Plant-Based Silver Nanoparticles for the Detection of Lead (II) Ions

Aliyu Muhammad; Abubakar Umar Birnin-Yauri; Hannatu Abubakar Sani; Yusuf Haruna; Sayudi Yahaya Haruna; Abdulmalik Aminu

doi:doi:10.11648/j.ajac.20231103.11

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Plant-Based Silver Nanoparticles for the Detection of Lead (II) Ions

Aliyu Muhammad, Abubakar Umar Birnin-Yauri, Hannatu Abubakar Sani, Yusuf Haruna, Sayudi Yahaya Haruna, Abdulmalik Aminu

Published in American Journal of Applied Chemistry (Volume 11, Issue 3)

Received: 4 May 2023 Accepted: 22 May 2023 Published: 5 June 2023

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Abstract

Here in, silver nanoparticles (AgNPs) is synthesized using orange (Citrus sinensis) peel as reducing agent and applied in the detection of lead (II) ions in water. A simple technique was used in the synthesis of the said nanoparticles Different analytical techniques such as; UV-Visible Spectroscopy (UV-Vis), Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), and X-ray Diffraction (XRD) were used to characterize the as-synthesized AgNPs. FTIR results revealed the fingerprint of the active antioxidants involved in the reduction of silver nitrate to AgNPs. The XRD results shows that silver nanoparticles possess crystalline face centered cubic (FCC) lattice structures. Variable experimental parameters such as; silver ion concentration, pH, incubation time, plant extract volume, and temperature were investigated. The results shows that 1:8 ratio of plant extract volume to silver salt precursor the nanoparticles have yellowish brown and golden brown colors and a surface plasmon peak around 420 nm, SEM images displayed an array of polydispersed spherical AgNPs having an average size of 55 nm. The XRD pattern revealed peaks that are similar to that of silver while FTIR results revealed the functional groups associated with reducing silver ions and stabilizing silver nanoparticles. Colorimetric studies showed that the AgNPs lose their characteristic color when they interact with lead ions, and with the color gone, the surface plasmon resonance (SPR) absorption peak also disappears. A high selectivity and sensitivity were recorded towards Pb (II) ions.

Published in	American Journal of Applied Chemistry (Volume 11, Issue 3)
DOI	10.11648/j.ajac.20231103.11
Page(s)	75-80
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2023. Published by Science Publishing Group

Keywords

AgNPs, Orange Peels, Surface Plasmon Resonance, Lead (II) Ions, Detection, Green Synthesis

