Quantitative Analysis of Nutrient Minerals in Malagasy Rice Species by EDXRF and Dietary Intake Assessment

Herinirina Nomenjanahary Ravoson; Manovantsoatsiferana Harinoely; Njaka Namelantsoa Andriamahenina; Natolotriniavo Nomena Fitiavana Andrianirinamanantsoa; Elise Octavie Rasoazanany; Lucienne Voahangilalao Rakotozafy; Roland Raboanary

doi:doi:10.11648/j.ajac.20190705.12

Quantitative Analysis of Nutrient Minerals in Malagasy Rice Species by EDXRF and Dietary Intake Assessment

Herinirina Nomenjanahary Ravoson, Manovantsoatsiferana Harinoely, Njaka Namelantsoa Andriamahenina, Natolotriniavo Nomena Fitiavana Andrianirinamanantsoa, Elise Octavie Rasoazanany, Lucienne Voahangilalao Rakotozafy, Roland Raboanary

Published in American Journal of Applied Chemistry (Volume 7, Issue 5)

Received: 11 September 2019 Accepted: 11 October 2019 Published: 23 October 2019

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Abstract

The elemental analysis of rice samples sold in local market in Antananarivo are carried out at Institut National des Sciences et Techniques Nucléaires-Madagascar (INSTN-Madagascar) using Energy Dispersive X-Ray Fluorescence (EDXRF) spectrometer. The study aims to assess the nutritional and mineral elements contents of rice which is the staple dietary food for Malagasy people. The Malagasy rice is divided into three species according to its color: red, pink and white rice. Essential major elements namely sodium (Na), magnesium (Mg), phosphorus (P), chloride (Cl), potassium (K), calcium (Ca) and trace elements such as chromium (Cr), manganese (Mn), iron (Fe), copper (Cu), zinc (Zn), selenium (Se) and iodine (I) are quantitatively determined. The accuracy of the instrumental method and analytical procedures are checked by using the Reference Material IPE 135 (Rice sample) from the Wageningen Evaluating Programmes for Analytical Laboratory (WEPAL) in Netherland. The experimental values are in good agreement with the certified values because of a coefficient of determination R² of 0.999 and a recovery rate %R between 87% and 114%. The comparison of the elemental content of the studied rice samples with the Recommended Dietary Allowance (RDA) reveals that Red rice foods have sufficient capacity to provide adult male consumers with P, Mn, Mg, Fe, Cu and Zn. Certainly insufficient daily intake of Mg (55%), Fe (58%), Cu (89%) and Zn (79%) could be met by ingestion of vegetables and meats that are served as a side dish.

Published in	American Journal of Applied Chemistry (Volume 7, Issue 5)
DOI	10.11648/j.ajac.20190705.12
Page(s)	137-144
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Rice, EDPXRF, Madagascar, Recommended Dietary Allowance

