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Study on the Effect of Clay Minerals on CO2 Hydrate Formation

Received: 12 March 2024    Accepted: 29 March 2024    Published: 12 April 2024
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Abstract

With the massive emission of greenhouse gases, global warming has become an important challenge for human beings at present. Storing carbon dioxide in the form of solid hydrates in the ocean is an effective strategy to mitigate climate warming. Clay in the ocean may have an effect on hydrate formation and CO2 storage. In this study, montmorillonite and kaolinite were selected as clay minerals, and the effects of clay particles on CO2 hydrate formation in suspensions with different mass fractions were experimentally analyzed. The results showed that the clay particles were able to promote hydrate nucleation and shorten the induction time, but the final amount of hydrate was reduced, which was related to the bound water. CO2 hydrate storage in clay minerals with different water contents was investigated. The amount of CO2 storage in montmorillonite minerals first decreased and then increased with the increase of water content, while the amount of storage in kaolinite minerals increased. The reason was that the amount of bound water on the surfaces of montmorillonite and kaolinite was different, and the stronger bound water was difficult to form hydrates. The results revealed the effect of clay particles on CO2 hydrate formation and provided some experimental support for the CO2 storage by hydrate method in the ocean.

Published in Science Discovery (Volume 12, Issue 2)
DOI 10.11648/j.sd.20241202.12
Page(s) 27-32
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Carbon Dioxide Storage, Hydrate, Clay, Induction Time

References
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  • APA Style

    Han, Y., Feng, Y., Ge, Y., Li, Q., Yang, L., et al. (2024). Study on the Effect of Clay Minerals on CO2 Hydrate Formation . Science Discovery, 12(2), 27-32. https://doi.org/10.11648/j.sd.20241202.12

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    ACS Style

    Han, Y.; Feng, Y.; Ge, Y.; Li, Q.; Yang, L., et al. Study on the Effect of Clay Minerals on CO2 Hydrate Formation . Sci. Discov. 2024, 12(2), 27-32. doi: 10.11648/j.sd.20241202.12

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    AMA Style

    Han Y, Feng Y, Ge Y, Li Q, Yang L, et al. Study on the Effect of Clay Minerals on CO2 Hydrate Formation . Sci Discov. 2024;12(2):27-32. doi: 10.11648/j.sd.20241202.12

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  • @article{10.11648/j.sd.20241202.12,
      author = {Yuze Han and Yu Feng and Yang Ge and Qingping Li and Lei Yang and Lunxiang Zhang and Yongchen Song},
      title = {Study on the Effect of Clay Minerals on CO2 Hydrate Formation
    },
      journal = {Science Discovery},
      volume = {12},
      number = {2},
      pages = {27-32},
      doi = {10.11648/j.sd.20241202.12},
      url = {https://doi.org/10.11648/j.sd.20241202.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20241202.12},
      abstract = {With the massive emission of greenhouse gases, global warming has become an important challenge for human beings at present. Storing carbon dioxide in the form of solid hydrates in the ocean is an effective strategy to mitigate climate warming. Clay in the ocean may have an effect on hydrate formation and CO2 storage. In this study, montmorillonite and kaolinite were selected as clay minerals, and the effects of clay particles on CO2 hydrate formation in suspensions with different mass fractions were experimentally analyzed. The results showed that the clay particles were able to promote hydrate nucleation and shorten the induction time, but the final amount of hydrate was reduced, which was related to the bound water. CO2 hydrate storage in clay minerals with different water contents was investigated. The amount of CO2 storage in montmorillonite minerals first decreased and then increased with the increase of water content, while the amount of storage in kaolinite minerals increased. The reason was that the amount of bound water on the surfaces of montmorillonite and kaolinite was different, and the stronger bound water was difficult to form hydrates. The results revealed the effect of clay particles on CO2 hydrate formation and provided some experimental support for the CO2 storage by hydrate method in the ocean.
    },
     year = {2024}
    }
    

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  • TY  - JOUR
    T1  - Study on the Effect of Clay Minerals on CO2 Hydrate Formation
    
    AU  - Yuze Han
    AU  - Yu Feng
    AU  - Yang Ge
    AU  - Qingping Li
    AU  - Lei Yang
    AU  - Lunxiang Zhang
    AU  - Yongchen Song
    Y1  - 2024/04/12
    PY  - 2024
    N1  - https://doi.org/10.11648/j.sd.20241202.12
    DO  - 10.11648/j.sd.20241202.12
    T2  - Science Discovery
    JF  - Science Discovery
    JO  - Science Discovery
    SP  - 27
    EP  - 32
    PB  - Science Publishing Group
    SN  - 2331-0650
    UR  - https://doi.org/10.11648/j.sd.20241202.12
    AB  - With the massive emission of greenhouse gases, global warming has become an important challenge for human beings at present. Storing carbon dioxide in the form of solid hydrates in the ocean is an effective strategy to mitigate climate warming. Clay in the ocean may have an effect on hydrate formation and CO2 storage. In this study, montmorillonite and kaolinite were selected as clay minerals, and the effects of clay particles on CO2 hydrate formation in suspensions with different mass fractions were experimentally analyzed. The results showed that the clay particles were able to promote hydrate nucleation and shorten the induction time, but the final amount of hydrate was reduced, which was related to the bound water. CO2 hydrate storage in clay minerals with different water contents was investigated. The amount of CO2 storage in montmorillonite minerals first decreased and then increased with the increase of water content, while the amount of storage in kaolinite minerals increased. The reason was that the amount of bound water on the surfaces of montmorillonite and kaolinite was different, and the stronger bound water was difficult to form hydrates. The results revealed the effect of clay particles on CO2 hydrate formation and provided some experimental support for the CO2 storage by hydrate method in the ocean.
    
    VL  - 12
    IS  - 2
    ER  - 

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Author Information
  • Key Laboratory of Ocean Energy Utilization and Energy Conservation of the Ministry of Education, Dalian University of Technology, Dalian, China

  • Key Laboratory of Ocean Energy Utilization and Energy Conservation of the Ministry of Education, Dalian University of Technology, Dalian, China

  • State Key Laboratory of Natural Gas Hydrates, China National Offshore Oil Corporation, Beijing, China

  • State Key Laboratory of Natural Gas Hydrates, China National Offshore Oil Corporation, Beijing, China

  • Key Laboratory of Ocean Energy Utilization and Energy Conservation of the Ministry of Education, Dalian University of Technology, Dalian, China; Ningbo Institute of Dalian University of Technology, Ningbo, China

  • Key Laboratory of Ocean Energy Utilization and Energy Conservation of the Ministry of Education, Dalian University of Technology, Dalian, China; Ningbo Institute of Dalian University of Technology, Ningbo, China

  • Key Laboratory of Ocean Energy Utilization and Energy Conservation of the Ministry of Education, Dalian University of Technology, Dalian, China

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