References

[1]	Annadhasan M., T. Muthukumarasamyvel, V. R. Sankar Babu and N. Rajendiran, (2014). ACS Sustain. Chem. Eng. 2, 887. doi: 10.1021/sc400500z.
[2]	Mohammed MB, Volkov V, Link S, Sayed MAE. (2000). The ‘lightning’ gold nanorods: fluorescence enhancement of over a million compared to the gold metal. Chem. Phy. Lett. 317: 517-523.
[3]	Rai M, Gade A, Yadav A. (2011). Biogenic nanoparticles: an introduction to what they are, how they are synthesized and their applications in microbiology. Springer, Berlin, pp. 1-16.
[4]	Yunus, I. S, A. Kurniawan Harwin, D. Adityawarman, A. Indarto. (2012). Nanotechnologies in water and air pollution treatment. Environ. Tech. Rev. 1. 136-148.
[5]	Kendall M, and Holgate S. (2012). Health impact and toxicological effects of nanomaterials in the lung. Respirology. 17: 743-758.
[6]	Zahir F., Rizwi, S. J., Haq, S. K., and Khan, R. H. (2005). Low dose lead toxicity and human health. Environmental Toxicology and Pharmacology, 20 (2), 351-60.
[7]	Yamini, Y, N. Alizadeh, M. Shamsipur. (1997). Solid phase extraction and determination of ultra-trace amounts of lead (II) using octadecyl silica membrane disks modified by hexathia-18-crown-6-tetraone and cold vapor atomic absorption spectrometry. Anal. Chim. Acta 355, 69-74.
[8]	Kuswandi, K., A. Nuriman, H. H. Dam, D. N. Reinhoudt, W. Verboom. (2007). Development of a disposable lead ion-selective optode based on trityl-picolamide as ionophore. Anal. Chim. Acta, 591, 208–213.
[9]	Fong, B., W. Mei, T. S. Siu, J. Lee, K. Sai, S. Tam. (2007). Determination of lead in whole blood and urine by inductively coupled plasma mass spectrometry. J. Anal. Toxicol. 31, 281–287.
[10]	Ichinoki, S., N. Kitahata, Y. Fujii. (2004). Selective determination of lead (II) ion in water by solvent extraction followed by reversed-phase HPLC. J. Liq. Chromatogr. Rel. Technol. 27, 1785-1798.
[11]	Aslan, K., J. R. Lakowicz, C. D. Geddes. (2004). Nanogold–plasmon-resonance-based glucose sensing. Anal. Biochem. 330, 145-155.
[12]	Park Y. (2014). New paradigm shift for the green synthesis of antibacterial silver nanoparticles utilizing plant extracts. Toxicol. Res., 30: 169-178.
[13]	Omobayo S. A., Chanbasha B., Khan Z., Abdulnaser A., Zia S. (2016). Biogenic synthesis of silver nanoparticles; study of the effect of physicochemical parameters and application as nanosensor in the colorimetric detection of Pb²⁺ in water. International Journal of Environmental Analytical Chemistry, 96: 8, 776-788.
[14]	Park, Y.; Hing, Y. N.; Weyers, A.; Kim, Y. S.; Linhardt, R. J. (2011). Polysaccharide and phytochemicals: A natural reservoir for the green synthesis of gold and silver nanoparticles. IET Nanobiotechnol. 5 (3), 69-78.
[15]	Zaki S, El-Kady MF, Abd-El-Haleem D. (2011). Determination of the effective origin source for nanosilver particles produced by Escherichia coli strain S78 and its application as antimicrobial agent. Mater. Res Bull., 46: 1571-1576.
[16]	Dubey, M.; Bhadauria, S.; Kushwah, B. S. (2009). Green synthesis of nanosilver particles from extract of Eucalyptus hybrida (Safeda) leaf. Dig. J. Nanomater. Biostruct. 4 (3), 537-543.
[17]	Pimprikar, P. S., Joshi, S. S., Kumar, A. R., Zinjarde, S. S., and Kulkarni, S. K. (2009). Influence of biomass and gold salt concentration on nanoparticle synthesis by the tropical marine yeast Yarrowia lipolytica NCIM 3589. Colloids and Surfaces, B: Biointerfaces, 74, 309e316.
[18]	Huang JL, Li QB, Sun DH, Lu YH, Su YB, Yang X. (2007). Biosynthesis of silver and gold nanoparticles by novel sundried Cinnamomum camphora leaf. Nanotechnology 18 (10), 105-106. http://dx.doi.org/10.1088/0957-4484/18/10/105104
[19]	Sathishkumar, M.; Sneha, K.; Yun, Y. S. (2009). Palladium nanocrystals synthesis using Curcuma longa tuber extract. Int. J. Mater. Sci., 4 (1), 11-17.
[20]	Vanaja, M.; Annadurai, G. (2012). Coleus aromaticus leaf extract mediated synthesis of silver nanoparticles and its bactericidal activity. Appl. Nanosci., DOI: 10.1007/s13204-012-0121-9.
[21]	Abdulmalik A. Sulayman A. O. (2020). Fast Orange Peel-Mediated Synthesis of Silver Nanoparticles and Use as Visual Colorimetric Sensor in the Selective Detection of Mercury (II) Ions", Arabian Journal for Science and Engineering, 46, 5477-5487.
[22]	Noruzi, M., Davood Z, Kamyar K, Daryoush D. (2011). Rapid green synthesis of gold nanoparticles using Rosa hybrida petal extract at room temperature. Spectrochimica Acta Part A, 79, 1461-1465.
[23]	Fayaz AM, Balaji K, Kalaichelvan PT, Venkatesan R. (2009). Fungal based synthesis of silver nanoparticles — an effect of temperature on the size of particles. Colloids Surf B; 74: 123-6.
[24]	Jiang H, Manolache S, Lee Wong AC, Denes FS. (2004). Plasma enhanced deposition of silver nanoparticles onto polymer and metal surfaces for the generation of antimicrobial characteristics. J. Appl. Polym. Sci., 93: 1411-1422.
[25]	Dhand V, Soumya L, Bharadwaj S. (2016). Green synthesis of silver nanoparticles using coffee arabica seed extract and its antibacterial activity. Mater. Sci. Eng, C., 58: 36-43.
[26]	Gopinatha V, Ali MD, Priyadarshini S, Meera Priyadharsshini N, Thajuddinb N, Velusamy P. (2012). Biosynthesis of silver nanoparticles from Tribulus terrestris and its antimicrobial activity: a novel biological approach. Colloid Surf B: Biointerface, 96 (69-74).
[27]	Rastogi R. B. L., Sashidhar, D., Karunasagar and J. Arunachalam, (2014). Gum kondagogu reduced/stabilized silver nanoparticles as direct colorimetric sensor for the sensitive detection of Pb²⁺ in aqueous system. Talanta, 118, 111-117. doi: 10.1016/j.talanta.2013.10.012.
[28]	Farhadi K., M. Forough, R. Molaei, S. Hajizadeh, A. Rafipour. (2012). Sens. Actuators B., 161; 880-885.

