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Preparation and Characterisation of Bio-Oil Produced from Sawdust of Selected Wood Species

Received: 22 March 2019    Accepted: 30 April 2019    Published: 21 January 2020
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Abstract

Renewable energy is of growing importance in satisfying environmental concerns over fossil fuel usage. The study was carried out to determine bio-fuel characteristics of pyrolytic oil produce from sawdust of selected wood species (Gmelina arborea, and Nesogordonia papaverifera). Sawdust samples of 200 gramms each were collected from Forestry Research Institute of Nigeria sawmill and oven-dried at 103±2°C for 24 hours to 12% moisture content. While four replicates of bio-oil were produced at each temperature regime for each of the samples, two different temperature regimes were used (500°C and 600°C). The metallic container (pyrolytic chamber) was filled with 200 grammes of the samples of each species and placed inside the Reactor which was connected to a condenser. Using standard test, physical properties, chemical and thermal characterization of bio oil and proximate analysis of the Bio-Char were assessed. Analysis of Variance (ANOVA) in Randomized Complete Block Design (RCBD) was used to ascertain significance difference in the oil yield produced at different temperature. The result shows that there was general increase in the volume of oil yield as the temperature increases. The volume of the oil ranged between 35.97±1.82 to 49.33±3.21 and 52.93±0.51 to 63.63±5.83, the highest and least mean of the pH of pyrolytic oil yield ranged from 3.52±0.02 to 3.54±0.02 and 3.64±0.36 to 3.73±0.01 for G. arborea and N. papaverifera respectively. There was significant difference in the means of the volume of bio-oil obtained as pyrolysis temperture increases. It further shows that the sawmill wood residues differs significantly at P<0.05 within the two temperature regime. The study established that pyrolysis is an efficient way to produce liquid fuels from biomass. The physical properties of the bio-oil obtained from sawmill wood residues falls within the acceptable range for fuel production. The selected wood species are therefore suitable for production of bio-oil with acceptable physical and chemical properties. Based on the result of the study, it is therefore among others recommended that residence time be taken for each temperature range to convert the feedstock to oil, and quantity of oil yield per specie.

Published in American Journal of Modern Energy (Volume 6, Issue 1)
DOI 10.11648/j.ajme.20200601.13
Page(s) 16-25
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Temperature, Gmelina Arborea, Pyrolysis, Nesogordonia Papaverifera and Bio-Oil

