Auto-Inflammation Test of Black Citric Acid Polymer (PN) and Fuel Oil (FO) Mixes - Coke Formation

Andry Tahina Rabeharitsara; Marie Nicole Rabemananjara; Nambinina Richard Randriana; Haritiana Jeannelle Rakotonirina; Edouard Andrianarison; André Razafimandefitra; Baholy Robijaona

doi:doi:10.11648/j.ajac.20170503.11

Auto-Inflammation Test of Black Citric Acid Polymer (PN) and Fuel Oil (FO) Mixes - Coke Formation

Andry Tahina Rabeharitsara, Marie Nicole Rabemananjara, Nambinina Richard Randriana, Haritiana Jeannelle Rakotonirina, Edouard Andrianarison, André Razafimandefitra, Baholy Robijaona

Published in American Journal of Applied Chemistry (Volume 5, Issue 3)

Received: 1 April 2017 Accepted: 13 April 2017 Published: 25 May 2017

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

Increasing the value of heavy oil or vacuum resides was one of the challenge of petroleum industry. It has been neglected for technology improvement because the petroleum industry has focused on lighter crude oils and their distillable liquid fractions. The great problem was its conversion yields revealed a practical maximum limits that are imposed by petroleum poly-nuclear aromatics (PNA) of the petroleum macromolecules. Our objective in this manuscript was to understand and to show the black citric acid polymers (PN) effects to the value of fuel oil. Then, we have prepared FO/PN mixes samples and tested their auto-inflammation temperature. Coke was formed and quantified by hexane and dichloromethane extraction. The results showed that not only the auto-inflammation temperature of the mixes were largely lower than the ones of fuel oil and PN but also during the mixes combustion not inconsiderable alkenes such as prop-1-ène and its derivatives non-aromatics organic compounds were formed that the rest was insoluble in hexane solvent. The PN gave an added value to the fuel oil.

Published in	American Journal of Applied Chemistry (Volume 5, Issue 3)
DOI	10.11648/j.ajac.20170503.11
Page(s)	45-52
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Black Citric Acid Polymer (PN), Fuel Oil, Auto-inflammation, Hexane, Dichloromethane, Soluble Coke, Insoluble Coke

References

[1]	Sammy Eric ANDRIAMBOLA Valorisation de l’acide citrique en polymères et en sels de mono- di- et tri-ammonium. Mémoire de fin d’étude en vue de l’obtention du diplôme d’Ingénieur en Génie Chimique. E. S. P. A. Université d’Antananarivo. 2013.
[2]	Advenced Chemistry Development ACD/ChemSketch.
[3]	MKE/BE/POM-BNL/PQM- Révision 00 (mars 2009)- TOTAL BELGIUM- 93, rue du Commerce – 1040 Bruxelles.
[4]	Gautier PETIT. Analyses thermochimiques et cinétiques de l’auto-inflammation en mode HCCI des isomers du butane. Développement et instrumentation d’un banc moteur dédié aux études de basse temperature. Thèse de Doctorat de l’Université de Lille 1. 2007.
[5]	R. W. WALKER, C. MORLEY. Comprehensive Chemical Kinetics, edited by R. G. Compton and G. Hancock, The royal Society of Chemistry, Vol. 35, “Low temperature combustion and autoignition, M. J.. Pilling, Chap. I: 1-37, 1997.
[6]	John GRIFFITHS. Des flammes froides qui chauffent mais ne brûlent pas. New Scientists Technology Publié le 30/06/2004.
[7]	Claude RONNEAU. Energie pollution de l’air et développement durable. Editeur: Presses Universitaire de Louvain Collection: Lectures Universitaire; Louvain-La-Neuve; 2004.
[8]	www.uqac.ca/chimie ens/Cinétique chimique/CHAP 7.html.
[9]	http://books.openedition.org/pucl/624?lang=fr.
[10]	Andry Tahina RABEHARITSARA. Etude de la formation de coke au cours de la transformation du méthylcyclohexane sur zéolithes. Thèse de Doctorat de l’Université de Poitiers. 2003.
[11]	Technique de l’ingénieur, extraction par solvant, 2008.
[12]	Irwin A. WIEHE Heavy Oil Conversion Chemistry: Part1 – The PNA Barrier.
[13]	John F. SCHARBON and James G. SPEIGHT. Correlation between carbon residue and molecular weight. Western Research Institute. 365 N. 9th ST;, Laramie, WY 82070-3380.

