Black Citric Acid Polymer (PN) Pozzolana Activated - Na-PN-Pozzolana-CE Material Synthesis Tested As Cationic Exchanger

Andry Tahina Rabeharitsara; Marie Nicole Rabemananjara; Nambinina Richard Randriana

doi:doi:10.11648/j.ajac.20190706.11

| Peer-Reviewed

Black Citric Acid Polymer (PN) Pozzolana Activated - Na-PN-Pozzolana-CE Material Synthesis Tested As Cationic Exchanger

Andry Tahina Rabeharitsara, Marie Nicole Rabemananjara, Nambinina Richard Randriana

Published in American Journal of Applied Chemistry (Volume 7, Issue 6)

Received: 1 October 2019 Accepted: 22 October 2019 Published: 7 November 2019

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

It was showed that black citric acid polymer (PN) have capacities to be a potential raw materials for realizing a cationic exchanger seeing that the treated water solution through PN kept a brown color of brown citric acid polymers from PN during its activations with NaOH. So, the objective of this publication was to realize not only materials and process which could clarify the brown color of the PN treated water but also to realize immediately a cationic exchanger materials with at the end a clarified transparent water. Consequently, two raw materials have been selected to do these realizations: pozzolana and black citric acid polymer (PN). The first step was to elaborate a procedure for synthesizing PN-pozzolana material founded upon water as PN’s liquid vector, pozzolana/PN weigh relationship, used pozzolana’s oxygen total atoms contents, water/pn molar relationship and water/pozzolana molar relationship. Then, PN-pozzolana was characterized by NaOH-0.05N titration enabled to value the on surface PN, the total PN dispersed, the on vacuole PN with maybe pozzolana vacuole porosity recovery rate. Also, the PN-pozzolana material was used to clarify by PN a treated water cationic exchanger according to a procedure using a PN-tubular filter with well-defined experimental conditions leading to good results. The second step was to elaborate a procedure for synthesizing Na-PN-pozzolana-CE cationic exchanger founded upon PN-pozzolana activation with NaOH as described on bibliography followed by thermic treatment. Then, Na-PN-pozzolana-CE cationic exchanger was characterized by HCl-0.049N enabled to value the total Na⁺ dispersed on PN-pozzolana and Na⁺ on surface per total PN moles ratio. Results and discussions of the thermic treatment were done seeing that there were all the time weight diminution of activated Na-PN-pozzolana thermic treated. Finally, exchange cationic tests with CaCO₃ solution were carried-out with different contact time on these Na-PN-pozzolana-CE cationic exchanger and the Ca²⁺ contents of treated water solution was followed by EDTA-complexometric titration. Results showed clearly that not only PN-pozzolana material could clarify the brown treated water but also Na-PN-pozzolana-CE is a good cationic exchanger with a maximal Ca²⁺ retained rate capacity around 93.27 [%].

Published in	American Journal of Applied Chemistry (Volume 7, Issue 6)
DOI	10.11648/j.ajac.20190706.11
Page(s)	145-160
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Black Citric Acid Polymer (PN), Pozzolana, Water, Cationic Exchange, Sodium Hydroxide, Chloride Acid, Calcium Carbonate, Complexometric-EDTA, Kinetics

