Nano Composite Polymer Resin Coating to Control Mild Steel Corrosion in Marine Environment

Athira Rajendran; Thenmozhi Sivalingam; Poongothai Narayanan; Salem Chandrasekaran Murugavel

doi:doi:10.11648/j.ajac.20180603.14

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Nano Composite Polymer Resin Coating to Control Mild Steel Corrosion in Marine Environment

Athira Rajendran, Thenmozhi Sivalingam, Poongothai Narayanan, Salem Chandrasekaran Murugavel

Published in American Journal of Applied Chemistry (Volume 6, Issue 3)

Received: 22 May 2018 Accepted: 12 June 2018 Published: 27 July 2018

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Abstract

The present study was carried out to analyze the performance of anti-corrosion property for the combination of PMMA, resin and ZnO nano particle coating on mild steel in 3.5% NaCl medium at 3hrs, 6hrs and 12hrs exposure. The synthesized nano particle was characterized by FTIR, XRD and SEM analysis. The Polymer +Resin +ZnO (PRZn) combination was coated on MS by dip and spin coating methods. The optimized concentration analyses were verified by visual observation and gravimetric method which were also confirmed by electrochemical studies such as Tafel, AC impedance studies and cyclic voltammetry studies and 10% PMMA and 10% PMMA-resin combination was identified as optimum concentration. So, 10% PMMA-resin combined with 0.1g ZnO was used for further studies and coated on MS and PRZn coating offered almost cent percent corrosion protection of MS upto 12hrs exposure in 3.5% NaCl. PRZn coating was characterized by using FTIR, XRD, Zeta potential measurements and thermal stability was analyzed by thermo gravimetric methods. The high I.E offered by the coating material was due to the presence of major constituents that forms a passive film on the metal surface that protects mild steel from corrosion was identified. Profilometer analysis shows that the thickness and roughness of polymer coated specimen is less than paint coated one. Zeta potential and contact angle measurements of the combination coating material shows a protection against corrosion due to more interfacial tension and reduced size of the particles on the metal surface.

Published in	American Journal of Applied Chemistry (Volume 6, Issue 3)
DOI	10.11648/j.ajac.20180603.14
Page(s)	102-125
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2018. Published by Science Publishing Group

Keywords

PMMA, Resin, ZnO Nano Particle, Mild Steel, Inhibition Efficiency

References

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[2]	AGGARWAL L. K., Anticorrosive Properties of Epoxy-Cardinol Resin Based Paints, Progress in Organic Coatings, 59, (2007), 76-80.
[3]	ATTA A. M., Corrosion Inhibition of Nano Composite Based on Acrylamide Copolymers for Steel, Digest Journal of Nano materials and Bio structures, (2014), 627-639.
[4]	AWAD G. H., Effect of Some Plant Extracts on the Corrosion of Mild Steel in NaCl, Proceedings on the 6th European Symposium on Corrosion Inhibitors (ESEIC), Ann. Univ. Ferrara, 1985, 8, 385-395.
[5]	CHANCHAL KUMAR KUNDU., WEI WANG., SHUN ZHOU., XIN WANG AND YUAN HU., A Green Approach to Constructing Multilayered Nano Coating for Flame Retardant of Polyamide 66 Fabric Chitosan and Sodium alginate, Carbohydrate Polymers, 166,(2017), 131-138.
[6]	CONG-CONG JIANG., A Review on the Application of Inorganic nanoparticles in Chemical Surface Coatings on Metallic Substrates, RSC Advances, 7, (2016), 7531.
[7]	MARIA CANTARELLA., Novel synthesis of ZnO/PMMA Nano composites for photo catalytic applications, scientific reports, 6, (2016), 12-16.
[8]	SUSAI RAJENDRAN., A combinatorial approach to corrosion inhibition of alloy, Research scholar, 9, (2017), 216-235.
[9]	HONH R. Y., QIAN J. Z., Synthesis and characterization of PMMA grafted ZnO nanoparticles, Powder Technology, 163, (2006), 160- 168.
[10]	HARISH. S. BHAT., Studies on Characterization of Doped ZnS nanoparticles, Journal of nanotechnology, 8, (2014), 1033-1039.
[11]	TAIB HEAKAL F. E., Impedance studies of the inhibitive effect of benzotriazole on the corrosion of Cu in NaCl medium, Corr. Sci., 20, (1980), 887-898.
[12]	HARUYAMA, Impedance studies on the corrosion of Cu in NaCl medium, Corr. Sci., 20, (1990), 1587-1898.
[13]	KOVTYUKHOVA N. I., GORCHINSKIY A. D., and WARAKSA C., Self- assembly of nanostructured composite ZnO-polyaniline films, Mater. Sci. Eng. B, 424, (2000), 69-70.
[14]	ELIHU. C. IHMS, Thermo gravimetric Analysis as a Polymer Identification Techniques, Journal of Forensic Sciences, 49(3),(2004), 505-510.
[15]	CAO J. X., Synthesis and Characterization of PMMA, Nano science, 168, (2006), 172-176.
[16]	YONG-FANG QIAN., Electro spinning of PMMA Nano fibers in different solvents, Iranian polymer journal; 19(2), (2010), 123-129.
[17]	KALANTARIAN. A, Methodology for Contact angle, Corr. Sci., 25, (2009), 14146-14154.
[18]	FRANK CHENG, Y., An intelligent coating doped with inhibitor encapsulated Nano containers for corrosion protection, Chemical engineering journal, (2017), 315, 537-551.