Cite This Article

Plain Text BibTeX RIS

APA Style

Andry Tahina Rabeharitsara, Marie Nicole Rabemananjara, Nambinina Richard Randriana, Haritiana Jeannelle Rakotonirina, Edouard Andrianarison, et al. (2017). Auto-Inflammation Test of Black Citric Acid Polymer (PN) and Fuel Oil (FO) Mixes - Coke Formation. American Journal of Applied Chemistry, 5(3), 45-52. https://doi.org/10.11648/j.ajac.20170503.11

Copy | Download

ACS Style

Andry Tahina Rabeharitsara; Marie Nicole Rabemananjara; Nambinina Richard Randriana; Haritiana Jeannelle Rakotonirina; Edouard Andrianarison, et al. Auto-Inflammation Test of Black Citric Acid Polymer (PN) and Fuel Oil (FO) Mixes - Coke Formation. Am. J. Appl. Chem. 2017, 5(3), 45-52. doi: 10.11648/j.ajac.20170503.11

Copy | Download

AMA Style

Andry Tahina Rabeharitsara, Marie Nicole Rabemananjara, Nambinina Richard Randriana, Haritiana Jeannelle Rakotonirina, Edouard Andrianarison, et al. Auto-Inflammation Test of Black Citric Acid Polymer (PN) and Fuel Oil (FO) Mixes - Coke Formation. Am J Appl Chem. 2017;5(3):45-52. doi: 10.11648/j.ajac.20170503.11

Copy | Download

@article{10.11648/j.ajac.20170503.11,
  author = {Andry Tahina Rabeharitsara and Marie Nicole Rabemananjara and Nambinina Richard Randriana and Haritiana Jeannelle Rakotonirina and Edouard Andrianarison and André Razafimandefitra and Baholy Robijaona},
  title = {Auto-Inflammation Test of Black Citric Acid Polymer (PN) and Fuel Oil (FO) Mixes - Coke Formation},
  journal = {American Journal of Applied Chemistry},
  volume = {5},
  number = {3},
  pages = {45-52},
  doi = {10.11648/j.ajac.20170503.11},
  url = {https://doi.org/10.11648/j.ajac.20170503.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20170503.11},
  abstract = {Increasing the value of heavy oil or vacuum resides was one of the challenge of petroleum industry. It has been neglected for technology improvement because the petroleum industry has focused on lighter crude oils and their distillable liquid fractions. The great problem was its conversion yields revealed a practical maximum limits that are imposed by petroleum poly-nuclear aromatics (PNA) of the petroleum macromolecules. Our objective in this manuscript was to understand and to show the black citric acid polymers (PN) effects to the value of fuel oil. Then, we have prepared FO/PN mixes samples and tested their auto-inflammation temperature. Coke was formed and quantified by hexane and dichloromethane extraction. The results showed that not only the auto-inflammation temperature of the mixes were largely lower than the ones of fuel oil and PN but also during the mixes combustion not inconsiderable alkenes such as prop-1-ène and its derivatives non-aromatics organic compounds were formed that the rest was insoluble in hexane solvent. The PN gave an added value to the fuel oil.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Auto-Inflammation Test of Black Citric Acid Polymer (PN) and Fuel Oil (FO) Mixes - Coke Formation
AU  - Andry Tahina Rabeharitsara
AU  - Marie Nicole Rabemananjara
AU  - Nambinina Richard Randriana
AU  - Haritiana Jeannelle Rakotonirina
AU  - Edouard Andrianarison
AU  - André Razafimandefitra
AU  - Baholy Robijaona
Y1  - 2017/05/25
PY  - 2017
N1  - https://doi.org/10.11648/j.ajac.20170503.11
DO  - 10.11648/j.ajac.20170503.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 45
EP  - 52
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20170503.11
AB  - Increasing the value of heavy oil or vacuum resides was one of the challenge of petroleum industry. It has been neglected for technology improvement because the petroleum industry has focused on lighter crude oils and their distillable liquid fractions. The great problem was its conversion yields revealed a practical maximum limits that are imposed by petroleum poly-nuclear aromatics (PNA) of the petroleum macromolecules. Our objective in this manuscript was to understand and to show the black citric acid polymers (PN) effects to the value of fuel oil. Then, we have prepared FO/PN mixes samples and tested their auto-inflammation temperature. Coke was formed and quantified by hexane and dichloromethane extraction. The results showed that not only the auto-inflammation temperature of the mixes were largely lower than the ones of fuel oil and PN but also during the mixes combustion not inconsiderable alkenes such as prop-1-ène and its derivatives non-aromatics organic compounds were formed that the rest was insoluble in hexane solvent. The PN gave an added value to the fuel oil.
VL  - 5
IS  - 3
ER  -

Copy | Download

Author Information

Andry Tahina Rabeharitsara

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Marie Nicole Rabemananjara

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Nambinina Richard Randriana

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Haritiana Jeannelle Rakotonirina