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APA Style

Aliyu Muhammad, Abubakar Umar Birnin-Yauri, Hannatu Abubakar Sani, Yusuf Haruna, Sayudi Yahaya Haruna, et al. (2023). Plant-Based Silver Nanoparticles for the Detection of Lead (II) Ions. American Journal of Applied Chemistry, 11(3), 75-80. https://doi.org/10.11648/j.ajac.20231103.11

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ACS Style

Aliyu Muhammad; Abubakar Umar Birnin-Yauri; Hannatu Abubakar Sani; Yusuf Haruna; Sayudi Yahaya Haruna, et al. Plant-Based Silver Nanoparticles for the Detection of Lead (II) Ions. Am. J. Appl. Chem. 2023, 11(3), 75-80. doi: 10.11648/j.ajac.20231103.11

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AMA Style

Aliyu Muhammad, Abubakar Umar Birnin-Yauri, Hannatu Abubakar Sani, Yusuf Haruna, Sayudi Yahaya Haruna, et al. Plant-Based Silver Nanoparticles for the Detection of Lead (II) Ions. Am J Appl Chem. 2023;11(3):75-80. doi: 10.11648/j.ajac.20231103.11

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@article{10.11648/j.ajac.20231103.11,
  author = {Aliyu Muhammad and Abubakar Umar Birnin-Yauri and Hannatu Abubakar Sani and Yusuf Haruna and Sayudi Yahaya Haruna and Abdulmalik Aminu},
  title = {Plant-Based Silver Nanoparticles for the Detection of Lead (II) Ions},
  journal = {American Journal of Applied Chemistry},
  volume = {11},
  number = {3},
  pages = {75-80},
  doi = {10.11648/j.ajac.20231103.11},
  url = {https://doi.org/10.11648/j.ajac.20231103.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20231103.11},
  abstract = {Here in, silver nanoparticles (AgNPs) is synthesized using orange (Citrus sinensis) peel as reducing agent and applied in the detection of lead (II) ions in water. A simple technique was used in the synthesis of the said nanoparticles Different analytical techniques such as; UV-Visible Spectroscopy (UV-Vis), Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), and X-ray Diffraction (XRD) were used to characterize the as-synthesized AgNPs. FTIR results revealed the fingerprint of the active antioxidants involved in the reduction of silver nitrate to AgNPs. The XRD results shows that silver nanoparticles possess crystalline face centered cubic (FCC) lattice structures. Variable experimental parameters such as; silver ion concentration, pH, incubation time, plant extract volume, and temperature were investigated. The results shows that 1:8 ratio of plant extract volume to silver salt precursor the nanoparticles have yellowish brown and golden brown colors and a surface plasmon peak around 420 nm, SEM images displayed an array of polydispersed spherical AgNPs having an average size of 55 nm. The XRD pattern revealed peaks that are similar to that of silver while FTIR results revealed the functional groups associated with reducing silver ions and stabilizing silver nanoparticles. Colorimetric studies showed that the AgNPs lose their characteristic color when they interact with lead ions, and with the color gone, the surface plasmon resonance (SPR) absorption peak also disappears. A high selectivity and sensitivity were recorded towards Pb (II) ions.},
 year = {2023}
}

