Broading Spectral Line Method for Determination Structural Parameters and Electronic Transitions in CdSe Artificial Atom

Mohammed Anwar Batal; Kaesar Alyamani

doi:doi:10.11648/j.ijpp.20170101.13

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Broading Spectral Line Method for Determination Structural Parameters and Electronic Transitions in CdSe Artificial Atom

Mohammed Anwar Batal, Kaesar Alyamani

Published in International Journal of Photochemistry and Photobiology (Volume 1, Issue 1)

Received: 21 September 2016 Accepted: 12 January 2017 Published: 1 March 2017

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Abstract

Multi layers CdSe artificial atoms system prepared using Spin coating method. Using W-H method, which based on XRD Broading line profile, structural parameters of FTO/CdSe system were calculated. XRD spectrum reveal that CdSe nanoparticles have hexagonal structure, have high strain, show deposition layer on other do more stress and strain (Crystallization size (6.16 A◦), lattice constant C(7.16A◦), effective strain (0.07377 (lin^–2 m^–4)) between the nano crystals and dislocation (irregular) (26.443×10²⁰ (lin^–2 m^–4)) were determined), which confirm more later by anther spectroscopic method. By doing fitting between experimental and theoretical absorption using Gaussian profile and Doppler broading line. Different electronic transitions were deduced and other broading curve were studying such as effect of particle size of artificial atoms, with doing more accurate fitting reveals existence of two intensities lines attributed to diffusion layer between FTO and CdSe artificial atoms.

Published in	International Journal of Photochemistry and Photobiology (Volume 1, Issue 1)
DOI	10.11648/j.ijpp.20170101.13
Page(s)	13-20
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

CdSe, Artificial Atoms, XRD Broading, Absorption Spectra, Doppler Broading

References

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[3]	P. K. Khanna: “Synthesis and optical properties of CdSe nanocrystal” Journal of Taylor & Francis in 26 sep 2008.
[4]	W. Xu, Y. Wang, S. Liang, R. Xu, G. Zhang, F. Xu and D. Yin: “Optimized synthesis and fluorescence spectrum analysis of CdSe quamtum dots” Journal of Taylor & Francis in 5 dec 2003.
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[8]	Tamaki H, Watanabe H, Kamiyama S, Oaki Y, Imai H. Size-dependent thermochromism through enhanced electron-phonon coupling in 1nm quantum dots. Angew Chem Int Ed Engl. 2014; 53: 10706-9.
[9]	Kenneth M. Goodfellow, Meni Wanunu, Chitraleema Chakraborty, Todd Krauss, Kristina Driscoll, Kelly Sowers, Pradeep Waduge, and A. Nick Vamivakas Distance-dependent energy transfer between CdSe/CdS quantum dots and a two-dimensional semiconductor. APPLIED PHYSICS LETTERS 108, 021101 (2016).
[10]	P. Gupta and M. Ramrakhiani "Influence of the Particle Size on the Optical Properties of CdSe Nanoparticles "The Open Nanoscience Journal, 2009, 3, 15-19.
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[15]	N J Suthan Kissinger, M Jayachandran K Perumal And C Sanjeevi Raja ”Structural and optical properties of electron beam evaporated CdSe thin films” Bull. Mater. Sci., Vol. 30, No. 6, December 2007, pp. 547–551.
[16]	G. W. F. Drake “Atomic, Molecular, & Optical Physics Handbook, Chaps. 19 and 57, ed. (AIP, Woodbury, NY, 1996).

