Metal complexes of Cr(III), Co(II) and Cd(II) ions were synthesizedwith a ONS containing Schiff base ligand, 2-bis(2-oxoindolin-3-ylidene)hydrazinecarbothioamide which was derived from the condensation reaction of thiosemicarbazide and isatin. The ligand and complexes were isolated from the reaction in the solid form and characterized by IR, UV-Visible, Thermal analysis and some physical measurements. Spectroscopic evidence indicated that the Schiff base behaved as ONS coordinating hexadentate chelating agent. Magnetic susceptibility data coupled with electronic spectra suggested a distorted octahedral structure of the complexes. The overall reaction was monitored by TLC and UV-Visible spectral analysis. The Schiff base and their metal complexes have been shown moderate to strong microbial activity.
| Published in | Chemical and Biomolecular Engineering (Volume 2, Issue 1) |
| DOI | 10.11648/j.cbe.20170201.16 |
| Page(s) | 41-50 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2017. Published by Science Publishing Group |
Transition Metal Complex, IR, UV-Visible Spectra Analysis, Antibacterial Activity, Schiff Base, TGA and DTG
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APA Style
Md. Saddam Hossain, Shudeepta Sarker, A. S. M. Elias Shaheed, Md. Mamun Hossain, Abdul Alim-Al-Bari, et al. (2017). Thermal and Spectral Characterization of Cr(III), Co(II) and Cd(II) Metal Complexes Containing Bis-Imine Novel Schiff Base Ligand Towards Potential Biological Application. Chemical and Biomolecular Engineering, 2(1), 41-50. https://doi.org/10.11648/j.cbe.20170201.16
ACS Style
Md. Saddam Hossain; Shudeepta Sarker; A. S. M. Elias Shaheed; Md. Mamun Hossain; Abdul Alim-Al-Bari, et al. Thermal and Spectral Characterization of Cr(III), Co(II) and Cd(II) Metal Complexes Containing Bis-Imine Novel Schiff Base Ligand Towards Potential Biological Application. Chem. Biomol. Eng. 2017, 2(1), 41-50. doi: 10.11648/j.cbe.20170201.16
AMA Style
Md. Saddam Hossain, Shudeepta Sarker, A. S. M. Elias Shaheed, Md. Mamun Hossain, Abdul Alim-Al-Bari, et al. Thermal and Spectral Characterization of Cr(III), Co(II) and Cd(II) Metal Complexes Containing Bis-Imine Novel Schiff Base Ligand Towards Potential Biological Application. Chem Biomol Eng. 2017;2(1):41-50. doi: 10.11648/j.cbe.20170201.16
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Download@article{10.11648/j.cbe.20170201.16,
author = {Md. Saddam Hossain and Shudeepta Sarker and A. S. M. Elias Shaheed and Md. Mamun Hossain and Abdul Alim-Al-Bari and Md. Rabiul Karim and C. M. Zakaria and Md. Kudrat-E-Zahan},
title = {Thermal and Spectral Characterization of Cr(III), Co(II) and Cd(II) Metal Complexes Containing Bis-Imine Novel Schiff Base Ligand Towards Potential Biological Application},
journal = {Chemical and Biomolecular Engineering},
volume = {2},
number = {1},
pages = {41-50},
doi = {10.11648/j.cbe.20170201.16},
url = {https://doi.org/10.11648/j.cbe.20170201.16},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.cbe.20170201.16},
abstract = {Metal complexes of Cr(III), Co(II) and Cd(II) ions were synthesizedwith a ONS containing Schiff base ligand, 2-bis(2-oxoindolin-3-ylidene)hydrazinecarbothioamide which was derived from the condensation reaction of thiosemicarbazide and isatin. The ligand and complexes were isolated from the reaction in the solid form and characterized by IR, UV-Visible, Thermal analysis and some physical measurements. Spectroscopic evidence indicated that the Schiff base behaved as ONS coordinating hexadentate chelating agent. Magnetic susceptibility data coupled with electronic spectra suggested a distorted octahedral structure of the complexes. The overall reaction was monitored by TLC and UV-Visible spectral analysis. The Schiff base and their metal complexes have been shown moderate to strong microbial activity.},
year = {2017}
}
TY - JOUR T1 - Thermal and Spectral Characterization of Cr(III), Co(II) and Cd(II) Metal Complexes Containing Bis-Imine Novel Schiff Base Ligand Towards Potential Biological Application AU - Md. Saddam Hossain AU - Shudeepta Sarker AU - A. S. M. Elias Shaheed AU - Md. Mamun Hossain AU - Abdul Alim-Al-Bari AU - Md. Rabiul Karim AU - C. M. Zakaria AU - Md. Kudrat-E-Zahan Y1 - 2017/02/24 PY - 2017 N1 - https://doi.org/10.11648/j.cbe.20170201.16 DO - 10.11648/j.cbe.20170201.16 T2 - Chemical and Biomolecular Engineering JF - Chemical and Biomolecular Engineering JO - Chemical and Biomolecular Engineering SP - 41 EP - 50 PB - Science Publishing Group SN - 2578-8884 UR - https://doi.org/10.11648/j.cbe.20170201.16 AB - Metal complexes of Cr(III), Co(II) and Cd(II) ions were synthesizedwith a ONS containing Schiff base ligand, 2-bis(2-oxoindolin-3-ylidene)hydrazinecarbothioamide which was derived from the condensation reaction of thiosemicarbazide and isatin. The ligand and complexes were isolated from the reaction in the solid form and characterized by IR, UV-Visible, Thermal analysis and some physical measurements. Spectroscopic evidence indicated that the Schiff base behaved as ONS coordinating hexadentate chelating agent. Magnetic susceptibility data coupled with electronic spectra suggested a distorted octahedral structure of the complexes. The overall reaction was monitored by TLC and UV-Visible spectral analysis. The Schiff base and their metal complexes have been shown moderate to strong microbial activity. VL - 2 IS - 1 ER -
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