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APA Style

Athira Rajendran, Thenmozhi Sivalingam, Poongothai Narayanan, Salem Chandrasekaran Murugavel. (2018). Nano Composite Polymer Resin Coating to Control Mild Steel Corrosion in Marine Environment. American Journal of Applied Chemistry, 6(3), 102-125. https://doi.org/10.11648/j.ajac.20180603.14

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ACS Style

Athira Rajendran; Thenmozhi Sivalingam; Poongothai Narayanan; Salem Chandrasekaran Murugavel. Nano Composite Polymer Resin Coating to Control Mild Steel Corrosion in Marine Environment. Am. J. Appl. Chem. 2018, 6(3), 102-125. doi: 10.11648/j.ajac.20180603.14

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AMA Style

Athira Rajendran, Thenmozhi Sivalingam, Poongothai Narayanan, Salem Chandrasekaran Murugavel. Nano Composite Polymer Resin Coating to Control Mild Steel Corrosion in Marine Environment. Am J Appl Chem. 2018;6(3):102-125. doi: 10.11648/j.ajac.20180603.14

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@article{10.11648/j.ajac.20180603.14,
  author = {Athira Rajendran and Thenmozhi Sivalingam and Poongothai Narayanan and Salem Chandrasekaran Murugavel},
  title = {Nano Composite Polymer Resin Coating to Control Mild Steel Corrosion in Marine Environment},
  journal = {American Journal of Applied Chemistry},
  volume = {6},
  number = {3},
  pages = {102-125},
  doi = {10.11648/j.ajac.20180603.14},
  url = {https://doi.org/10.11648/j.ajac.20180603.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20180603.14},
  abstract = {The present study was carried out to analyze the performance of anti-corrosion property for the combination of PMMA, resin and ZnO nano particle coating on mild steel in 3.5% NaCl medium at 3hrs, 6hrs and 12hrs exposure. The synthesized nano particle was characterized by FTIR, XRD and SEM analysis. The Polymer +Resin +ZnO (PRZn) combination was coated on MS by dip and spin coating methods. The optimized concentration analyses were verified by visual observation and gravimetric method which were also confirmed by electrochemical studies such as Tafel, AC impedance studies and cyclic voltammetry studies and 10% PMMA and 10% PMMA-resin combination was identified as optimum concentration. So, 10% PMMA-resin combined with 0.1g ZnO was used for further studies and coated on MS and PRZn coating offered almost cent percent corrosion protection of MS upto 12hrs exposure in 3.5% NaCl. PRZn coating was characterized by using FTIR, XRD, Zeta potential measurements and thermal stability was analyzed by thermo gravimetric methods. The high I.E offered by the coating material was due to the presence of major constituents that forms a passive film on the metal surface that protects mild steel from corrosion was identified. Profilometer analysis shows that the thickness and roughness of polymer coated specimen is less than paint coated one. Zeta potential and contact angle measurements of the combination coating material shows a protection against corrosion due to more interfacial tension and reduced size of the particles on the metal surface.},
 year = {2018}
}