References

[1]	Andry Tahina Rabeharitsara, Marie Nicole Rabemananjara, Nambinina Richard Randriana–“Black Citric Acid Polymer (PN) Capacity As Raw Material For Cationic Exchanger Realization”. American Journal of Applied Chemistry in Vol. 7, Issue Number 2, April 2019.
[2]	Sammy Eric ANDRIAMBOLA–«Valorisation de l’acide citrique en polymères et en sels de mono-di-et tri-ammonium». Mémoire de fin d’étude en vue de l’obtention du diplôme d’Ingénieur en Génie Chimique. E. S. P. A. Université d’Antananarivo. 2013.
[3]	Andry Tahina RABEHARITSARA, Behevitra ROVATAHIANJANAHARY, Nambinina Richard RANDRIANA–«Pine Wood Powder Treatment To B_XH⁺ Homogeneous Catalyst (H⁺/H₂SO₄) Supported On Its Aromatics And PNA–Application In Black Citric Acid Polymer Synthesis». American Journal of Polymer Science and Technology. Vol. 4, No. 1, 2018, pp. 1-27. doi: 10.11648/j.ajpst.20180401.11.
[4]	Behevitra ROVATAHIANJANAHARY - «Synthèse de catalyseurs homogènes B_XH⁺ supportés sur les alcènes des aromatiques et des polynucléaires aromatiques oxygénés composant le bois du pin par traitement à l’acide sulfurique – Application dans la synthèse des polymères noires d’acide citrique». Mémoire de fin d’étude en vue de l’obtention du diplôme de Licence en génie des procédés chimiques et industriels. Ecole Supérieure Polytechnique Antananarivo (E. S. P. A)–Université d’Antananarivo. 2018.
[5]	Andry Tahina RABEHARITSARA, Marie Nicole RABEMANANJARA, Nambinina Richard RANDRIANA, Haritiana Jeannelle RAKOTONIRINA, Edouard ANDRIANARISON, André RAZAFIMANDEFITRA, Baholy ROBIJAONA. «Auto-Inflammation Test of Black Citric Acid Polymer (PN) and Fuel Oil (FO) Mixes–Coke Formation». American Journal of Applied Chemistry. Vol. 5, No. 3, June 2017. doi: 10.11648/j.ajac.20170503.11.
[6]	Marie Louise Nicole RABEMANANJARA. «Test d’auto-inflammation du mélange polymère noir d’acide citrique (PN) et du fuel oil (FO)–Etude de la formation de coke». Mémoire de fin d’étude en vue de l’obtention du diplôme de Licence en génie des procédés chimiques et industriels. Ecole Supérieure Polytechnique Antananarivo (E. S. P. A)–Université d’Antananarivo. 2017.
[7]	Philippe Rocher, Géologue, BRGM Auvergne “La pouzzolane–Fiches détaillées”.
[8]	www.a2bpouzzolanes.com/index.php/caracteristiques-de-la-pouzzolane-06/07/2019
[9]	Alsac. C. «Contribution à l’étude des pouzzolanes de Madagascar», Ministère de l’économie nationale, 1963, Antananarivo–Madagascar.
[10]	Rijalalaina Rakotosaona (1), Lanto Harivola Rabarioelisolo (1), Rianasoambolanoro Rakotosaona (2), Frédéric Randrianarivelo (1), Jean de Dieu Ramaroson (3), Phillipe Andrianary (1), Lala Andrianaivo (1) «Etude du pouvoir décolorant de la pouzzolane pour le traitement des eaux usées» MADA-HARY, ISSN 2410-0315, VOL. 3, 2015. (1) Ecole Supérieure Polytechnique d’Antananarivo, (2) Institut Malgache des Recherches Appliquées, (3) Centre National des Recherches Industrielle et Technologique, Département Matériaux et Génie Civil.
[11]	Isabelle Guénot-Delahaie «Contribution à l’analyse physique et à la modélisation du fluage propre du béton»
[12]	Regourd M. «L’eau » in Le béton hydraulique, Presses de l’ENPC, Paris, pp. 59-68 [1982b].
[13]	Sierra R. «Répartition des différentes formes d’eau dans la structure des pâtes pures de C₃S et de ciment Portland, in Proceedings of the 7th International Congress on the Chemistry of Cement, Paris, France, vol. 3, pp. 201-206 [1980].
[14]	https://fr.wikipedia.org/wiki/Verre.
[15]	BTS FEE Lycée Monge Nantes «Dureté d’une eau minérale–Dosage complexométrique» http://nicole.cortial.net.
[16]	B. Kiruthiga «Complexometric titration with EDTA» Dept. of pharmaceutical chemistry.
[17]	Prof. Dr. Klaus Köhler “Modern Methods in Heterogeneous Catalysis Reserch” Lecture series Fritz Haber Institute, TU Berlin & HU Berlin: November, 10^th, 2006–Department Chemie, TU München.

