Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe<sup>3+</sup> Site

Pedro Antonio Mariño-Castellanos; Valery Alexevich Lapshinsky; Carlos Pupo; Arles Vega-García; Eduardo Fernández-Cruz; Braddy Ivan Jimenez-Morales

doi:doi:10.11648/j.ajetm.20190406.12

Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe³⁺ Site

Pedro Antonio Mariño-Castellanos, Valery Alexevich Lapshinsky, Carlos Pupo, Arles Vega-García, Eduardo Fernández-Cruz, Braddy Ivan Jimenez-Morales

Published in American Journal of Engineering and Technology Management (Volume 4, Issue 6)

Received: 29 September 2019 Accepted: 5 November 2019 Published: 2 December 2019

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Abstract

A theoretical and experimental study of magnetic properties of M-type barium hexaferrites, doped with two cations in the Fe³⁺ sites: (Co³⁺, Al³⁺), (Co²⁺, Ti⁴⁺) and (Co²⁺, Sn⁴⁺) is reported. The theoretical predictions were made using the generalization of a model on the distribution of dopants in the crystallographic sites under study. This approach allows a better interpretation of the kinetics of obtaining the samples from the structural and magnetic characterization. In the reported model, the maximum limit refers to theoretical optimum parameters. With these concepts, were established quantitative relationships between dopant amount per crystallographic site and magnetic properties predicted of these systems. The comparison between the experimental values and the predicted magnitudes showed that, in general, the samples were obtained with parameters obtained close to the theoretical ones for traditional ceramic methods. Such an approach is rarely taken into account in the reported bibliography.

Published in	American Journal of Engineering and Technology Management (Volume 4, Issue 6)
DOI	10.11648/j.ajetm.20190406.12
Page(s)	83-90
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Sol-Gel Methods, Magnetic Properties, Hexaferrite, Theoretical Predictions, Rietveld Refinement

References

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[2]	X. Zhang, Y. Zhang, Z. Yue, J. Zhang, “Influences of sintering atmosphere on the magnetic and electrical properties of barium hexaferrites”, AIP Advances 9, 085129 (2019) 1-6.
[3]	R. S. Alam, M. Moradi, M. Rostami, H. Nikmanesh, R. Moayedi, Y. Bai, J. Magn. Magn. Mater. 381 (2015) 1–9.
[4]	P. A. Mariño, “Estudio de la hexaferrita de bario Tipo-M dopada: predicciones y resultados experimentales”, 2012, La Habana Editorial Universitaria ISBN 978-959-16-1960-0.
[5]	H. Nikmanesh, S. Hoghoghifard, B. Hadi-Sichani, “Study of the structural, magnetic, and microwave absorption properties of the simultaneous substitution of several cations in the barium hexaferrite structure”, Journal of Alloys and Compounds 775 (2019) 1101-1108.
[6]	P. A Mariño-Castellanos, A. C. Moreno-Borges, G. Orozco-Melgar, J. A. García and E. Govea-Alcaide, “Structural and magnetic study of the Ti4+-doped barium hexaferrite ceramic samples: Theoretical and experimental results”, Physica B: Condensed Matter 406 (2011) 3130–3136.
[7]	P. A. Mariño, V. A. Lapshinsky, C. Pupo, J. Matilla, and A. Vega, “Obtaining and Structural Characterization of M-type Hexaferrites Doped with Two Cations in the Fe 3+ Sites” in MEPhI’s Section of the Scientific Session on “Breakthrough directions of scientific research at MEPhI: Development prospects within the Strategic Academic Units”, KnE Engineering, (2018), pages 328–335.
[8]	L. Glasser, “Lattice energies of crystals with multiple ions: a generalized Kapustinskii equation”, 1995, Inorg. Chem. 34 4935-4936.
[9]	J. Matilla-Arias, E. Govea-Alcaide, P. Mariño-Castellanos, F. Rosales-Saiz “Phenomenological Model for Prediction of Cation Substitution Distribution and Some Physical Properties in Mn³⁺-Doped Barium Hexaferrite”, J Supercond Nov Magn 31 (2018) 251–256.
[10]	B. B. Rath, “Kinetics of nucleation and growth processes”, July 1995, Materials Science and Engineering: B 32 (3) 101-106.
[11]	J. Matilla-Arias, E. Govea-Alcaide, P. Mariño-Castellanos, F. Rosales-Saiz, I. F. Machado, K. Montero-Rey, “Effects of Lanthanum on Structural and Magnetic Properties of Sr_1−xLa_2x/3Fe₁₂O₁₉ Compounds: Theoretical and Experimental Results”, JSupercondNovMagn (2019) 152-158.
[12]	S. Asiri, S. Güner, A. D. Korkmaz, Md. Amir, K. M. Batoo, M. A. Almessiere, H. Gungunes, H. Sözeri, A. Baykal, “ Magneto-optical properties of BaCryFe12-yO19 (0.0≤ y≤1.0) hexaferrites”, Journal of Magnetism and Magnetic Materials 451 (2018) 463–472
[13]	F. L Wei, H. C. Fang, C. K. Ong, C. S. Wang and Z. Yang, “Magnetic properties of BaFe_12-2xZn_xZr_xO₁₉ particles”, June 2000, J. Appl. Phys. 87 (12) 8636-8639.

