Citric acid is a α-hydroxylated tricarboxylic acid present in abundance in lemon. More than one million tons of citric acid are industrially produced throughout the year. Our objective in this manuscript was to increase the value of the citric acid to ammonium citric acid salts by crystallization such as ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate. Studies and tests were carried out in this direction but the characteristic of our last process was the use of a co-solvent ethanol which proved more effective and more economical. At the end, we tested the capacity of the ammonium Di-hydrogenocitrate and the ammonium mono-hydrogenocitrate to swell a mixture and compared theirs capacities to the sodium bicarbonate. Results showed an excellent swelling capacity of the ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate to produce a uniformly very not much porous product’s texture.
| Published in | American Journal of Applied Chemistry (Volume 6, Issue 1) |
| DOI | 10.11648/j.ajac.20180601.12 |
| Page(s) | 6-14 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2017. Published by Science Publishing Group |
Citric Acid, Ammonia, Ethanol, Crystallization, Co-solvent Crystallization, Ammonium Di-hydrogenocitrate, Ammonium Mono-hydrogenocitrate, Sodium Bicarbonate, Swelling Test
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APA Style
Andry Tahina Rabeharitsara, Maheriniaina Andriamasinoro Andriamandroso, Nambinina Richard Randriana, Rijalalaina Rakotosaona, Edouard Andrianarison, et al. (2017). Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity. American Journal of Applied Chemistry, 6(1), 6-14. https://doi.org/10.11648/j.ajac.20180601.12
ACS Style
Andry Tahina Rabeharitsara; Maheriniaina Andriamasinoro Andriamandroso; Nambinina Richard Randriana; Rijalalaina Rakotosaona; Edouard Andrianarison, et al. Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity. Am. J. Appl. Chem. 2017, 6(1), 6-14. doi: 10.11648/j.ajac.20180601.12
AMA Style
Andry Tahina Rabeharitsara, Maheriniaina Andriamasinoro Andriamandroso, Nambinina Richard Randriana, Rijalalaina Rakotosaona, Edouard Andrianarison, et al. Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity. Am J Appl Chem. 2017;6(1):6-14. doi: 10.11648/j.ajac.20180601.12
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Download@article{10.11648/j.ajac.20180601.12,
author = {Andry Tahina Rabeharitsara and Maheriniaina Andriamasinoro Andriamandroso and Nambinina Richard Randriana and Rijalalaina Rakotosaona and Edouard Andrianarison and André Razafimandefitra and Baholy Robijaona},
title = {Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity},
journal = {American Journal of Applied Chemistry},
volume = {6},
number = {1},
pages = {6-14},
doi = {10.11648/j.ajac.20180601.12},
url = {https://doi.org/10.11648/j.ajac.20180601.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20180601.12},
abstract = {Citric acid is a α-hydroxylated tricarboxylic acid present in abundance in lemon. More than one million tons of citric acid are industrially produced throughout the year. Our objective in this manuscript was to increase the value of the citric acid to ammonium citric acid salts by crystallization such as ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate. Studies and tests were carried out in this direction but the characteristic of our last process was the use of a co-solvent ethanol which proved more effective and more economical. At the end, we tested the capacity of the ammonium Di-hydrogenocitrate and the ammonium mono-hydrogenocitrate to swell a mixture and compared theirs capacities to the sodium bicarbonate. Results showed an excellent swelling capacity of the ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate to produce a uniformly very not much porous product’s texture.},
year = {2017}
}
TY - JOUR T1 - Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity AU - Andry Tahina Rabeharitsara AU - Maheriniaina Andriamasinoro Andriamandroso AU - Nambinina Richard Randriana AU - Rijalalaina Rakotosaona AU - Edouard Andrianarison AU - André Razafimandefitra AU - Baholy Robijaona Y1 - 2017/12/23 PY - 2017 N1 - https://doi.org/10.11648/j.ajac.20180601.12 DO - 10.11648/j.ajac.20180601.12 T2 - American Journal of Applied Chemistry JF - American Journal of Applied Chemistry JO - American Journal of Applied Chemistry SP - 6 EP - 14 PB - Science Publishing Group SN - 2330-8745 UR - https://doi.org/10.11648/j.ajac.20180601.12 AB - Citric acid is a α-hydroxylated tricarboxylic acid present in abundance in lemon. More than one million tons of citric acid are industrially produced throughout the year. Our objective in this manuscript was to increase the value of the citric acid to ammonium citric acid salts by crystallization such as ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate. Studies and tests were carried out in this direction but the characteristic of our last process was the use of a co-solvent ethanol which proved more effective and more economical. At the end, we tested the capacity of the ammonium Di-hydrogenocitrate and the ammonium mono-hydrogenocitrate to swell a mixture and compared theirs capacities to the sodium bicarbonate. Results showed an excellent swelling capacity of the ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate to produce a uniformly very not much porous product’s texture. VL - 6 IS - 1 ER -
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