Cite This Article

Plain Text BibTeX RIS

APA Style

Andry Tahina Rabeharitsara, Marie Nicole Rabemananjara, Nambinina Richard Randriana. (2019). Black Citric Acid Polymer (PN) Pozzolana Activated - Na-PN-Pozzolana-CE Material Synthesis Tested As Cationic Exchanger. American Journal of Applied Chemistry, 7(6), 145-160. https://doi.org/10.11648/j.ajac.20190706.11

Copy | Download

ACS Style

Andry Tahina Rabeharitsara; Marie Nicole Rabemananjara; Nambinina Richard Randriana. Black Citric Acid Polymer (PN) Pozzolana Activated - Na-PN-Pozzolana-CE Material Synthesis Tested As Cationic Exchanger. Am. J. Appl. Chem. 2019, 7(6), 145-160. doi: 10.11648/j.ajac.20190706.11

Copy | Download

AMA Style

Andry Tahina Rabeharitsara, Marie Nicole Rabemananjara, Nambinina Richard Randriana. Black Citric Acid Polymer (PN) Pozzolana Activated - Na-PN-Pozzolana-CE Material Synthesis Tested As Cationic Exchanger. Am J Appl Chem. 2019;7(6):145-160. doi: 10.11648/j.ajac.20190706.11

Copy | Download

@article{10.11648/j.ajac.20190706.11,
  author = {Andry Tahina Rabeharitsara and Marie Nicole Rabemananjara and Nambinina Richard Randriana},
  title = {Black Citric Acid Polymer (PN) Pozzolana Activated - Na-PN-Pozzolana-CE Material Synthesis Tested As Cationic Exchanger},
  journal = {American Journal of Applied Chemistry},
  volume = {7},
  number = {6},
  pages = {145-160},
  doi = {10.11648/j.ajac.20190706.11},
  url = {https://doi.org/10.11648/j.ajac.20190706.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20190706.11},
  abstract = {It was showed that black citric acid polymer (PN) have capacities to be a potential raw materials for realizing a cationic exchanger seeing that the treated water solution through PN kept a brown color of brown citric acid polymers from PN during its activations with NaOH. So, the objective of this publication was to realize not only materials and process which could clarify the brown color of the PN treated water but also to realize immediately a cationic exchanger materials with at the end a clarified transparent water. Consequently, two raw materials have been selected to do these realizations: pozzolana and black citric acid polymer (PN). The first step was to elaborate a procedure for synthesizing PN-pozzolana material founded upon water as PN’s liquid vector, pozzolana/PN weigh relationship, used pozzolana’s oxygen total atoms contents, water/pn molar relationship and water/pozzolana molar relationship. Then, PN-pozzolana was characterized by NaOH-0.05N titration enabled to value the on surface PN, the total PN dispersed, the on vacuole PN with maybe pozzolana vacuole porosity recovery rate. Also, the PN-pozzolana material was used to clarify by PN a treated water cationic exchanger according to a procedure using a PN-tubular filter with well-defined experimental conditions leading to good results. The second step was to elaborate a procedure for synthesizing Na-PN-pozzolana-CE cationic exchanger founded upon PN-pozzolana activation with NaOH as described on bibliography followed by thermic treatment. Then, Na-PN-pozzolana-CE cationic exchanger was characterized by HCl-0.049N enabled to value the total Na+ dispersed on PN-pozzolana and Na+ on surface per total PN moles ratio. Results and discussions of the thermic treatment were done seeing that there were all the time weight diminution of activated Na-PN-pozzolana thermic treated. Finally, exchange cationic tests with CaCO3 solution were carried-out with different contact time on these Na-PN-pozzolana-CE cationic exchanger and the Ca2+ contents of treated water solution was followed by EDTA-complexometric titration. Results showed clearly that not only PN-pozzolana material could clarify the brown treated water but also Na-PN-pozzolana-CE is a good cationic exchanger with a maximal Ca2+ retained rate capacity around 93.27 [%].},
 year = {2019}
}

