In order to prevent of detergent surfactant contamination to water and soil, or even in well water, decreasing surfactant in a laundry wastewater has been studied by using photodegradation under UV/TiO2/H2O2 (photo-Fenton-like) and UV/Fe2+/H2O2 (photo-Fenton) processes. Photodegradation processes were performed in a batch system by exposing UV light to the laundry wastewater for a period of time. In both processes, the factors influencing the effectiveness of the photodegradation have been evaluated. The surfactant concentration left in the wastewater was determined by UV/Visible spectrophotometry using methylene blue as a coloring agent. The research results indicated that the surfactant concentration in the laundry wastewater could be decreased significantly by using both UV/TiO2/H2O2 and UV/Fe2+/H2O2 processes. In both processes, it was observed the dependency of the surfactant photodegradation effectiveness on TiO2 dose, Fe(II) and H2O2 concentrations, pH and time. From the influencing factors study, the optimal conditions could be obtained. To get the surfactant concentration in the wastewater that fulfills the quality standard regulated by Indonesian Government, two steps of both UV/TiO2/H2O2 and UV/Fe2+/H2O2 processes were required. It also is clearly confirmed that UV/Fe2+/H2O2 (photo-Fenton) process was more effective in the surfactant photodegradation than that of UV/TiO2/H2O2 (photo-Fenton-like) process.
| Published in | American Journal of Applied Chemistry (Volume 4, Issue 5) |
| DOI | 10.11648/j.ajac.20160405.13 |
| Page(s) | 174-180 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2016. Published by Science Publishing Group |
Surfactant, Photodegradation, UV/TiO2/H2O2, UV/Fe2+/H2O2
| [1] | Holmberg, K., Johnson, B., Kronberg, B, and Lindman, B, 2002, Surfactant and Polymers in Aqueous Solution, John Wiley and sons, London. |
| [2] | Ogundiran, M. A. Fawole, O. O, Adewoye, S. O., and Ayandiran, T. A, 2010, Toxicological Impact of Detergent Effluent on Juvenile of African Catfish, Agr. Bio. J. N. Am., 1 (3), 330-342. |
| [3] | Bizukojc, E. L., Miksch, K., Jutsz, A. M., and Kalka, J., 2005, Acute Toxicology and Genotoxicity of Five Selected Anionicad Nonionic Surfactants, Chemosphere, 58, 1249-1253. |
| [4] | Moreno-Caselles, Joaquin, Prats, Daniel, Moral, D., Perez-Murcia, M. D., Perez-Espinosa, A., Paredes, C., and Leon, V., 2006, Effects of Linear Alkylbenzene Sulfonates (LASs) in Sewage Sludge-Amended Soils on Nutrient Contents of Broccoli Plants, Poster Paper, Communications in Soil Science and Plant Analysis, 37: 2605-2614, ISSN 0010-36. |
| [5] | Aboulhassan, M. A., Souabi, S., Yaacoubi, A. and Boudu, M., 2006, Removal of Surfactant from Industrial Wastewater by Coagulation-Flocculation Process, J. Environ. SCi. Tech., 3 (4), 327-332. |
| [6] | Conrad, A., Cadoret, A., Corteel, P., Leroy, P., and Block J. C., 2006, Adsorption/Desorption of Linear Alkylbenzenasulfonate (LAS) and Azoprotein by /from Activated Sludge Flocs, J. Chemosphere, 62, 53-60. |
| [7] | Yang, W. B., Li, A., Fan, J., Yang, L., and Zhang, Q., 2006, Adsorption of Branched Alkylbenzene Sulfonat on to Styrene and Acrylic Ester resins, J. Chemosphere, 64, 984-990. |
| [8] | Taffarel, S. R., and Rubio, J., 2010, Adsorption of Sodium Dodecyl Benzene Sulfonate form Aqueous Solution Using a Modified Natural Zeolite with CTAB, J. Min. Eng., 23, 771-779. |
| [9] | Peressutti, S. R., Olivera, N. L., Babay, P. A., Costagliola, M., and Alvarez, H. M., 2008, Degradation of Linear Alkylbenzene Sulfonate by a Bacterial Consortium Isolated from the Aquatic Environment of Argentina, Journal of Applied Microbiology, 105 (2008) 276-484, ISSN 1364-5072. |