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TY  - JOUR
T1  - Plant-Based Silver Nanoparticles for the Detection of Lead (II) Ions
AU  - Aliyu Muhammad
AU  - Abubakar Umar Birnin-Yauri
AU  - Hannatu Abubakar Sani
AU  - Yusuf Haruna
AU  - Sayudi Yahaya Haruna
AU  - Abdulmalik Aminu
Y1  - 2023/06/05
PY  - 2023
N1  - https://doi.org/10.11648/j.ajac.20231103.11
DO  - 10.11648/j.ajac.20231103.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 75
EP  - 80
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20231103.11
AB  - Here in, silver nanoparticles (AgNPs) is synthesized using orange (Citrus sinensis) peel as reducing agent and applied in the detection of lead (II) ions in water. A simple technique was used in the synthesis of the said nanoparticles Different analytical techniques such as; UV-Visible Spectroscopy (UV-Vis), Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), and X-ray Diffraction (XRD) were used to characterize the as-synthesized AgNPs. FTIR results revealed the fingerprint of the active antioxidants involved in the reduction of silver nitrate to AgNPs. The XRD results shows that silver nanoparticles possess crystalline face centered cubic (FCC) lattice structures. Variable experimental parameters such as; silver ion concentration, pH, incubation time, plant extract volume, and temperature were investigated. The results shows that 1:8 ratio of plant extract volume to silver salt precursor the nanoparticles have yellowish brown and golden brown colors and a surface plasmon peak around 420 nm, SEM images displayed an array of polydispersed spherical AgNPs having an average size of 55 nm. The XRD pattern revealed peaks that are similar to that of silver while FTIR results revealed the functional groups associated with reducing silver ions and stabilizing silver nanoparticles. Colorimetric studies showed that the AgNPs lose their characteristic color when they interact with lead ions, and with the color gone, the surface plasmon resonance (SPR) absorption peak also disappears. A high selectivity and sensitivity were recorded towards Pb (II) ions.
VL  - 11
IS  - 3
ER  -

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Author Information

Aliyu Muhammad

Department of Pure and Applied Chemistry, Faculty of Physical Sciences, Kebbi State University of Science and Technology, Aliero, Nigeria
Abubakar Umar Birnin-Yauri

Department of Pure and Applied Chemistry, Faculty of Physical Sciences, Kebbi State University of Science and Technology, Aliero, Nigeria
Hannatu Abubakar Sani

Department of Pure and Applied Chemistry, Faculty of Physical Sciences, Kebbi State University of Science and Technology, Aliero, Nigeria
Yusuf Haruna

Department of Pure and Applied Chemistry, Faculty of Physical Sciences, Kebbi State University of Science and Technology, Aliero, Nigeria
Sayudi Yahaya Haruna

Department of Pure and Applied Chemistry, Faculty of Physical Sciences, Kebbi State University of Science and Technology, Aliero, Nigeria
Abdulmalik Aminu

Department of Pure and Industrial Chemistry, Faculty of Science, Federal University, Birnin Kebbi, Nigeria

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Plain Text BibTeX RIS

APA Style

Aliyu Muhammad, Abubakar Umar Birnin-Yauri, Hannatu Abubakar Sani, Yusuf Haruna, Sayudi Yahaya Haruna, et al. (2023). Plant-Based Silver Nanoparticles for the Detection of Lead (II) Ions. American Journal of Applied Chemistry, 11(3), 75-80. https://doi.org/10.11648/j.ajac.20231103.11

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ACS Style

Aliyu Muhammad; Abubakar Umar Birnin-Yauri; Hannatu Abubakar Sani; Yusuf Haruna; Sayudi Yahaya Haruna, et al. Plant-Based Silver Nanoparticles for the Detection of Lead (II) Ions. Am. J. Appl. Chem. 2023, 11(3), 75-80. doi: 10.11648/j.ajac.20231103.11

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AMA Style

Aliyu Muhammad, Abubakar Umar Birnin-Yauri, Hannatu Abubakar Sani, Yusuf Haruna, Sayudi Yahaya Haruna, et al. Plant-Based Silver Nanoparticles for the Detection of Lead (II) Ions. Am J Appl Chem. 2023;11(3):75-80. doi: 10.11648/j.ajac.20231103.11

