarova, Islam Mustafayev, Sevinc Melikova. Effects of Gamma Radiation on the Composition of the Hydrocarbon Mixture Hexane-hexene. Radiat Sci Technol. 2020;6(2):12-18. doi: 10.11648/j.rst.20200602.11

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  • @article{10.11648/j.rst.20200602.11,
      author = {Ramin Akberov and Lala Jabbarova and Islam Mustafayev and Sevinc Melikova},
      title = {Effects of Gamma Radiation on the Composition of the Hydrocarbon Mixture Hexane-hexene},
      journal = {Radiation Science and Technology},
      volume = {6},
      number = {2},
      pages = {12-18},
      doi = {10.11648/j.rst.20200602.11},
      url = {https://doi.org/10.11648/j.rst.20200602.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.rst.20200602.11},
      abstract = {In work the impact of ionizing radiation on mixes hexane- hexenе was investigated. Laboratory researches were conducted on a gamma source 60Co at the power of dose of P=0.10 of Gy / s in intervals of the absorbed doses D=34-103 kGy. Impact of ionizing radiation on structural and group composition of mix hexane- hexene in static conditions was investigated. Density, viscosity, iodic numbers of mixes hexane- hexenе were determined. before radiation at various absorbed doses. Existence of olefin connections is the main reason for small stability in hydrocarbon fuels. Studying of radiolysis of mixes of saturated and nonsaturated hydrocarbons at various concentration gives the chance to draw conclusions about the nature of the main radiochemical processes. In the fuels containing a large amount of nonsaturated hydrocarbons in the course of radiation the coking behavior increases and color worsens. Structuring is physically shown in organic liquids in change of viscosity and density. The processes which arose in connection with radiolysis for a long time develop after the radiation termination that can lead to change of composition of fuel. As a result of it at ambient temperature operational properties of oil fuels worsen. Communication between the chemical composition of fuel and its stability is still insufficiently well studied. These experiments continue for the purpose of studying of impact of ionizing radiation on changes of physical and chemical properties of hydrocarbons of oil.},
     year = {2020}
    }
    

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  • TY  - JOUR
    T1  - Effects of Gamma Radiation on the Composition of the Hydrocarbon Mixture Hexane-hexene
    AU  - Ramin Akberov
    AU  - Lala Jabbarova
    AU  - Islam Mustafayev
    AU  - Sevinc Melikova
    Y1  - 2020/06/28
    PY  - 2020
    N1  - https://doi.org/10.11648/j.rst.20200602.11
    DO  - 10.11648/j.rst.20200602.11
    T2  - Radiation Science and Technology
    JF  - Radiation Science and Technology
    JO  - Radiation Science and Technology
    SP  - 12
    EP  - 18
    PB  - Science Publishing Group
    SN  - 2575-5943
    UR  - https://doi.org/10.11648/j.rst.20200602.11
    AB  - In work the impact of ionizing radiation on mixes hexane- hexenе was investigated. Laboratory researches were conducted on a gamma source 60Co at the power of dose of P=0.10 of Gy / s in intervals of the absorbed doses D=34-103 kGy. Impact of ionizing radiation on structural and group composition of mix hexane- hexene in static conditions was investigated. Density, viscosity, iodic numbers of mixes hexane- hexenе were determined. before radiation at various absorbed doses. Existence of olefin connections is the main reason for small stability in hydrocarbon fuels. Studying of radiolysis of mixes of saturated and nonsaturated hydrocarbons at various concentration gives the chance to draw conclusions about the nature of the main radiochemical processes. In the fuels containing a large amount of nonsaturated hydrocarbons in the course of radiation the coking behavior increases and color worsens. Structuring is physically shown in organic liquids in change of viscosity and density. The processes which arose in connection with radiolysis for a long time develop after the radiation termination that can lead to change of composition of fuel. As a result of it at ambient temperature operational properties of oil fuels worsen. Communication between the chemical composition of fuel and its stability is still insufficiently well studied. These experiments continue for the purpose of studying of impact of ionizing radiation on changes of physical and chemical properties of hydrocarbons of oil.
    VL  - 6
    IS  - 2
    ER  - 

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Author Information
  • Institute of Radiation Problems, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan

  • Institute of Radiation Problems, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan

  • Institute of Radiation Problems, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan

  • Institute of Radiation Problems, National Academy of Sciences of Azerbaijan, Baku, Azerbaijan

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