A Fresh Look at the Kinetics of Pentosan Removal from Lignocellulosic Biomass

Surendra Pratap Yadav; Uttam Kumar Ghosh; Amiya Kumar Ray

doi:doi:10.11648/j.ajche.20160406.14

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A Fresh Look at the Kinetics of Pentosan Removal from Lignocellulosic Biomass

Surendra Pratap Yadav, Uttam Kumar Ghosh, Amiya Kumar Ray

Published in American Journal of Chemical Engineering (Volume 4, Issue 6)

Received: 4 October 2016 Accepted: 13 October 2016 Published: 7 January 2017

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Abstract

The effect of time, temperature and concentration of prehydrolyzing agent on the biomass prehydrolysis have been studied for pentosan removal. Basic kinetic parameters i.e. rate constant, order of reaction, energy of activation and frequency factor were calculated. This study on the kinetics of pentosan removal reveals that the rate of pentosan removal does not follow exactly first order kinetics and shifting of order is observed during the reaction. In searching for a kinetic equation for pentosan removal, it was found that the data was well fitted by an order at higher concentration and by another order at lower concentration of prehydrolyzing agent. The order of reaction of pentosan removal lies between 0.8 to 1.40. A regression model was developed for % pentosan removal relating to temperature and time for water prehydrolysis at higher temperatures. This model was well fitted by data given in literature.

Published in	American Journal of Chemical Engineering (Volume 4, Issue 6)
DOI	10.11648/j.ajche.20160406.14
Page(s)	161-169
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Hemicelluloses, Pentosan, Prehydrolysis, Arrhenius, Reaction Order

References

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APA Style

Surendra Pratap Yadav, Uttam Kumar Ghosh, Amiya Kumar Ray. (2017). A Fresh Look at the Kinetics of Pentosan Removal from Lignocellulosic Biomass. American Journal of Chemical Engineering, 4(6), 161-169. https://doi.org/10.11648/j.ajche.20160406.14

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ACS Style

Surendra Pratap Yadav; Uttam Kumar Ghosh; Amiya Kumar Ray. A Fresh Look at the Kinetics of Pentosan Removal from Lignocellulosic Biomass. Am. J. Chem. Eng. 2017, 4(6), 161-169. doi: 10.11648/j.ajche.20160406.14

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AMA Style

Surendra Pratap Yadav, Uttam Kumar Ghosh, Amiya Kumar Ray. A Fresh Look at the Kinetics of Pentosan Removal from Lignocellulosic Biomass. Am J Chem Eng. 2017;4(6):161-169. doi: 10.11648/j.ajche.20160406.14

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@article{10.11648/j.ajche.20160406.14,
  author = {Surendra Pratap Yadav and Uttam Kumar Ghosh and Amiya Kumar Ray},
  title = {A Fresh Look at the Kinetics of Pentosan Removal from Lignocellulosic Biomass},
  journal = {American Journal of Chemical Engineering},
  volume = {4},
  number = {6},
  pages = {161-169},
  doi = {10.11648/j.ajche.20160406.14},
  url = {https://doi.org/10.11648/j.ajche.20160406.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20160406.14},
  abstract = {The effect of time, temperature and concentration of prehydrolyzing agent on the biomass prehydrolysis have been studied for pentosan removal. Basic kinetic parameters i.e. rate constant, order of reaction, energy of activation and frequency factor were calculated. This study on the kinetics of pentosan removal reveals that the rate of pentosan removal does not follow exactly first order kinetics and shifting of order is observed during the reaction. In searching for a kinetic equation for pentosan removal, it was found that the data was well fitted by an order at higher concentration and by another order at lower concentration of prehydrolyzing agent. The order of reaction of pentosan removal lies between 0.8 to 1.40. A regression model was developed for % pentosan removal relating to temperature and time for water prehydrolysis at higher temperatures. This model was well fitted by data given in literature.},
 year = {2017}
}

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TY  - JOUR
T1  - A Fresh Look at the Kinetics of Pentosan Removal from Lignocellulosic Biomass
AU  - Surendra Pratap Yadav
AU  - Uttam Kumar Ghosh
AU  - Amiya Kumar Ray
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PY  - 2017
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DO  - 10.11648/j.ajche.20160406.14
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 161
EP  - 169
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20160406.14
AB  - The effect of time, temperature and concentration of prehydrolyzing agent on the biomass prehydrolysis have been studied for pentosan removal. Basic kinetic parameters i.e. rate constant, order of reaction, energy of activation and frequency factor were calculated. This study on the kinetics of pentosan removal reveals that the rate of pentosan removal does not follow exactly first order kinetics and shifting of order is observed during the reaction. In searching for a kinetic equation for pentosan removal, it was found that the data was well fitted by an order at higher concentration and by another order at lower concentration of prehydrolyzing agent. The order of reaction of pentosan removal lies between 0.8 to 1.40. A regression model was developed for % pentosan removal relating to temperature and time for water prehydrolysis at higher temperatures. This model was well fitted by data given in literature.
VL  - 4
IS  - 6
ER  -