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TY  - JOUR
T1  - Nano Composite Polymer Resin Coating to Control Mild Steel Corrosion in Marine Environment
AU  - Athira Rajendran
AU  - Thenmozhi Sivalingam
AU  - Poongothai Narayanan
AU  - Salem Chandrasekaran Murugavel
Y1  - 2018/07/27
PY  - 2018
N1  - https://doi.org/10.11648/j.ajac.20180603.14
DO  - 10.11648/j.ajac.20180603.14
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 102
EP  - 125
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20180603.14
AB  - The present study was carried out to analyze the performance of anti-corrosion property for the combination of PMMA, resin and ZnO nano particle coating on mild steel in 3.5% NaCl medium at 3hrs, 6hrs and 12hrs exposure. The synthesized nano particle was characterized by FTIR, XRD and SEM analysis. The Polymer +Resin +ZnO (PRZn) combination was coated on MS by dip and spin coating methods. The optimized concentration analyses were verified by visual observation and gravimetric method which were also confirmed by electrochemical studies such as Tafel, AC impedance studies and cyclic voltammetry studies and 10% PMMA and 10% PMMA-resin combination was identified as optimum concentration. So, 10% PMMA-resin combined with 0.1g ZnO was used for further studies and coated on MS and PRZn coating offered almost cent percent corrosion protection of MS upto 12hrs exposure in 3.5% NaCl. PRZn coating was characterized by using FTIR, XRD, Zeta potential measurements and thermal stability was analyzed by thermo gravimetric methods. The high I.E offered by the coating material was due to the presence of major constituents that forms a passive film on the metal surface that protects mild steel from corrosion was identified. Profilometer analysis shows that the thickness and roughness of polymer coated specimen is less than paint coated one. Zeta potential and contact angle measurements of the combination coating material shows a protection against corrosion due to more interfacial tension and reduced size of the particles on the metal surface.
VL  - 6
IS  - 3
ER  -

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Author Information

Athira Rajendran

Department of Sciences, Amrita School of Engineering, Coimbatore, India
Thenmozhi Sivalingam

Department of Chemistry, PSG College of Technology, Coimbatore, India
Poongothai Narayanan

Department of Sciences, Amrita School of Engineering, Coimbatore, India
Salem Chandrasekaran Murugavel

Department of Chemistry, PSG College of Technology, Coimbatore, India

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APA Style

Athira Rajendran, Thenmozhi Sivalingam, Poongothai Narayanan, Salem Chandrasekaran Murugavel. (2018). Nano Composite Polymer Resin Coating to Control Mild Steel Corrosion in Marine Environment. American Journal of Applied Chemistry, 6(3), 102-125. https://doi.org/10.11648/j.ajac.20180603.14

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ACS Style

Athira Rajendran; Thenmozhi Sivalingam; Poongothai Narayanan; Salem Chandrasekaran Murugavel. Nano Composite Polymer Resin Coating to Control Mild Steel Corrosion in Marine Environment. Am. J. Appl. Chem. 2018, 6(3), 102-125. doi: 10.11648/j.ajac.20180603.14

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AMA Style

Athira Rajendran, Thenmozhi Sivalingam, Poongothai Narayanan, Salem Chandrasekaran Murugavel. Nano Composite Polymer Resin Coating to Control Mild Steel Corrosion in Marine Environment. Am J Appl Chem. 2018;6(3):102-125. doi: 10.11648/j.ajac.20180603.14