References

[1]	http://ricepedia.org/madagascar.
[2]	JICA News – “Revolution in Madagascar, a Rice-Growing Country,” (Dec. 2013; https://www.jica.go.jp/english/news/field/2013/131204_01. Html.
[3]	Nam K. Aras, O. Yavuz Ataman, Trace Element Analysis of Food and Diet, The Royal Society of Chemistry (RCS Publishing), (2006).
[4]	Smita Kumari Panda, Kulwant Lakra, Sadhu Charan; “Panda Dietary Diversity Among Women in the Reproductive Age Group in Urban Field Practice Area, Vimsar, Burla, (2019).
[5]	Luciane B. OliveiraWagna P. C. dos Santos Leonardo S. G. Teixeira, Maria Graças A. Korn, "Direct Analysis of Cocoa Powder, Chocolate Powder, and Powdered Chocolate Drink for Multi-element Determination by Energy Dispersive X-ray Fluorescence Spectrometry", (2019).
[6]	Yusuf I. Koleleni, Shaban A. Mbike, “Analysis of Heavy Metals in Soil and Maize Grown around Namungo Gold Mine in Ruangwa District, Lindi Region in Tanzania Using X-ray Fluorescence”, (2018).
[7]	W. Wubishet Gezahegn, A. Srinivasulu, B. Aruna, S. Banerjee, M. Sudarshan, P. V. Lakshmi Narayana, A. D. P. Rao,"Analysis of Major, Minor and Trace elements Related to Ethiopia Cereal crops using EDXRF Technique", (2017).
[8]	Spectro Analytical Instruments, SPECTRO XEPOS; https://www.spectro.com/products/xrf-spectrometer/xepos-edxrf-spectrometer.
[9]	SPECTRO Analytical Instruments, Software Help X-LabPro 5; Revision 4; (2011).
[10]	Coefficient of Determination (R Squared): Definition, Calculation https://www.statisticshowto.datasciencecentral.com/probability-and-statistics/coefficient-of-determination-r-squared/.
[11]	Appendix F: “Guidelines for Standard Method Performance Requirements,” (2012), AOAC Official Methods of Analysis, p. 9; http://www.eoma.aoac.org/app_f.pdf.
[12]	C. Galas, “Assessment of trace metal bioavailability in soils and river waters using different analytical techniques to predict metals uptake by biota,” Thesis, Universita Degli Studi di Roma "TOR VERGATA", (2008), p. 19.
[13]	A. Catharine Ross, Christine L. Taylor, Ann L. Yaktine, Heather B. Del Valle, “Dietary Reference Intakes for Calcium and Vitamin D,” Institute of Medicine (US), Washington (DC), The National Academies Press, (2011), pp. 1108-1109; https://www.ncbi.nlm.nih.gov/books/NBK56070/pdf/Bookshelf_NBK56070.pdf.
[14]	Creswell J. Eastman, Michael B. Zimmermann, “The iodine deficiency disorders,” Endotext, South Dartmouth (MA), MDText.com, Inc, PMID: 25905411 (Feb. 2018) https://www.ncbi.nlm.nih.gov/books/NBK285556/.
[15]	WHO Guideline: Sodium intake for adults and children. Geneva, World Health Organization, (2012), p. 5.
[16]	FAO- “GIEWS Country Brief -Madagascar,” (2018); p. 2; https://reliefweb.int/sites/reliefweb.int/files/resources /MDG11-January-2018.pdf.

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Herinirina Nomenjanahary Ravoson, Manovantsoatsiferana Harinoely, Njaka Namelantsoa Andriamahenina, Natolotriniavo Nomena Fitiavana Andrianirinamanantsoa, Elise Octavie Rasoazanany, et al. (2019). Quantitative Analysis of Nutrient Minerals in Malagasy Rice Species by EDXRF and Dietary Intake Assessment. American Journal of Applied Chemistry, 7(5), 137-144. https://doi.org/10.11648/j.ajac.20190705.12

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ACS Style

Herinirina Nomenjanahary Ravoson; Manovantsoatsiferana Harinoely; Njaka Namelantsoa Andriamahenina; Natolotriniavo Nomena Fitiavana Andrianirinamanantsoa; Elise Octavie Rasoazanany, et al. Quantitative Analysis of Nutrient Minerals in Malagasy Rice Species by EDXRF and Dietary Intake Assessment. Am. J. Appl. Chem. 2019, 7(5), 137-144. doi: 10.11648/j.ajac.20190705.12

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AMA Style

Herinirina Nomenjanahary Ravoson, Manovantsoatsiferana Harinoely, Njaka Namelantsoa Andriamahenina, Natolotriniavo Nomena Fitiavana Andrianirinamanantsoa, Elise Octavie Rasoazanany, et al. Quantitative Analysis of Nutrient Minerals in Malagasy Rice Species by EDXRF and Dietary Intake Assessment. Am J Appl Chem. 2019;7(5):137-144. doi: 10.11648/j.ajac.20190705.12