| [10] | Marretig-Bruns and Jelen, E., 2009, Anaerobic Biodegradation of Detergent Surfactant, Materials, 2, 181-206. |
| [11] | Manousaki, E., Psillakis, E., Kalogerakis, N., and Mantzavinos, D., 2004, Degradation of sodium Dodecylbenzene Sulfonate in water by Ultrasonic Irradiation, J. Wat. Res., 38, 3751-3759. |
| [12] | Deghani, M. H., Najafpoor, A. A., and Azam, K., 2010, Using Sonochemical Reactor for Degradation of LAS from Effluent of Wastewater Treatment, J. Desalination, 250, 82-86. |
| [13] | Naldoni, E., Schiboula, A., Bianchi, C. L., and Bremmer, D. H., 2011, Mineralization of Surfactant Using Ultrasound and advanced Fenton Process, Water, Air, Soil Pollut., 215, 487-495. |
| [14] | Diaz, J. D. M., Sanchez-Polo, M, Rivera-Utrilla, J., and Bautista-Toledo, M. L., 2009, Effectiveness of Different Oxidizing Agents for Removing Sodium Dodecyl Benzena Sulphonate in Aqueous System, Water. Res., 43, 1621-1629. |
| [15] | Eng, Y., Sharma, V. K., and Ray, A. K., 2010, Photocatalytic Degradation of Nonionic Surfactant Brij 35 in Aqueous TiO2 Suspensions, J. Chemosphere, 79, 205-209. |
| [16] | Sugiharto, E., Suratman, A., Natsir, T. A., and Wahyuni, E. T., 2014, Determination of Surfactant in the river from laundry waste water disposal and the removal by photocatalytic degradation with TiO2, American Chemical Science Journal, 4 (6), 715-725. |
| [17] | M. R. Hoffmann, S. T. Martin, W. Choi, and D. W. Bahnemann, 1995, “Environmental Application of Semiconductor Photocatalysis”, Chem. Rev. vol. 95, 69-96. |
| [18] | Saquib, M., Tariq, M. A., Haque, M. M., and Muneer, M., 2008, Photocatalytic Degradation, Disperse Blue I Using UV/TiO2/H2O2 Process, J. Environ. Manage, 88, 300-306. |
| [19] | Elmola, E. S. and Malay, C., 2010, Photocatalytic Degradation of Amoxicillin, Amphicillin, and Cloaxacillin Antibiotics in Aqueous Solution Using UV/TiO2 and UV/H2O2/TiO2 Photocatalysis. J. Desalination, 252, 46-52. |
| [20] | Sanchez, E., Taxt-Lamolle, S. F. M., Hole, E. O., Krivokapic, A., Sagstuen, E., and Haugen, H. J., 2013, TiO2 Suspension Exposed to H2O2 in Ambient Light of Darkness: Degradation of Methylene Blue and EPR Evidence for Radical Oxygen Species, Appl. Catal. B., 142-142, 662-667. |
| [21] | Kang, Y. W., and Hwang, K. Y., 2000, Effect of Reaction Conditions on The Oxidation Efficiency In The Fenton Process. Water Res., 34, 10, 2786– 2790. |
| [22] | Kusic, H., Koprivanac, N., Bozic, A. L., and Selanec, I., 2009, Photo-assisted Fenton Type Process for The Deradation of Phenol: A Kinetic Study. Journal of Hazardouz Materials B., 136, 632-644. |
| [23] | Moraes, J. E. F., Quina, F. H., Nascimento, C. A. O., Silva, D. N., and Chiavone-Filho, O., 2004, Treatment of saline wastewater contaminated with hydrocarbons by the photo-Fenton process, Environ. Sci. Technol., 38 (4), 1183-1187. |
| [24] | Kavitha, V. and Palanivelu, K, 2005, Destruction of Cresols by Fenton Oxidation Process, Water Res, 39, 3062-3072. |
| [25] | Masomboon, N., Chavalit, R., and Ming-chun, L., 2009, Chemical Oxidation of 2,6-Dimethylaniline in the Fenton Process, Environ. Sci. Technol., 43, 8629-8634. |
| [26] | Chen, C. C., and Wu, R. J., 2009, Chemical Oxidation Degradation of Acridine Orange Dye in Aqueous Solution by Fenton’s Reagent, Journal of the Chinese Chemical Society, 56, 1147-1155. |
| [27] | Mousavi, S. A. R., Mahvi, S., and Nasseri, Sh. Ghafari, 2011, Effect of Fenton Process (H2O2/Fe2+) on Removal of Liniear Alkylbenzene Sulfonate Using Central Composite, Iran. J. Environ. Health. Sci. Eng., Vol. 8, No. 2, pp. 129-138. |
| [28] | Nideesh, P. V., Gadhimathi, R., and Ramesh, S. T., 2013, Degradation of Dyes from Aqueous solution of Fenton Process: a Review, Environ. Sci. Pollut. Res., 20, 2099-2132. |