References
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[2] Huber, G. W. (2008). National Science Foundation Report, Breaking the Chemical and Engineering Barriers to Lignocellulosic Biofuels: Next Generation Hydrocarbon Biocarbon Biorefineries, Chemical, Bioengineering, Environmental, and Transport Systems Division, Washington, DC, 2008, 180 p.
[3] Bridgwater, A. V. (2002). An introduction to fast pyrolysis of biomass for fuels and chemicals In Fast pyrolysis of biomass: A handbook, Bridgwater, A. V., Ed., CPLPress: Newbury, UK.
[4] Trimble, J. L.; Vanhook, R. I.; Folger, A. G. 1984: Biomass for energy: The environmental-issues. Biomass 6, 3–13.
[5] E. C. http: //ec.europa.eu/research/energy/nn/nn_rt/nn_rt_bm/article_1111_en.htm. Elliott, D. C. 1986. Analysis and Comparison of Biomass Pyrolysis/Gasification Condesates Final Report, PNL-5943, Contract DE-AC06-76RLO.
[6] Demirbas A. (2001). Biomass resource facilities and biomass conversion processing for fuels and chemicals. Energy Conv Manage 2001; 42: 1357–78.
[7] Adegoke I. A (2017). Physico-Chemical Characterisation of Bio-Oil Produced from Pyrolysis of Gmelina arborea Roxb. Sawdust. Ph. D. submitted to the Department of Forest Resources Management, University of Ibadan. Ibadan, Nigeria.
[8] Mohan, D.; Pittman, C. U., Jr.; Steele, P. H. 2006: Pyrolysis of wood/biomass for bio-oil: A critical review. Energy Fuels 20, 848–889.
[9] Lu G. Q, Toyama T, Kim H. J, Naruse I, Ohtake K. (1997). Fundamental study on combustion characteristics of biobriquette. Kagaku Kogaku Ronbun1997; 23: 404–12.
[10] Soria, A. J.; McDonald, A. G.; Shook, S. R. 2008: Wood solubilization anddepolymerization using supercritical methanol. Part 1: Process optimization and analysis of methanol insoluble components (bio-char). Holzforschung, 62, 402-408.
[11] Soria, A. J.; McDonald, A. G.; He, B. B. 2008: Wood solubilization and depolymerization by supercritical methanol. Part 2: Analysis of methanol soluble compounds. Holzforschung, 62, 409–416.
[12] Fuwape, J. A. 2007: Bioenergy: Conservation and Utilization of wood biofuel in Nigeria. In: Proceeding of Division 5 IUFRO conference, October 29-Nov. 2nd 2007. Tapei Taiwan. Pp 81.
[13] Solantausta, Y.; Nylund, N. O.; Westerholm, M.; Koljonen, T.; Oasmaa, A. (1993). “Wood Pyrolysis Oil as a Fuel in a Diesel Power Plant.” Bioresource Technology. Vol. 46, 1993; pp. 177-188.
[14] Park, W. CH., Atreya, A., Baum, H. R. (2010). Experimental and theoretical investigation of heat and mass transfer processes during wood pyrolysis, Comb. Flame 157 (2010) 481-494.
[15] Keown, D. M., G. Favas, J. I. Hayashi and C. Z. Li (2005). Volatilisation of alkali and alkaline earth metallic species during the pyrolysis of biomass: differences between sugar cane bagasse and cane trash. Bioresource Technology. 95: 1570-1577.
[16] Bio Therm (1999). BiothermTM A system for continuous quality, fast pyrolysis bio oil. Fourth Biomass Conference of the Americas, Oakland, California. September. 1999.
[17] Chiaramonti, D., Bonini, M., Fratini, E., Tondi, G., Gartner, K., Bridgwater, A. V., Grimm, H. P., Soldaini, I., Webster, A., Baglioni, P 2003: Development of Emulsions from Bio mass Pyrolysis Liquid and Diesel and Their Use in Engines – Part 1: Emulsion Production, Biomass &Bioenergy, 25 pp. 85-99; Part 2: Tests in Diesel Engines, Bi mass & Bioenergy, 25 pp. 101-111.
[18] Adegoke, I. A and Fuwape, J. A 2008: combustion properties of briquettes as affected by Production process. Proc. 1st Annual Conf. in Forests and Forest Products, 16th 19th April 2008, FUTA. Nigeria. Pp 193-197.
[19] Russell, J. A., R. K. Miller and P. M. Molton, 1983. Formation of aromatic compounds from condensation reactions of cellulose degradation products. Biomass, 3: 43-57. DOI: 10.1016/0144- 4565 (83) 90007-0.
[20] Meier, D., O. Oasmaa and G. V. C. Peacocke. (1997). Properties of Fast Pyrolysis Liquids: Status of Test Methods. In A. V. Bridgwater and D. G. B. Boocock (Eds). Developments in Thermochemical Biomass Conversion. London: Blackie Academic & Professional. 391-408.
[21] Bramer, E. A., Holthis, M. R., Brem, G. (2004). Development of a Cyclonic Reactor with Internal Particle Filter for the Flash Pyrolysis of Biomass; the Pyros Reactor, Proceedings, 2nd World Conference on Bioenergy, Rome, May 10-14, 2004, in press.
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    Idowu Abimbola Adegoke, Rotowa Odunayo James. (2020). Preparation and Characterisation of Bio-Oil Produced from Sawdust of Selected Wood Species. American Journal of Modern Energy, 6(1), 16-25. https://doi.org/10.11648/j.ajme.20200601.13

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    ACS Style

    Idowu Abimbola Adegoke; Rotowa Odunayo James. Preparation and Characterisation of Bio-Oil Produced from Sawdust of Selected Wood Species. Am. J. Mod. Energy 2020, 6(1), 16-25. doi: 10.11648/j.ajme.20200601.13

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    AMA Style

    Idowu Abimbola Adegoke, Rotowa Odunayo James. Preparation and Characterisation of Bio-Oil Produced from Sawdust of Selected Wood Species. Am J Mod Energy. 2020;6(1):16-25. doi: 10.11648/j.ajme.20200601.13