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@article{10.11648/j.ajac.20190705.12,
  author = {Herinirina Nomenjanahary Ravoson and Manovantsoatsiferana Harinoely and Njaka Namelantsoa Andriamahenina and Natolotriniavo Nomena Fitiavana Andrianirinamanantsoa and Elise Octavie Rasoazanany and Lucienne Voahangilalao Rakotozafy and Roland Raboanary},
  title = {Quantitative Analysis of Nutrient Minerals in Malagasy Rice Species by EDXRF and Dietary Intake Assessment},
  journal = {American Journal of Applied Chemistry},
  volume = {7},
  number = {5},
  pages = {137-144},
  doi = {10.11648/j.ajac.20190705.12},
  url = {https://doi.org/10.11648/j.ajac.20190705.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20190705.12},
  abstract = {The elemental analysis of rice samples sold in local market in Antananarivo are carried out at Institut National des Sciences et Techniques Nucléaires-Madagascar (INSTN-Madagascar) using Energy Dispersive X-Ray Fluorescence (EDXRF) spectrometer. The study aims to assess the nutritional and mineral elements contents of rice which is the staple dietary food for Malagasy people. The Malagasy rice is divided into three species according to its color: red, pink and white rice. Essential major elements namely sodium (Na), magnesium (Mg), phosphorus (P), chloride (Cl), potassium (K), calcium (Ca) and trace elements such as chromium (Cr), manganese (Mn), iron (Fe), copper (Cu), zinc (Zn), selenium (Se) and iodine (I) are quantitatively determined. The accuracy of the instrumental method and analytical procedures are checked by using the Reference Material IPE 135 (Rice sample) from the Wageningen Evaluating Programmes for Analytical Laboratory (WEPAL) in Netherland. The experimental values are in good agreement with the certified values because of a coefficient of determination R² of 0.999 and a recovery rate %R between 87% and 114%. The comparison of the elemental content of the studied rice samples with the Recommended Dietary Allowance (RDA) reveals that Red rice foods have sufficient capacity to provide adult male consumers with P, Mn, Mg, Fe, Cu and Zn. Certainly insufficient daily intake of Mg (55%), Fe (58%), Cu (89%) and Zn (79%) could be met by ingestion of vegetables and meats that are served as a side dish.},
 year = {2019}
}

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TY  - JOUR
T1  - Quantitative Analysis of Nutrient Minerals in Malagasy Rice Species by EDXRF and Dietary Intake Assessment
AU  - Herinirina Nomenjanahary Ravoson
AU  - Manovantsoatsiferana Harinoely
AU  - Njaka Namelantsoa Andriamahenina
AU  - Natolotriniavo Nomena Fitiavana Andrianirinamanantsoa
AU  - Elise Octavie Rasoazanany
AU  - Lucienne Voahangilalao Rakotozafy
AU  - Roland Raboanary
Y1  - 2019/10/23
PY  - 2019
N1  - https://doi.org/10.11648/j.ajac.20190705.12
DO  - 10.11648/j.ajac.20190705.12
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 137
EP  - 144
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20190705.12
AB  - The elemental analysis of rice samples sold in local market in Antananarivo are carried out at Institut National des Sciences et Techniques Nucléaires-Madagascar (INSTN-Madagascar) using Energy Dispersive X-Ray Fluorescence (EDXRF) spectrometer. The study aims to assess the nutritional and mineral elements contents of rice which is the staple dietary food for Malagasy people. The Malagasy rice is divided into three species according to its color: red, pink and white rice. Essential major elements namely sodium (Na), magnesium (Mg), phosphorus (P), chloride (Cl), potassium (K), calcium (Ca) and trace elements such as chromium (Cr), manganese (Mn), iron (Fe), copper (Cu), zinc (Zn), selenium (Se) and iodine (I) are quantitatively determined. The accuracy of the instrumental method and analytical procedures are checked by using the Reference Material IPE 135 (Rice sample) from the Wageningen Evaluating Programmes for Analytical Laboratory (WEPAL) in Netherland. The experimental values are in good agreement with the certified values because of a coefficient of determination R² of 0.999 and a recovery rate %R between 87% and 114%. The comparison of the elemental content of the studied rice samples with the Recommended Dietary Allowance (RDA) reveals that Red rice foods have sufficient capacity to provide adult male consumers with P, Mn, Mg, Fe, Cu and Zn. Certainly insufficient daily intake of Mg (55%), Fe (58%), Cu (89%) and Zn (79%) could be met by ingestion of vegetables and meats that are served as a side dish.
VL  - 7
IS  - 5
ER  -