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Edouard Andrianarison

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
André Razafimandefitra

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Baholy Robijaona

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Andry Tahina Rabeharitsara, Marie Nicole Rabemananjara, Nambinina Richard Randriana, Haritiana Jeannelle Rakotonirina, Edouard Andrianarison, et al. (2017). Auto-Inflammation Test of Black Citric Acid Polymer (PN) and Fuel Oil (FO) Mixes - Coke Formation. American Journal of Applied Chemistry, 5(3), 45-52. https://doi.org/10.11648/j.ajac.20170503.11

Copy | Download

ACS Style

Andry Tahina Rabeharitsara; Marie Nicole Rabemananjara; Nambinina Richard Randriana; Haritiana Jeannelle Rakotonirina; Edouard Andrianarison, et al. Auto-Inflammation Test of Black Citric Acid Polymer (PN) and Fuel Oil (FO) Mixes - Coke Formation. Am. J. Appl. Chem. 2017, 5(3), 45-52. doi: 10.11648/j.ajac.20170503.11

Copy | Download

AMA Style

Andry Tahina Rabeharitsara, Marie Nicole Rabemananjara, Nambinina Richard Randriana, Haritiana Jeannelle Rakotonirina, Edouard Andrianarison, et al. Auto-Inflammation Test of Black Citric Acid Polymer (PN) and Fuel Oil (FO) Mixes - Coke Formation. Am J Appl Chem. 2017;5(3):45-52. doi: 10.11648/j.ajac.20170503.11

Copy | Download

@article{10.11648/j.ajac.20170503.11,
  author = {Andry Tahina Rabeharitsara and Marie Nicole Rabemananjara and Nambinina Richard Randriana and Haritiana Jeannelle Rakotonirina and Edouard Andrianarison and André Razafimandefitra and Baholy Robijaona},
  title = {Auto-Inflammation Test of Black Citric Acid Polymer (PN) and Fuel Oil (FO) Mixes - Coke Formation},
  journal = {American Journal of Applied Chemistry},
  volume = {5},
  number = {3},
  pages = {45-52},
  doi = {10.11648/j.ajac.20170503.11},
  url = {https://doi.org/10.11648/j.ajac.20170503.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20170503.11},
  abstract = {Increasing the value of heavy oil or vacuum resides was one of the challenge of petroleum industry. It has been neglected for technology improvement because the petroleum industry has focused on lighter crude oils and their distillable liquid fractions. The great problem was its conversion yields revealed a practical maximum limits that are imposed by petroleum poly-nuclear aromatics (PNA) of the petroleum macromolecules. Our objective in this manuscript was to understand and to show the black citric acid polymers (PN) effects to the value of fuel oil. Then, we have prepared FO/PN mixes samples and tested their auto-inflammation temperature. Coke was formed and quantified by hexane and dichloromethane extraction. The results showed that not only the auto-inflammation temperature of the mixes were largely lower than the ones of fuel oil and PN but also during the mixes combustion not inconsiderable alkenes such as prop-1-ène and its derivatives non-aromatics organic compounds were formed that the rest was insoluble in hexane solvent. The PN gave an added value to the fuel oil.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Auto-Inflammation Test of Black Citric Acid Polymer (PN) and Fuel Oil (FO) Mixes - Coke Formation
AU  - Andry Tahina Rabeharitsara
AU  - Marie Nicole Rabemananjara
AU  - Nambinina Richard Randriana
AU  - Haritiana Jeannelle Rakotonirina
AU  - Edouard Andrianarison
AU  - André Razafimandefitra
AU  - Baholy Robijaona
Y1  - 2017/05/25
PY  - 2017
N1  - https://doi.org/10.11648/j.ajac.20170503.11
DO  - 10.11648/j.ajac.20170503.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 45
EP  - 52
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20170503.11
AB  - Increasing the value of heavy oil or vacuum resides was one of the challenge of petroleum industry. It has been neglected for technology improvement because the petroleum industry has focused on lighter crude oils and their distillable liquid fractions. The great problem was its conversion yields revealed a practical maximum limits that are imposed by petroleum poly-nuclear aromatics (PNA) of the petroleum macromolecules. Our objective in this manuscript was to understand and to show the black citric acid polymers (PN) effects to the value of fuel oil. Then, we have prepared FO/PN mixes samples and tested their auto-inflammation temperature. Coke was formed and quantified by hexane and dichloromethane extraction. The results showed that not only the auto-inflammation temperature of the mixes were largely lower than the ones of fuel oil and PN but also during the mixes combustion not inconsiderable alkenes such as prop-1-ène and its derivatives non-aromatics organic compounds were formed that the rest was insoluble in hexane solvent. The PN gave an added value to the fuel oil.
VL  - 5
IS  - 3
ER  -

Copy | Download