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Mohammed Anwar Batal, Kaesar Alyamani. (2017). Broading Spectral Line Method for Determination Structural Parameters and Electronic Transitions in CdSe Artificial Atom. International Journal of Photochemistry and Photobiology, 1(1), 13-20. https://doi.org/10.11648/j.ijpp.20170101.13

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ACS Style

Mohammed Anwar Batal; Kaesar Alyamani. Broading Spectral Line Method for Determination Structural Parameters and Electronic Transitions in CdSe Artificial Atom. Int. J. Photochem. Photobiol. 2017, 1(1), 13-20. doi: 10.11648/j.ijpp.20170101.13

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AMA Style

Mohammed Anwar Batal, Kaesar Alyamani. Broading Spectral Line Method for Determination Structural Parameters and Electronic Transitions in CdSe Artificial Atom. Int J Photochem Photobiol. 2017;1(1):13-20. doi: 10.11648/j.ijpp.20170101.13

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@article{10.11648/j.ijpp.20170101.13,
  author = {Mohammed Anwar Batal and Kaesar Alyamani},
  title = {Broading Spectral Line Method for Determination Structural Parameters and Electronic Transitions in CdSe Artificial Atom},
  journal = {International Journal of Photochemistry and Photobiology},
  volume = {1},
  number = {1},
  pages = {13-20},
  doi = {10.11648/j.ijpp.20170101.13},
  url = {https://doi.org/10.11648/j.ijpp.20170101.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijpp.20170101.13},
  abstract = {Multi layers CdSe artificial atoms system prepared using Spin coating method. Using W-H method, which based on XRD Broading line profile, structural parameters of FTO/CdSe system were calculated. XRD spectrum reveal that CdSe nanoparticles have hexagonal structure, have high strain, show deposition layer on other do more stress and strain (Crystallization size (6.16 A◦), lattice constant C(7.16A◦), effective strain (0.07377 (lin–2 m–4)) between the nano crystals and dislocation (irregular) (26.443×1020 (lin–2 m–4)) were determined), which confirm more later by anther spectroscopic method. By doing fitting between experimental and theoretical absorption using Gaussian profile and Doppler broading line. Different electronic transitions were deduced and other broading curve were studying such as effect of particle size of artificial atoms, with doing more accurate fitting reveals existence of two intensities lines attributed to diffusion layer between FTO and CdSe artificial atoms.},
 year = {2017}
}

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TY  - JOUR
T1  - Broading Spectral Line Method for Determination Structural Parameters and Electronic Transitions in CdSe Artificial Atom
AU  - Mohammed Anwar Batal
AU  - Kaesar Alyamani
Y1  - 2017/03/01
PY  - 2017
N1  - https://doi.org/10.11648/j.ijpp.20170101.13
DO  - 10.11648/j.ijpp.20170101.13
T2  - International Journal of Photochemistry and Photobiology
JF  - International Journal of Photochemistry and Photobiology
JO  - International Journal of Photochemistry and Photobiology
SP  - 13
EP  - 20
PB  - Science Publishing Group
SN  - 2640-429X
UR  - https://doi.org/10.11648/j.ijpp.20170101.13
AB  - Multi layers CdSe artificial atoms system prepared using Spin coating method. Using W-H method, which based on XRD Broading line profile, structural parameters of FTO/CdSe system were calculated. XRD spectrum reveal that CdSe nanoparticles have hexagonal structure, have high strain, show deposition layer on other do more stress and strain (Crystallization size (6.16 A◦), lattice constant C(7.16A◦), effective strain (0.07377 (lin–2 m–4)) between the nano crystals and dislocation (irregular) (26.443×1020 (lin–2 m–4)) were determined), which confirm more later by anther spectroscopic method. By doing fitting between experimental and theoretical absorption using Gaussian profile and Doppler broading line. Different electronic transitions were deduced and other broading curve were studying such as effect of particle size of artificial atoms, with doing more accurate fitting reveals existence of two intensities lines attributed to diffusion layer between FTO and CdSe artificial atoms.
VL  - 1
IS  - 1
ER  -

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Author Information

Mohammed Anwar Batal

Department of Physics, College of Science, Aleppo University, Aleppo City, Syria
Kaesar Alyamani