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Author Information

Herinirina Nomenjanahary Ravoson

Department of X-Ray Fluorescence and Environment, Institut National des Sciences et Techniques Nucléaires-Madagascar, Antananarivo, Madagascar
Manovantsoatsiferana Harinoely

Department of X-Ray Fluorescence and Environment, Institut National des Sciences et Techniques Nucléaires-Madagascar, Antananarivo, Madagascar
Njaka Namelantsoa Andriamahenina

Department of X-Ray Fluorescence and Environment, Institut National des Sciences et Techniques Nucléaires-Madagascar, Antananarivo, Madagascar
Natolotriniavo Nomena Fitiavana Andrianirinamanantsoa

Department of X-Ray Fluorescence and Environment, Institut National des Sciences et Techniques Nucléaires-Madagascar, Antananarivo, Madagascar
Elise Octavie Rasoazanany

Department of X-Ray Fluorescence and Environment, Institut National des Sciences et Techniques Nucléaires-Madagascar, Antananarivo, Madagascar
Lucienne Voahangilalao Rakotozafy

Department of X-Ray Fluorescence and Environment, Institut National des Sciences et Techniques Nucléaires-Madagascar, Antananarivo, Madagascar
Roland Raboanary

Department of X-Ray Fluorescence and Environment, Institut National des Sciences et Techniques Nucléaires-Madagascar, Antananarivo, Madagascar

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APA Style

Herinirina Nomenjanahary Ravoson, Manovantsoatsiferana Harinoely, Njaka Namelantsoa Andriamahenina, Natolotriniavo Nomena Fitiavana Andrianirinamanantsoa, Elise Octavie Rasoazanany, et al. (2019). Quantitative Analysis of Nutrient Minerals in Malagasy Rice Species by EDXRF and Dietary Intake Assessment. American Journal of Applied Chemistry, 7(5), 137-144. https://doi.org/10.11648/j.ajac.20190705.12

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ACS Style

Herinirina Nomenjanahary Ravoson; Manovantsoatsiferana Harinoely; Njaka Namelantsoa Andriamahenina; Natolotriniavo Nomena Fitiavana Andrianirinamanantsoa; Elise Octavie Rasoazanany, et al. Quantitative Analysis of Nutrient Minerals in Malagasy Rice Species by EDXRF and Dietary Intake Assessment. Am. J. Appl. Chem. 2019, 7(5), 137-144. doi: 10.11648/j.ajac.20190705.12

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AMA Style

Herinirina Nomenjanahary Ravoson, Manovantsoatsiferana Harinoely, Njaka Namelantsoa Andriamahenina, Natolotriniavo Nomena Fitiavana Andrianirinamanantsoa, Elise Octavie Rasoazanany, et al. Quantitative Analysis of Nutrient Minerals in Malagasy Rice Species by EDXRF and Dietary Intake Assessment. Am J Appl Chem. 2019;7(5):137-144. doi: 10.11648/j.ajac.20190705.12