| [29] | Bautista, P. Mohedano, M. A., Gillaranz, J. A., Casas, J. A., and Rodriguez, J. J., 2007, Application of Fenton Oxidation to Cosmetics Wastewater Treatment, J. Hazard Mater, 143, 128-134. |
| [30] | Lucas, M. S., and Peres, J. A., 2009, Removal COD from Olive Mill Wastewater by Fenton’s Reagent: Kinetic Study. J. Hazard Mater., 168, 1253-1259, ISSN 0304-3894. |
| [31] | Aris, A. and Sharrat, P. N., 2007, Evaluation of Photo-Fenton Degradation of Reactive Black 5 Using Respon Surface Method, Malays. J. Civ. Eng, 19 (1), 26-41. |
| [32] | Xiu, M., Wan, Q., and Hao, Y., 2007, Removal of Carbon From Wastepaper Pulp Effluent by Lab Scale Solar-Photo-Fenton Process. J. Hazard Mater, 148, 1003-109. |
| [33] | Farias, J., Germa, H., Rossetti, E. D. A. and Orlando, M. A, 2007, Solar Degradation of Formic Acid: Temperature Effects on the Photo-Fenton Reaction, Ind. Eng. Chem. Res., 46, 7580-7586. |
| [34] | Kajitvichyanukul, P., Lu, Ming-Chun, and Jamroensan, A., 2008, Formaldehyde Degradation in The Presence of Methanol by Photo-Fenton Process, Journal of Environmental Management, 86, 545-553. |
| [35] | Samet, Y., Hmani, E. and Abdelhedi, R., 2012, Fenton and Solar Photo-Fenton Proccesses for Removal of Chlorphyrifos Insecticide in Wastewater, Water Res., 38, 4. |
| [36] | Ahmed, B., Limem, E., Wahab, A., and Nasr, B., 2011, Photo-Fenton Treatment of Actual Agro-industrial Wastewater, Indian J. Eng. Chem. Res., 50, 6673-6680. |
| [37] | Hernandez, M. A., Marin, C. M., dan Castaneda, H. T., 2012, Solar photo-Fenton Optimisation in Treating Carbofuran-Contaminated Water, Ing. E. Investigation, 32, 1, 71-76. |
| [38] | Kavitha, V., and Palanivelu, K., 2004, The Role of Ferrous Ion in Fenton and Photo-Fenton Processes for the Degradation of Phenol, Chemosphere, 55, 1235–1243. |
| [39] | Karale, R. S., Manu, B., and Shirari, S., 2013, Fenton and Photo-Fenton Oxidation Processes for Degradation of 3-Aminopyridine from Water, Procedia APCBEE, 9, 25-29. |
| [40] | Hu, Q., Zhang, C., Wang, Z., Chen, Y., Mao, K., Zhang, X., Xiong, Y., and Zhu, M., 2008, Photodegradation of Methyl ter-Butyl Ether (MTBE) by UV/ H2O2 and UV/TiO2, J. Hazard Mater, 154, 795-803. |
| [41] | Tabrizi, G. B. and Mehrvar, M., 2006, Pilot-Plant Study for The Photochemical Treatment of Aqueous Linear Alkylbenzena sulfonate, Sep. Purif. Technol., 49, 115-121. |
| [42] | Dincer, A. R., Karakaya, N., Gunes, E. and Gunes, Y., 2008, Removal of COD from oil recovery Industry Wastewater by Advanced Oxydation Processes (AOP) based on H2O2, J. Global Nest, 10, 1, 31-38. |
APA Style
Endang Tri Wahyuni, R. Roto, M. Sabrina, V. Anggraini, N. F. Leswana, et al. (2016). Photodegradation of Detergent Anionic Surfactant in Wastewater Using UV/TiO2/H2O2 and UV/Fe2+/H2O2 Processes. American Journal of Applied Chemistry, 4(5), 174-180. https://doi.org/10.11648/j.ajac.20160405.13
ACS Style
Endang Tri Wahyuni; R. Roto; M. Sabrina; V. Anggraini; N. F. Leswana, et al. Photodegradation of Detergent Anionic Surfactant in Wastewater Using UV/TiO2/H2O2 and UV/Fe2+/H2O2 Processes. Am. J. Appl. Chem. 2016, 4(5), 174-180. doi: 10.11648/j.ajac.20160405.13
AMA Style
Endang Tri Wahyuni, R. Roto, M. Sabrina, V. Anggraini, N. F. Leswana, et al. Photodegradation of Detergent Anionic Surfactant in Wastewater Using UV/TiO2/H2O2 and UV/Fe2+/H2O2 Processes. Am J Appl Chem. 2016;4(5):174-180. doi: 10.11648/j.ajac.20160405.13
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Download@article{10.11648/j.ajac.20160405.13,
author = {Endang Tri Wahyuni and R. Roto and M. Sabrina and V. Anggraini and N. F. Leswana and A. C. Vionita},
title = {Photodegradation of Detergent Anionic Surfactant in Wastewater Using UV/TiO2/H2O2 and UV/Fe2+/H2O2 Processes},
journal = {American Journal of Applied Chemistry},
volume = {4},