Department of Physics, College of Science, Aleppo University, Aleppo City, Syria

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APA Style

Mohammed Anwar Batal, Kaesar Alyamani. (2017). Broading Spectral Line Method for Determination Structural Parameters and Electronic Transitions in CdSe Artificial Atom. International Journal of Photochemistry and Photobiology, 1(1), 13-20. https://doi.org/10.11648/j.ijpp.20170101.13

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ACS Style

Mohammed Anwar Batal; Kaesar Alyamani. Broading Spectral Line Method for Determination Structural Parameters and Electronic Transitions in CdSe Artificial Atom. Int. J. Photochem. Photobiol. 2017, 1(1), 13-20. doi: 10.11648/j.ijpp.20170101.13

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AMA Style

Mohammed Anwar Batal, Kaesar Alyamani. Broading Spectral Line Method for Determination Structural Parameters and Electronic Transitions in CdSe Artificial Atom. Int J Photochem Photobiol. 2017;1(1):13-20. doi: 10.11648/j.ijpp.20170101.13

Copy | Download

@article{10.11648/j.ijpp.20170101.13,
  author = {Mohammed Anwar Batal and Kaesar Alyamani},
  title = {Broading Spectral Line Method for Determination Structural Parameters and Electronic Transitions in CdSe Artificial Atom},
  journal = {International Journal of Photochemistry and Photobiology},
  volume = {1},
  number = {1},
  pages = {13-20},
  doi = {10.11648/j.ijpp.20170101.13},
  url = {https://doi.org/10.11648/j.ijpp.20170101.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijpp.20170101.13},
  abstract = {Multi layers CdSe artificial atoms system prepared using Spin coating method. Using W-H method, which based on XRD Broading line profile, structural parameters of FTO/CdSe system were calculated. XRD spectrum reveal that CdSe nanoparticles have hexagonal structure, have high strain, show deposition layer on other do more stress and strain (Crystallization size (6.16 A◦), lattice constant C(7.16A◦), effective strain (0.07377 (lin–2 m–4)) between the nano crystals and dislocation (irregular) (26.443×1020 (lin–2 m–4)) were determined), which confirm more later by anther spectroscopic method. By doing fitting between experimental and theoretical absorption using Gaussian profile and Doppler broading line. Different electronic transitions were deduced and other broading curve were studying such as effect of particle size of artificial atoms, with doing more accurate fitting reveals existence of two intensities lines attributed to diffusion layer between FTO and CdSe artificial atoms.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Broading Spectral Line Method for Determination Structural Parameters and Electronic Transitions in CdSe Artificial Atom
AU  - Mohammed Anwar Batal
AU  - Kaesar Alyamani
Y1  - 2017/03/01
PY  - 2017
N1  - https://doi.org/10.11648/j.ijpp.20170101.13
DO  - 10.11648/j.ijpp.20170101.13
T2  - International Journal of Photochemistry and Photobiology
JF  - International Journal of Photochemistry and Photobiology
JO  - International Journal of Photochemistry and Photobiology
SP  - 13
EP  - 20
PB  - Science Publishing Group
SN  - 2640-429X
UR  - https://doi.org/10.11648/j.ijpp.20170101.13
AB  - Multi layers CdSe artificial atoms system prepared using Spin coating method. Using W-H method, which based on XRD Broading line profile, structural parameters of FTO/CdSe system were calculated. XRD spectrum reveal that CdSe nanoparticles have hexagonal structure, have high strain, show deposition layer on other do more stress and strain (Crystallization size (6.16 A◦), lattice constant C(7.16A◦), effective strain (0.07377 (lin–2 m–4)) between the nano crystals and dislocation (irregular) (26.443×1020 (lin–2 m–4)) were determined), which confirm more later by anther spectroscopic method. By doing fitting between experimental and theoretical absorption using Gaussian profile and Doppler broading line. Different electronic transitions were deduced and other broading curve were studying such as effect of particle size of artificial atoms, with doing more accurate fitting reveals existence of two intensities lines attributed to diffusion layer between FTO and CdSe artificial atoms.
VL  - 1
IS  - 1
ER  -

Copy | Download