Synthesis of 2-(2'-hydroxyphenyl)-2-oxazoline(2-Phox) and 2-(4-hydroxyphenyl)-2-oxazoline(4-Phox) and their complexes with Ni(II), Cu(II), Zn(II) and Cd(II) have been done. They have been characterized by elemental analysis, magnetic susceptibility, NMR (HH-COSY, HSQC, HMBC), UV-vis, IR spectroscopy and conductance measurement. The complexes were formed in 1:2 (M:L) ratio. Their molar conductance of one millimolar solution measured in DMF indicated them to be non electrolyte. On the basis of these studies a tetrahedral geometry has been assigned for all the complexes.
Published in | American Journal of Applied Chemistry (Volume 3, Issue 2) |
DOI | 10.11648/j.ajac.20150302.12 |
Page(s) | 40-47 |
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Oxazoline, Metal Complexes, Spectroscopy
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APA Style
Bitew Kassaw Dessie, Muluye Melak Zenebe, Atnafu Guadie Assefa. (2015). Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands. American Journal of Applied Chemistry, 3(2), 40-47. https://doi.org/10.11648/j.ajac.20150302.12
ACS Style
Bitew Kassaw Dessie; Muluye Melak Zenebe; Atnafu Guadie Assefa. Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands. Am. J. Appl. Chem. 2015, 3(2), 40-47. doi: 10.11648/j.ajac.20150302.12
AMA Style
Bitew Kassaw Dessie, Muluye Melak Zenebe, Atnafu Guadie Assefa. Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands. Am J Appl Chem. 2015;3(2):40-47. doi: 10.11648/j.ajac.20150302.12
@article{10.11648/j.ajac.20150302.12, author = {Bitew Kassaw Dessie and Muluye Melak Zenebe and Atnafu Guadie Assefa}, title = {Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands}, journal = {American Journal of Applied Chemistry}, volume = {3}, number = {2}, pages = {40-47}, doi = {10.11648/j.ajac.20150302.12}, url = {https://doi.org/10.11648/j.ajac.20150302.12}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20150302.12}, abstract = {Synthesis of 2-(2'-hydroxyphenyl)-2-oxazoline(2-Phox) and 2-(4-hydroxyphenyl)-2-oxazoline(4-Phox) and their complexes with Ni(II), Cu(II), Zn(II) and Cd(II) have been done. They have been characterized by elemental analysis, magnetic susceptibility, NMR (HH-COSY, HSQC, HMBC), UV-vis, IR spectroscopy and conductance measurement. The complexes were formed in 1:2 (M:L) ratio. Their molar conductance of one millimolar solution measured in DMF indicated them to be non electrolyte. On the basis of these studies a tetrahedral geometry has been assigned for all the complexes.}, year = {2015} }
TY - JOUR T1 - Synthesis and Structural Elucidation of Ni(II), Cu(II), Zn(II) and Cd(II) Metal Complexes of Oxazoline Based Ligands AU - Bitew Kassaw Dessie AU - Muluye Melak Zenebe AU - Atnafu Guadie Assefa Y1 - 2015/02/16 PY - 2015 N1 - https://doi.org/10.11648/j.ajac.20150302.12 DO - 10.11648/j.ajac.20150302.12 T2 - American Journal of Applied Chemistry JF - American Journal of Applied Chemistry JO - American Journal of Applied Chemistry SP - 40 EP - 47 PB - Science Publishing Group SN - 2330-8745 UR - https://doi.org/10.11648/j.ajac.20150302.12 AB - Synthesis of 2-(2'-hydroxyphenyl)-2-oxazoline(2-Phox) and 2-(4-hydroxyphenyl)-2-oxazoline(4-Phox) and their complexes with Ni(II), Cu(II), Zn(II) and Cd(II) have been done. They have been characterized by elemental analysis, magnetic susceptibility, NMR (HH-COSY, HSQC, HMBC), UV-vis, IR spectroscopy and conductance measurement. The complexes were formed in 1:2 (M:L) ratio. Their molar conductance of one millimolar solution measured in DMF indicated them to be non electrolyte. On the basis of these studies a tetrahedral geometry has been assigned for all the complexes. VL - 3 IS - 2 ER -