Copy | Download

@article{10.11648/j.ajac.20231103.11,
  author = {Aliyu Muhammad and Abubakar Umar Birnin-Yauri and Hannatu Abubakar Sani and Yusuf Haruna and Sayudi Yahaya Haruna and Abdulmalik Aminu},
  title = {Plant-Based Silver Nanoparticles for the Detection of Lead (II) Ions},
  journal = {American Journal of Applied Chemistry},
  volume = {11},
  number = {3},
  pages = {75-80},
  doi = {10.11648/j.ajac.20231103.11},
  url = {https://doi.org/10.11648/j.ajac.20231103.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20231103.11},
  abstract = {Here in, silver nanoparticles (AgNPs) is synthesized using orange (Citrus sinensis) peel as reducing agent and applied in the detection of lead (II) ions in water. A simple technique was used in the synthesis of the said nanoparticles Different analytical techniques such as; UV-Visible Spectroscopy (UV-Vis), Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), and X-ray Diffraction (XRD) were used to characterize the as-synthesized AgNPs. FTIR results revealed the fingerprint of the active antioxidants involved in the reduction of silver nitrate to AgNPs. The XRD results shows that silver nanoparticles possess crystalline face centered cubic (FCC) lattice structures. Variable experimental parameters such as; silver ion concentration, pH, incubation time, plant extract volume, and temperature were investigated. The results shows that 1:8 ratio of plant extract volume to silver salt precursor the nanoparticles have yellowish brown and golden brown colors and a surface plasmon peak around 420 nm, SEM images displayed an array of polydispersed spherical AgNPs having an average size of 55 nm. The XRD pattern revealed peaks that are similar to that of silver while FTIR results revealed the functional groups associated with reducing silver ions and stabilizing silver nanoparticles. Colorimetric studies showed that the AgNPs lose their characteristic color when they interact with lead ions, and with the color gone, the surface plasmon resonance (SPR) absorption peak also disappears. A high selectivity and sensitivity were recorded towards Pb (II) ions.},
 year = {2023}
}

Copy | Download

TY  - JOUR
T1  - Plant-Based Silver Nanoparticles for the Detection of Lead (II) Ions
AU  - Aliyu Muhammad
AU  - Abubakar Umar Birnin-Yauri
AU  - Hannatu Abubakar Sani
AU  - Yusuf Haruna
AU  - Sayudi Yahaya Haruna
AU  - Abdulmalik Aminu
Y1  - 2023/06/05
PY  - 2023
N1  - https://doi.org/10.11648/j.ajac.20231103.11
DO  - 10.11648/j.ajac.20231103.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 75
EP  - 80
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20231103.11
AB  - Here in, silver nanoparticles (AgNPs) is synthesized using orange (Citrus sinensis) peel as reducing agent and applied in the detection of lead (II) ions in water. A simple technique was used in the synthesis of the said nanoparticles Different analytical techniques such as; UV-Visible Spectroscopy (UV-Vis), Scanning Electron Microscopy (SEM), Fourier Transform Infrared Spectroscopy (FTIR), and X-ray Diffraction (XRD) were used to characterize the as-synthesized AgNPs. FTIR results revealed the fingerprint of the active antioxidants involved in the reduction of silver nitrate to AgNPs. The XRD results shows that silver nanoparticles possess crystalline face centered cubic (FCC) lattice structures. Variable experimental parameters such as; silver ion concentration, pH, incubation time, plant extract volume, and temperature were investigated. The results shows that 1:8 ratio of plant extract volume to silver salt precursor the nanoparticles have yellowish brown and golden brown colors and a surface plasmon peak around 420 nm, SEM images displayed an array of polydispersed spherical AgNPs having an average size of 55 nm. The XRD pattern revealed peaks that are similar to that of silver while FTIR results revealed the functional groups associated with reducing silver ions and stabilizing silver nanoparticles. Colorimetric studies showed that the AgNPs lose their characteristic color when they interact with lead ions, and with the color gone, the surface plasmon resonance (SPR) absorption peak also disappears. A high selectivity and sensitivity were recorded towards Pb (II) ions.
VL  - 11
IS  - 3
ER  -

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