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Pedro Antonio Mariño-Castellanos, Valery Alexevich Lapshinsky, Carlos Pupo, Arles Vega-García, Eduardo Fernández-Cruz, et al. (2019). Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site. American Journal of Engineering and Technology Management, 4(6), 83-90. https://doi.org/10.11648/j.ajetm.20190406.12

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ACS Style

Pedro Antonio Mariño-Castellanos; Valery Alexevich Lapshinsky; Carlos Pupo; Arles Vega-García; Eduardo Fernández-Cruz, et al. Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site. Am. J. Eng. Technol. Manag. 2019, 4(6), 83-90. doi: 10.11648/j.ajetm.20190406.12

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AMA Style

Pedro Antonio Mariño-Castellanos, Valery Alexevich Lapshinsky, Carlos Pupo, Arles Vega-García, Eduardo Fernández-Cruz, et al. Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site. Am J Eng Technol Manag. 2019;4(6):83-90. doi: 10.11648/j.ajetm.20190406.12

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@article{10.11648/j.ajetm.20190406.12,
  author = {Pedro Antonio Mariño-Castellanos and Valery Alexevich Lapshinsky and Carlos Pupo and Arles Vega-García and Eduardo Fernández-Cruz and Braddy Ivan Jimenez-Morales},
  title = {Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site},
  journal = {American Journal of Engineering and Technology Management},
  volume = {4},
  number = {6},
  pages = {83-90},
  doi = {10.11648/j.ajetm.20190406.12},
  url = {https://doi.org/10.11648/j.ajetm.20190406.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajetm.20190406.12},
  abstract = {A theoretical and experimental study of magnetic properties of M-type barium hexaferrites, doped with two cations in the Fe3+ sites: (Co3+, Al3+), (Co2+, Ti4+) and (Co2+, Sn4+) is reported. The theoretical predictions were made using the generalization of a model on the distribution of dopants in the crystallographic sites under study. This approach allows a better interpretation of the kinetics of obtaining the samples from the structural and magnetic characterization. In the reported model, the maximum limit refers to theoretical optimum parameters. With these concepts, were established quantitative relationships between dopant amount per crystallographic site and magnetic properties predicted of these systems. The comparison between the experimental values and the predicted magnitudes showed that, in general, the samples were obtained with parameters obtained close to the theoretical ones for traditional ceramic methods. Such an approach is rarely taken into account in the reported bibliography.},
 year = {2019}
}

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TY  - JOUR
T1  - Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site
AU  - Pedro Antonio Mariño-Castellanos
AU  - Valery Alexevich Lapshinsky
AU  - Carlos Pupo
AU  - Arles Vega-García
AU  - Eduardo Fernández-Cruz
AU  - Braddy Ivan Jimenez-Morales
Y1  - 2019/12/02
PY  - 2019
N1  - https://doi.org/10.11648/j.ajetm.20190406.12
DO  - 10.11648/j.ajetm.20190406.12
T2  - American Journal of Engineering and Technology Management
JF  - American Journal of Engineering and Technology Management
JO  - American Journal of Engineering and Technology Management
SP  - 83
EP  - 90
PB  - Science Publishing Group
SN  - 2575-1441
UR  - https://doi.org/10.11648/j.ajetm.20190406.12
AB  - A theoretical and experimental study of magnetic properties of M-type barium hexaferrites, doped with two cations in the Fe3+ sites: (Co3+, Al3+), (Co2+, Ti4+) and (Co2+, Sn4+) is reported. The theoretical predictions were made using the generalization of a model on the distribution of dopants in the crystallographic sites under study. This approach allows a better interpretation of the kinetics of obtaining the samples from the structural and magnetic characterization. In the reported model, the maximum limit refers to theoretical optimum parameters. With these concepts, were established quantitative relationships between dopant amount per crystallographic site and magnetic properties predicted of these systems. The comparison between the experimental values and the predicted magnitudes showed that, in general, the samples were obtained with parameters obtained close to the theoretical ones for traditional ceramic methods. Such an approach is rarely taken into account in the reported bibliography.
VL  - 4
IS  - 6
ER  -