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Author Information

Surendra Pratap Yadav

Department of Polymer & Process Engg., Indian Institute of Technology Roorkee, Roorkee, India
Uttam Kumar Ghosh

Department of Polymer & Process Engg., Indian Institute of Technology Roorkee, Roorkee, India
Amiya Kumar Ray

Department of Polymer & Process Engg., Indian Institute of Technology Roorkee, Roorkee, India

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Plain Text BibTeX RIS

APA Style

Surendra Pratap Yadav, Uttam Kumar Ghosh, Amiya Kumar Ray. (2017). A Fresh Look at the Kinetics of Pentosan Removal from Lignocellulosic Biomass. American Journal of Chemical Engineering, 4(6), 161-169. https://doi.org/10.11648/j.ajche.20160406.14

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ACS Style

Surendra Pratap Yadav; Uttam Kumar Ghosh; Amiya Kumar Ray. A Fresh Look at the Kinetics of Pentosan Removal from Lignocellulosic Biomass. Am. J. Chem. Eng. 2017, 4(6), 161-169. doi: 10.11648/j.ajche.20160406.14

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AMA Style

Surendra Pratap Yadav, Uttam Kumar Ghosh, Amiya Kumar Ray. A Fresh Look at the Kinetics of Pentosan Removal from Lignocellulosic Biomass. Am J Chem Eng. 2017;4(6):161-169. doi: 10.11648/j.ajche.20160406.14

Copy | Download

@article{10.11648/j.ajche.20160406.14,
  author = {Surendra Pratap Yadav and Uttam Kumar Ghosh and Amiya Kumar Ray},
  title = {A Fresh Look at the Kinetics of Pentosan Removal from Lignocellulosic Biomass},
  journal = {American Journal of Chemical Engineering},
  volume = {4},
  number = {6},
  pages = {161-169},
  doi = {10.11648/j.ajche.20160406.14},
  url = {https://doi.org/10.11648/j.ajche.20160406.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajche.20160406.14},
  abstract = {The effect of time, temperature and concentration of prehydrolyzing agent on the biomass prehydrolysis have been studied for pentosan removal. Basic kinetic parameters i.e. rate constant, order of reaction, energy of activation and frequency factor were calculated. This study on the kinetics of pentosan removal reveals that the rate of pentosan removal does not follow exactly first order kinetics and shifting of order is observed during the reaction. In searching for a kinetic equation for pentosan removal, it was found that the data was well fitted by an order at higher concentration and by another order at lower concentration of prehydrolyzing agent. The order of reaction of pentosan removal lies between 0.8 to 1.40. A regression model was developed for % pentosan removal relating to temperature and time for water prehydrolysis at higher temperatures. This model was well fitted by data given in literature.},
 year = {2017}
}

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TY  - JOUR
T1  - A Fresh Look at the Kinetics of Pentosan Removal from Lignocellulosic Biomass
AU  - Surendra Pratap Yadav
AU  - Uttam Kumar Ghosh
AU  - Amiya Kumar Ray
Y1  - 2017/01/07
PY  - 2017
N1  - https://doi.org/10.11648/j.ajche.20160406.14
DO  - 10.11648/j.ajche.20160406.14
T2  - American Journal of Chemical Engineering
JF  - American Journal of Chemical Engineering
JO  - American Journal of Chemical Engineering
SP  - 161
EP  - 169
PB  - Science Publishing Group
SN  - 2330-8613
UR  - https://doi.org/10.11648/j.ajche.20160406.14
AB  - The effect of time, temperature and concentration of prehydrolyzing agent on the biomass prehydrolysis have been studied for pentosan removal. Basic kinetic parameters i.e. rate constant, order of reaction, energy of activation and frequency factor were calculated. This study on the kinetics of pentosan removal reveals that the rate of pentosan removal does not follow exactly first order kinetics and shifting of order is observed during the reaction. In searching for a kinetic equation for pentosan removal, it was found that the data was well fitted by an order at higher concentration and by another order at lower concentration of prehydrolyzing agent. The order of reaction of pentosan removal lies between 0.8 to 1.40. A regression model was developed for % pentosan removal relating to temperature and time for water prehydrolysis at higher temperatures. This model was well fitted by data given in literature.
VL  - 4
IS  - 6
ER  -

Copy | Download