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  • @article{10.11648/j.ajme.20200601.13,
      author = {Idowu Abimbola Adegoke and Rotowa Odunayo James},
      title = {Preparation and Characterisation of Bio-Oil Produced from Sawdust of Selected Wood Species},
      journal = {American Journal of Modern Energy},
      volume = {6},
      number = {1},
      pages = {16-25},
      doi = {10.11648/j.ajme.20200601.13},
      url = {https://doi.org/10.11648/j.ajme.20200601.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajme.20200601.13},
      abstract = {Renewable energy is of growing importance in satisfying environmental concerns over fossil fuel usage. The study was carried out to determine bio-fuel characteristics of pyrolytic oil produce from sawdust of selected wood species (Gmelina arborea, and Nesogordonia papaverifera). Sawdust samples of 200 gramms each were collected from Forestry Research Institute of Nigeria sawmill and oven-dried at 103±2°C for 24 hours to 12% moisture content. While four replicates of bio-oil were produced at each temperature regime for each of the samples, two different temperature regimes were used (500°C and 600°C). The metallic container (pyrolytic chamber) was filled with 200 grammes of the samples of each species and placed inside the Reactor which was connected to a condenser. Using standard test, physical properties, chemical and thermal characterization of bio oil and proximate analysis of the Bio-Char were assessed. Analysis of Variance (ANOVA) in Randomized Complete Block Design (RCBD) was used to ascertain significance difference in the oil yield produced at different temperature. The result shows that there was general increase in the volume of oil yield as the temperature increases. The volume of the oil ranged between 35.97±1.82 to 49.33±3.21 and 52.93±0.51 to 63.63±5.83, the highest and least mean of the pH of pyrolytic oil yield ranged from 3.52±0.02 to 3.54±0.02 and 3.64±0.36 to 3.73±0.01 for G. arborea and N. papaverifera respectively. There was significant difference in the means of the volume of bio-oil obtained as pyrolysis temperture increases. It further shows that the sawmill wood residues differs significantly at P<0.05 within the two temperature regime. The study established that pyrolysis is an efficient way to produce liquid fuels from biomass. The physical properties of the bio-oil obtained from sawmill wood residues falls within the acceptable range for fuel production. The selected wood species are therefore suitable for production of bio-oil with acceptable physical and chemical properties. Based on the result of the study, it is therefore among others recommended that residence time be taken for each temperature range to convert the feedstock to oil, and quantity of oil yield per specie.},
     year = {2020}
    }
    

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  • TY  - JOUR
    T1  - Preparation and Characterisation of Bio-Oil Produced from Sawdust of Selected Wood Species
    AU  - Idowu Abimbola Adegoke
    AU  - Rotowa Odunayo James
    Y1  - 2020/01/21
    PY  - 2020
    N1  - https://doi.org/10.11648/j.ajme.20200601.13
    DO  - 10.11648/j.ajme.20200601.13
    T2  - American Journal of Modern Energy
    JF  - American Journal of Modern Energy
    JO  - American Journal of Modern Energy
    SP  - 16
    EP  - 25
    PB  - Science Publishing Group
    SN  - 2575-3797
    UR  - https://doi.org/10.11648/j.ajme.20200601.13
    AB  - Renewable energy is of growing importance in satisfying environmental concerns over fossil fuel usage. The study was carried out to determine bio-fuel characteristics of pyrolytic oil produce from sawdust of selected wood species (Gmelina arborea, and Nesogordonia papaverifera). Sawdust samples of 200 gramms each were collected from Forestry Research Institute of Nigeria sawmill and oven-dried at 103±2°C for 24 hours to 12% moisture content. While four replicates of bio-oil were produced at each temperature regime for each of the samples, two different temperature regimes were used (500°C and 600°C). The metallic container (pyrolytic chamber) was filled with 200 grammes of the samples of each species and placed inside the Reactor which was connected to a condenser. Using standard test, physical properties, chemical and thermal characterization of bio oil and proximate analysis of the Bio-Char were assessed. Analysis of Variance (ANOVA) in Randomized Complete Block Design (RCBD) was used to ascertain significance difference in the oil yield produced at different temperature. The result shows that there was general increase in the volume of oil yield as the temperature increases. The volume of the oil ranged between 35.97±1.82 to 49.33±3.21 and 52.93±0.51 to 63.63±5.83, the highest and least mean of the pH of pyrolytic oil yield ranged from 3.52±0.02 to 3.54±0.02 and 3.64±0.36 to 3.73±0.01 for G. arborea and N. papaverifera respectively. There was significant difference in the means of the volume of bio-oil obtained as pyrolysis temperture increases. It further shows that the sawmill wood residues differs significantly at P<0.05 within the two temperature regime. The study established that pyrolysis is an efficient way to produce liquid fuels from biomass. The physical properties of the bio-oil obtained from sawmill wood residues falls within the acceptable range for fuel production. The selected wood species are therefore suitable for production of bio-oil with acceptable physical and chemical properties. Based on the result of the study, it is therefore among others recommended that residence time be taken for each temperature range to convert the feedstock to oil, and quantity of oil yield per specie.
    VL  - 6
    IS  - 1
    ER  - 

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Author Information
  • Department of Forestry and Wildlife Management, Faculty of Agriculture, Federal University Gashua, Gashua, Nigeria

  • Department of Forestry and Wildlife Management, Faculty of Agriculture, Nasarawa State University, Shabu-Lafia Campus, Nasarawa, Nigeria

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