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@article{10.11648/j.ajac.20190705.12,
  author = {Herinirina Nomenjanahary Ravoson and Manovantsoatsiferana Harinoely and Njaka Namelantsoa Andriamahenina and Natolotriniavo Nomena Fitiavana Andrianirinamanantsoa and Elise Octavie Rasoazanany and Lucienne Voahangilalao Rakotozafy and Roland Raboanary},
  title = {Quantitative Analysis of Nutrient Minerals in Malagasy Rice Species by EDXRF and Dietary Intake Assessment},
  journal = {American Journal of Applied Chemistry},
  volume = {7},
  number = {5},
  pages = {137-144},
  doi = {10.11648/j.ajac.20190705.12},
  url = {https://doi.org/10.11648/j.ajac.20190705.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20190705.12},
  abstract = {The elemental analysis of rice samples sold in local market in Antananarivo are carried out at Institut National des Sciences et Techniques Nucléaires-Madagascar (INSTN-Madagascar) using Energy Dispersive X-Ray Fluorescence (EDXRF) spectrometer. The study aims to assess the nutritional and mineral elements contents of rice which is the staple dietary food for Malagasy people. The Malagasy rice is divided into three species according to its color: red, pink and white rice. Essential major elements namely sodium (Na), magnesium (Mg), phosphorus (P), chloride (Cl), potassium (K), calcium (Ca) and trace elements such as chromium (Cr), manganese (Mn), iron (Fe), copper (Cu), zinc (Zn), selenium (Se) and iodine (I) are quantitatively determined. The accuracy of the instrumental method and analytical procedures are checked by using the Reference Material IPE 135 (Rice sample) from the Wageningen Evaluating Programmes for Analytical Laboratory (WEPAL) in Netherland. The experimental values are in good agreement with the certified values because of a coefficient of determination R² of 0.999 and a recovery rate %R between 87% and 114%. The comparison of the elemental content of the studied rice samples with the Recommended Dietary Allowance (RDA) reveals that Red rice foods have sufficient capacity to provide adult male consumers with P, Mn, Mg, Fe, Cu and Zn. Certainly insufficient daily intake of Mg (55%), Fe (58%), Cu (89%) and Zn (79%) could be met by ingestion of vegetables and meats that are served as a side dish.},
 year = {2019}
}

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TY  - JOUR
T1  - Quantitative Analysis of Nutrient Minerals in Malagasy Rice Species by EDXRF and Dietary Intake Assessment
AU  - Herinirina Nomenjanahary Ravoson
AU  - Manovantsoatsiferana Harinoely
AU  - Njaka Namelantsoa Andriamahenina
AU  - Natolotriniavo Nomena Fitiavana Andrianirinamanantsoa
AU  - Elise Octavie Rasoazanany
AU  - Lucienne Voahangilalao Rakotozafy
AU  - Roland Raboanary
Y1  - 2019/10/23
PY  - 2019
N1  - https://doi.org/10.11648/j.ajac.20190705.12
DO  - 10.11648/j.ajac.20190705.12
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 137
EP  - 144
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20190705.12
AB  - The elemental analysis of rice samples sold in local market in Antananarivo are carried out at Institut National des Sciences et Techniques Nucléaires-Madagascar (INSTN-Madagascar) using Energy Dispersive X-Ray Fluorescence (EDXRF) spectrometer. The study aims to assess the nutritional and mineral elements contents of rice which is the staple dietary food for Malagasy people. The Malagasy rice is divided into three species according to its color: red, pink and white rice. Essential major elements namely sodium (Na), magnesium (Mg), phosphorus (P), chloride (Cl), potassium (K), calcium (Ca) and trace elements such as chromium (Cr), manganese (Mn), iron (Fe), copper (Cu), zinc (Zn), selenium (Se) and iodine (I) are quantitatively determined. The accuracy of the instrumental method and analytical procedures are checked by using the Reference Material IPE 135 (Rice sample) from the Wageningen Evaluating Programmes for Analytical Laboratory (WEPAL) in Netherland. The experimental values are in good agreement with the certified values because of a coefficient of determination R² of 0.999 and a recovery rate %R between 87% and 114%. The comparison of the elemental content of the studied rice samples with the Recommended Dietary Allowance (RDA) reveals that Red rice foods have sufficient capacity to provide adult male consumers with P, Mn, Mg, Fe, Cu and Zn. Certainly insufficient daily intake of Mg (55%), Fe (58%), Cu (89%) and Zn (79%) could be met by ingestion of vegetables and meats that are served as a side dish.
VL  - 7
IS  - 5
ER  -

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