Copy | Download

@article{10.11648/j.ajac.20180603.14,
  author = {Athira Rajendran and Thenmozhi Sivalingam and Poongothai Narayanan and Salem Chandrasekaran Murugavel},
  title = {Nano Composite Polymer Resin Coating to Control Mild Steel Corrosion in Marine Environment},
  journal = {American Journal of Applied Chemistry},
  volume = {6},
  number = {3},
  pages = {102-125},
  doi = {10.11648/j.ajac.20180603.14},
  url = {https://doi.org/10.11648/j.ajac.20180603.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20180603.14},
  abstract = {The present study was carried out to analyze the performance of anti-corrosion property for the combination of PMMA, resin and ZnO nano particle coating on mild steel in 3.5% NaCl medium at 3hrs, 6hrs and 12hrs exposure. The synthesized nano particle was characterized by FTIR, XRD and SEM analysis. The Polymer +Resin +ZnO (PRZn) combination was coated on MS by dip and spin coating methods. The optimized concentration analyses were verified by visual observation and gravimetric method which were also confirmed by electrochemical studies such as Tafel, AC impedance studies and cyclic voltammetry studies and 10% PMMA and 10% PMMA-resin combination was identified as optimum concentration. So, 10% PMMA-resin combined with 0.1g ZnO was used for further studies and coated on MS and PRZn coating offered almost cent percent corrosion protection of MS upto 12hrs exposure in 3.5% NaCl. PRZn coating was characterized by using FTIR, XRD, Zeta potential measurements and thermal stability was analyzed by thermo gravimetric methods. The high I.E offered by the coating material was due to the presence of major constituents that forms a passive film on the metal surface that protects mild steel from corrosion was identified. Profilometer analysis shows that the thickness and roughness of polymer coated specimen is less than paint coated one. Zeta potential and contact angle measurements of the combination coating material shows a protection against corrosion due to more interfacial tension and reduced size of the particles on the metal surface.},
 year = {2018}
}

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TY  - JOUR
T1  - Nano Composite Polymer Resin Coating to Control Mild Steel Corrosion in Marine Environment
AU  - Athira Rajendran
AU  - Thenmozhi Sivalingam
AU  - Poongothai Narayanan
AU  - Salem Chandrasekaran Murugavel
Y1  - 2018/07/27
PY  - 2018
N1  - https://doi.org/10.11648/j.ajac.20180603.14
DO  - 10.11648/j.ajac.20180603.14
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 102
EP  - 125
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20180603.14
AB  - The present study was carried out to analyze the performance of anti-corrosion property for the combination of PMMA, resin and ZnO nano particle coating on mild steel in 3.5% NaCl medium at 3hrs, 6hrs and 12hrs exposure. The synthesized nano particle was characterized by FTIR, XRD and SEM analysis. The Polymer +Resin +ZnO (PRZn) combination was coated on MS by dip and spin coating methods. The optimized concentration analyses were verified by visual observation and gravimetric method which were also confirmed by electrochemical studies such as Tafel, AC impedance studies and cyclic voltammetry studies and 10% PMMA and 10% PMMA-resin combination was identified as optimum concentration. So, 10% PMMA-resin combined with 0.1g ZnO was used for further studies and coated on MS and PRZn coating offered almost cent percent corrosion protection of MS upto 12hrs exposure in 3.5% NaCl. PRZn coating was characterized by using FTIR, XRD, Zeta potential measurements and thermal stability was analyzed by thermo gravimetric methods. The high I.E offered by the coating material was due to the presence of major constituents that forms a passive film on the metal surface that protects mild steel from corrosion was identified. Profilometer analysis shows that the thickness and roughness of polymer coated specimen is less than paint coated one. Zeta potential and contact angle measurements of the combination coating material shows a protection against corrosion due to more interfacial tension and reduced size of the particles on the metal surface.
VL  - 6
IS  - 3
ER  -

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