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Author Information

Pedro Antonio Mariño-Castellanos
Valery Alexevich Lapshinsky

Peoples Friendship University of Russia, Moscow, Russian Federation
Carlos Pupo

University of Holguin, Holguin, Cuba; Peoples Friendship University of Russia, Moscow, Russian Federation
Arles Vega-García

University of Holguin, Holguin, Cuba
Eduardo Fernández-Cruz

Department of Physics, University of Camagüey, Camagüey, Cuba
Braddy Ivan Jimenez-Morales

Physics Institute, Kazan Federal University, Kazan, Russian Federation

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APA Style

Pedro Antonio Mariño-Castellanos, Valery Alexevich Lapshinsky, Carlos Pupo, Arles Vega-García, Eduardo Fernández-Cruz, et al. (2019). Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site. American Journal of Engineering and Technology Management, 4(6), 83-90. https://doi.org/10.11648/j.ajetm.20190406.12

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ACS Style

Pedro Antonio Mariño-Castellanos; Valery Alexevich Lapshinsky; Carlos Pupo; Arles Vega-García; Eduardo Fernández-Cruz, et al. Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site. Am. J. Eng. Technol. Manag. 2019, 4(6), 83-90. doi: 10.11648/j.ajetm.20190406.12

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AMA Style

Pedro Antonio Mariño-Castellanos, Valery Alexevich Lapshinsky, Carlos Pupo, Arles Vega-García, Eduardo Fernández-Cruz, et al. Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site. Am J Eng Technol Manag. 2019;4(6):83-90. doi: 10.11648/j.ajetm.20190406.12

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@article{10.11648/j.ajetm.20190406.12,
  author = {Pedro Antonio Mariño-Castellanos and Valery Alexevich Lapshinsky and Carlos Pupo and Arles Vega-García and Eduardo Fernández-Cruz and Braddy Ivan Jimenez-Morales},
  title = {Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site},
  journal = {American Journal of Engineering and Technology Management},
  volume = {4},
  number = {6},
  pages = {83-90},
  doi = {10.11648/j.ajetm.20190406.12},
  url = {https://doi.org/10.11648/j.ajetm.20190406.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajetm.20190406.12},
  abstract = {A theoretical and experimental study of magnetic properties of M-type barium hexaferrites, doped with two cations in the Fe3+ sites: (Co3+, Al3+), (Co2+, Ti4+) and (Co2+, Sn4+) is reported. The theoretical predictions were made using the generalization of a model on the distribution of dopants in the crystallographic sites under study. This approach allows a better interpretation of the kinetics of obtaining the samples from the structural and magnetic characterization. In the reported model, the maximum limit refers to theoretical optimum parameters. With these concepts, were established quantitative relationships between dopant amount per crystallographic site and magnetic properties predicted of these systems. The comparison between the experimental values and the predicted magnitudes showed that, in general, the samples were obtained with parameters obtained close to the theoretical ones for traditional ceramic methods. Such an approach is rarely taken into account in the reported bibliography.},
 year = {2019}
}

Copy | Download

TY  - JOUR
T1  - Predictions and Magnetic Characterization of M-type Hexaferrites Doped with Two Cations in the Fe3+ Site
AU  - Pedro Antonio Mariño-Castellanos
AU  - Valery Alexevich Lapshinsky
AU  - Carlos Pupo
AU  - Arles Vega-García
AU  - Eduardo Fernández-Cruz
AU  - Braddy Ivan Jimenez-Morales
Y1  - 2019/12/02
PY  - 2019
N1  - https://doi.org/10.11648/j.ajetm.20190406.12
DO  - 10.11648/j.ajetm.20190406.12
T2  - American Journal of Engineering and Technology Management
JF  - American Journal of Engineering and Technology Management
JO  - American Journal of Engineering and Technology Management
SP  - 83
EP  - 90
PB  - Science Publishing Group
SN  - 2575-1441
UR  - https://doi.org/10.11648/j.ajetm.20190406.12
AB  - A theoretical and experimental study of magnetic properties of M-type barium hexaferrites, doped with two cations in the Fe3+ sites: (Co3+, Al3+), (Co2+, Ti4+) and (Co2+, Sn4+) is reported. The theoretical predictions were made using the generalization of a model on the distribution of dopants in the crystallographic sites under study. This approach allows a better interpretation of the kinetics of obtaining the samples from the structural and magnetic characterization. In the reported model, the maximum limit refers to theoretical optimum parameters. With these concepts, were established quantitative relationships between dopant amount per crystallographic site and magnetic properties predicted of these systems. The comparison between the experimental values and the predicted magnitudes showed that, in general, the samples were obtained with parameters obtained close to the theoretical ones for traditional ceramic methods. Such an approach is rarely taken into account in the reported bibliography.
VL  - 4
IS  - 6
ER  -

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