number = {5},
pages = {174-180},
doi = {10.11648/j.ajac.20160405.13},
url = {https://doi.org/10.11648/j.ajac.20160405.13},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20160405.13},
abstract = {In order to prevent of detergent surfactant contamination to water and soil, or even in well water, decreasing surfactant in a laundry wastewater has been studied by using photodegradation under UV/TiO2/H2O2 (photo-Fenton-like) and UV/Fe2+/H2O2 (photo-Fenton) processes. Photodegradation processes were performed in a batch system by exposing UV light to the laundry wastewater for a period of time. In both processes, the factors influencing the effectiveness of the photodegradation have been evaluated. The surfactant concentration left in the wastewater was determined by UV/Visible spectrophotometry using methylene blue as a coloring agent. The research results indicated that the surfactant concentration in the laundry wastewater could be decreased significantly by using both UV/TiO2/H2O2 and UV/Fe2+/H2O2 processes. In both processes, it was observed the dependency of the surfactant photodegradation effectiveness on TiO2 dose, Fe(II) and H2O2 concentrations, pH and time. From the influencing factors study, the optimal conditions could be obtained. To get the surfactant concentration in the wastewater that fulfills the quality standard regulated by Indonesian Government, two steps of both UV/TiO2/H2O2 and UV/Fe2+/H2O2 processes were required. It also is clearly confirmed that UV/Fe2+/H2O2 (photo-Fenton) process was more effective in the surfactant photodegradation than that of UV/TiO2/H2O2 (photo-Fenton-like) process.},
year = {2016}
}
TY - JOUR T1 - Photodegradation of Detergent Anionic Surfactant in Wastewater Using UV/TiO2/H2O2 and UV/Fe2+/H2O2 Processes AU - Endang Tri Wahyuni AU - R. Roto AU - M. Sabrina AU - V. Anggraini AU - N. F. Leswana AU - A. C. Vionita Y1 - 2016/08/31 PY - 2016 N1 - https://doi.org/10.11648/j.ajac.20160405.13 DO - 10.11648/j.ajac.20160405.13 T2 - American Journal of Applied Chemistry JF - American Journal of Applied Chemistry JO - American Journal of Applied Chemistry SP - 174 EP - 180 PB - Science Publishing Group SN - 2330-8745 UR - https://doi.org/10.11648/j.ajac.20160405.13 AB - In order to prevent of detergent surfactant contamination to water and soil, or even in well water, decreasing surfactant in a laundry wastewater has been studied by using photodegradation under UV/TiO2/H2O2 (photo-Fenton-like) and UV/Fe2+/H2O2 (photo-Fenton) processes. Photodegradation processes were performed in a batch system by exposing UV light to the laundry wastewater for a period of time. In both processes, the factors influencing the effectiveness of the photodegradation have been evaluated. The surfactant concentration left in the wastewater was determined by UV/Visible spectrophotometry using methylene blue as a coloring agent. The research results indicated that the surfactant concentration in the laundry wastewater could be decreased significantly by using both UV/TiO2/H2O2 and UV/Fe2+/H2O2 processes. In both processes, it was observed the dependency of the surfactant photodegradation effectiveness on TiO2 dose, Fe(II) and H2O2 concentrations, pH and time. From the influencing factors study, the optimal conditions could be obtained. To get the surfactant concentration in the wastewater that fulfills the quality standard regulated by Indonesian Government, two steps of both UV/TiO2/H2O2 and UV/Fe2+/H2O2 processes were required. It also is clearly confirmed that UV/Fe2+/H2O2 (photo-Fenton) process was more effective in the surfactant photodegradation than that of UV/TiO2/H2O2 (photo-Fenton-like) process. VL - 4 IS - 5 ER -
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