Copy | Download

TY  - JOUR
T1  - Black Citric Acid Polymer (PN) Pozzolana Activated - Na-PN-Pozzolana-CE Material Synthesis Tested As Cationic Exchanger
AU  - Andry Tahina Rabeharitsara
AU  - Marie Nicole Rabemananjara
AU  - Nambinina Richard Randriana
Y1  - 2019/11/07
PY  - 2019
N1  - https://doi.org/10.11648/j.ajac.20190706.11
DO  - 10.11648/j.ajac.20190706.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 145
EP  - 160
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20190706.11
AB  - It was showed that black citric acid polymer (PN) have capacities to be a potential raw materials for realizing a cationic exchanger seeing that the treated water solution through PN kept a brown color of brown citric acid polymers from PN during its activations with NaOH. So, the objective of this publication was to realize not only materials and process which could clarify the brown color of the PN treated water but also to realize immediately a cationic exchanger materials with at the end a clarified transparent water. Consequently, two raw materials have been selected to do these realizations: pozzolana and black citric acid polymer (PN). The first step was to elaborate a procedure for synthesizing PN-pozzolana material founded upon water as PN’s liquid vector, pozzolana/PN weigh relationship, used pozzolana’s oxygen total atoms contents, water/pn molar relationship and water/pozzolana molar relationship. Then, PN-pozzolana was characterized by NaOH-0.05N titration enabled to value the on surface PN, the total PN dispersed, the on vacuole PN with maybe pozzolana vacuole porosity recovery rate. Also, the PN-pozzolana material was used to clarify by PN a treated water cationic exchanger according to a procedure using a PN-tubular filter with well-defined experimental conditions leading to good results. The second step was to elaborate a procedure for synthesizing Na-PN-pozzolana-CE cationic exchanger founded upon PN-pozzolana activation with NaOH as described on bibliography followed by thermic treatment. Then, Na-PN-pozzolana-CE cationic exchanger was characterized by HCl-0.049N enabled to value the total Na+ dispersed on PN-pozzolana and Na+ on surface per total PN moles ratio. Results and discussions of the thermic treatment were done seeing that there were all the time weight diminution of activated Na-PN-pozzolana thermic treated. Finally, exchange cationic tests with CaCO3 solution were carried-out with different contact time on these Na-PN-pozzolana-CE cationic exchanger and the Ca2+ contents of treated water solution was followed by EDTA-complexometric titration. Results showed clearly that not only PN-pozzolana material could clarify the brown treated water but also Na-PN-pozzolana-CE is a good cationic exchanger with a maximal Ca2+ retained rate capacity around 93.27 [%].
VL  - 7
IS  - 6
ER  -

Copy | Download

Author Information

Andry Tahina Rabeharitsara

Chemical Process Engineering Department E. S. P. A, Antananarivo University, Antananarivo, Madagascar
Marie Nicole Rabemananjara

Chemical Process Engineering Department E. S. P. A, Antananarivo University, Antananarivo, Madagascar
Nambinina Richard Randriana

Chemical Process Engineering Department E. S. P. A, Antananarivo University, Antananarivo, Madagascar

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Andry Tahina Rabeharitsara, Marie Nicole Rabemananjara, Nambinina Richard Randriana. (2019). Black Citric Acid Polymer (PN) Pozzolana Activated - Na-PN-Pozzolana-CE Material Synthesis Tested As Cationic Exchanger. American Journal of Applied Chemistry, 7(6), 145-160. https://doi.org/10.11648/j.ajac.20190706.11

Copy | Download

ACS Style

Andry Tahina Rabeharitsara; Marie Nicole Rabemananjara; Nambinina Richard Randriana. Black Citric Acid Polymer (PN) Pozzolana Activated - Na-PN-Pozzolana-CE Material Synthesis Tested As Cationic Exchanger. Am. J. Appl. Chem. 2019, 7(6), 145-160. doi: 10.11648/j.ajac.20190706.11

Copy | Download

AMA Style

Andry Tahina Rabeharitsara, Marie Nicole Rabemananjara, Nambinina Richard Randriana. Black Citric Acid Polymer (PN) Pozzolana Activated - Na-PN-Pozzolana-CE Material Synthesis Tested As Cationic Exchanger. Am J Appl Chem. 2019;7(6):145-160. doi: 10.11648/j.ajac.20190706.11

Copy | Download

@article{10.11648/j.ajac.20190706.11,
  author = {Andry Tahina Rabeharitsara and Marie Nicole Rabemananjara and Nambinina Richard Randriana},
  title = {Black Citric Acid Polymer (PN) Pozzolana Activated - Na-PN-Pozzolana-CE Material Synthesis Tested As Cationic Exchanger},
  journal = {American Journal of Applied Chemistry},
  volume = {7},
  number = {6},
  pages = {145-160},
  doi = {10.11648/j.ajac.20190706.11},
  url = {https://doi.org/10.11648/j.ajac.20190706.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20190706.11},
  abstract = {It was showed that black citric acid polymer (PN) have capacities to be a potential raw materials for realizing a cationic exchanger seeing that the treated water solution through PN kept a brown color of brown citric acid polymers from PN during its activations with NaOH. So, the objective of this publication was to realize not only materials and process which could clarify the brown color of the PN treated water but also to realize immediately a cationic exchanger materials with at the end a clarified transparent water. Consequently, two raw materials have been selected to do these realizations: pozzolana and black citric acid polymer (PN). The first step was to elaborate a procedure for synthesizing PN-pozzolana material founded upon water as PN’s liquid vector, pozzolana/PN weigh relationship, used pozzolana’s oxygen total atoms contents, water/pn molar relationship and water/pozzolana molar relationship. Then, PN-pozzolana was characterized by NaOH-0.05N titration enabled to value the on surface PN, the total PN dispersed, the on vacuole PN with maybe pozzolana vacuole porosity recovery rate. Also, the PN-pozzolana material was used to clarify by PN a treated water cationic exchanger according to a procedure using a PN-tubular filter with well-defined experimental conditions leading to good results. The second step was to elaborate a procedure for synthesizing Na-PN-pozzolana-CE cationic exchanger founded upon PN-pozzolana activation with NaOH as described on bibliography followed by thermic treatment. Then, Na-PN-pozzolana-CE cationic exchanger was characterized by HCl-0.049N enabled to value the total Na+ dispersed on PN-pozzolana and Na+ on surface per total PN moles ratio. Results and discussions of the thermic treatment were done seeing that there were all the time weight diminution of activated Na-PN-pozzolana thermic treated. Finally, exchange cationic tests with CaCO3 solution were carried-out with different contact time on these Na-PN-pozzolana-CE cationic exchanger and the Ca2+ contents of treated water solution was followed by EDTA-complexometric titration. Results showed clearly that not only PN-pozzolana material could clarify the brown treated water but also Na-PN-pozzolana-CE is a good cationic exchanger with a maximal Ca2+ retained rate capacity around 93.27 [%].},
 year = {2019}
}

Copy | Download

TY  - JOUR
T1  - Black Citric Acid Polymer (PN) Pozzolana Activated - Na-PN-Pozzolana-CE Material Synthesis Tested As Cationic Exchanger
AU  - Andry Tahina Rabeharitsara
AU  - Marie Nicole Rabemananjara
AU  - Nambinina Richard Randriana
Y1  - 2019/11/07
PY  - 2019
N1  - https://doi.org/10.11648/j.ajac.20190706.11
DO  - 10.11648/j.ajac.20190706.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 145
EP  - 160
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20190706.11
AB  - It was showed that black citric acid polymer (PN) have capacities to be a potential raw materials for realizing a cationic exchanger seeing that the treated water solution through PN kept a brown color of brown citric acid polymers from PN during its activations with NaOH. So, the objective of this publication was to realize not only materials and process which could clarify the brown color of the PN treated water but also to realize immediately a cationic exchanger materials with at the end a clarified transparent water. Consequently, two raw materials have been selected to do these realizations: pozzolana and black citric acid polymer (PN). The first step was to elaborate a procedure for synthesizing PN-pozzolana material founded upon water as PN’s liquid vector, pozzolana/PN weigh relationship, used pozzolana’s oxygen total atoms contents, water/pn molar relationship and water/pozzolana molar relationship. Then, PN-pozzolana was characterized by NaOH-0.05N titration enabled to value the on surface PN, the total PN dispersed, the on vacuole PN with maybe pozzolana vacuole porosity recovery rate. Also, the PN-pozzolana material was used to clarify by PN a treated water cationic exchanger according to a procedure using a PN-tubular filter with well-defined experimental conditions leading to good results. The second step was to elaborate a procedure for synthesizing Na-PN-pozzolana-CE cationic exchanger founded upon PN-pozzolana activation with NaOH as described on bibliography followed by thermic treatment. Then, Na-PN-pozzolana-CE cationic exchanger was characterized by HCl-0.049N enabled to value the total Na+ dispersed on PN-pozzolana and Na+ on surface per total PN moles ratio. Results and discussions of the thermic treatment were done seeing that there were all the time weight diminution of activated Na-PN-pozzolana thermic treated. Finally, exchange cationic tests with CaCO3 solution were carried-out with different contact time on these Na-PN-pozzolana-CE cationic exchanger and the Ca2+ contents of treated water solution was followed by EDTA-complexometric titration. Results showed clearly that not only PN-pozzolana material could clarify the brown treated water but also Na-PN-pozzolana-CE is a good cationic exchanger with a maximal Ca2+ retained rate capacity around 93.27 [%].
VL  - 7
IS  - 6
ER  -

Copy | Download